Lanthano-phosphotungstate: A water soluble and reusable catalyst for oxidation of alcohols using H2O2 as an oxidant

RSC Advances ◽  
2014 ◽  
Vol 4 (72) ◽  
pp. 38446-38449 ◽  
Author(s):  
Mukesh Kumar Saini ◽  
Rakesh Gupta ◽  
Swati Parbhakar ◽  
Surendra Singh ◽  
Firasat Hussain
Keyword(s):  
Carbonyl Compounds ◽  
Water Soluble ◽  
Reusable Catalyst ◽  
Oxidation Of Alcohols

Oxidation of alcohols using H2O2 to corresponding carbonyl compounds in good yields for lanthano-phosphotungstates catalysts and its recyclability up to five cycles was envisaged in water.

A Metalloprotein Inspired Ruthenium Complex as an Efficient and Reusable Catalyst for Selective Oxidation of Alcohols to their Corresponding Carbonyl Compounds

2016 ◽  
Vol 1 (18) ◽  
pp. 5929-5935 ◽  
Author(s):  
Ramen Jamatia ◽  
Ajay Gupta ◽  
Mrityunjoy Mahato ◽  
Ranjit A. Patil ◽  
Yuan-Ron Ma ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Ruthenium Complex ◽  
Reusable Catalyst ◽  
Oxidation Of Alcohols

New active and recyclable catalytic systems based on [Zn4(H2O)2(PW9O34)2]10– for alcohol oxidation with hydrogen peroxide in water

2011 ◽  
Vol 89 (1) ◽  
pp. 13-18 ◽  
Author(s):  
Yong Ding ◽  
Wei Zhao ◽  
Bao-chun Ma ◽  
Wen-yuan Qiu
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Alcohol Oxidation ◽  
Reusable Catalyst ◽  
Catalytic Systems ◽  
Oxidation Of Alcohols ◽  
Sandwich Type ◽  
High Yields

A “sandwich” type tungstophosphate, [Zn4(H2O)2(PW9O34)2]10–, was used as the efficient and reusable catalyst for alcohol oxidation. The catalyst I of K10Zn4(H2O)2(PW9O34)2·20H2O and the catalyst II of [(C18H37)2(CH3)2N]8K2[Zn4(H2O)2(PW9O34)2] were used to catalyze the oxidation of alcohols in water. High yields of the corresponding carbonyl compounds were obtained. The catalysts were recycled several times without loss in activity.

scholarly journals 2-Iodoxybenzoic Acid: An Oxidant for Functional Group Transformations: (A-Review)

2020 ◽  
Vol 36 (05) ◽  
pp. 792-803
Author(s):  
Vipin A. Nair
Keyword(s):  
Carbonyl Compounds ◽  
Room Temperature ◽  
Water Soluble ◽  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Carbon Carbon Bond ◽  
Oxidation Of Alcohols ◽  
Major Application ◽  
Almost All ◽  
Derivatives Of

A major application of 2-Iodoxybenzoic acid (IBX) is the oxidation of alcohols to carbonyl compounds, at room temperature. IBX is insoluble in almost all solvents, except DMSO. IBX tolerates amine functionality and is therefore used for the oxidation of amino alcohols to amino carbonyl compounds. IBX oxidizes 1,2-glycols without the cleavage of the glycol carbon-carbon bond. Allylic and benzylic positions are also susceptible to oxidation by IBX. Synthesis of a,b-unsaturated carbonyl compounds from carbonyl compounds can be accomplished by using IBX as oxidant. Silyl enol ethers undergo oxidation upon exposure to IBX and 4-methoxypyridine N-oxide. Water-soluble derivatives of IBX, and polymer-based IBX, with additional advantages, have also been developed. IBX mediated transformations facilitate the construction of diverse heterocyclic systems.

Ruthenium/magnesium–lanthanum mixed oxide: An efficient reusable catalyst for oxidation of alcohols by using molecular oxygen

2012 ◽  
Vol 359 ◽  
pp. 1-7 ◽  
Author(s):  
M. Lakshmi Kantam ◽  
R. Sudarshan Reddy ◽  
Ujjwal Pal ◽  
M. Sudhakar ◽  
A. Venugopal ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Mixed Oxide ◽  
Reusable Catalyst ◽  
Oxidation Of Alcohols

N-tert-Butylbenzenesulfenamide-catalyzed oxidation of alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide

Tetrahedron ◽  
2003 ◽  
Vol 59 (35) ◽  
pp. 6739-6750 ◽  
Author(s):  
Jun-ichi Matsuo ◽  
Daisuke Iida ◽  
Hiroyuki Yamanaka ◽  
Teruaki Mukaiyama
Keyword(s):  
Carbonyl Compounds ◽  
Oxidation Of Alcohols ◽  
Catalyzed Oxidation

Chemoselective C−H Oxidation of Alcohols to Carbonyl Compounds with Iodosobenzene Catalyzed by (Salen)chromium Complex

2000 ◽  
Vol 65 (7) ◽  
pp. 1915-1918 ◽  
Author(s):  
Waldemar Adam ◽  
Feyissa Gadissa Gelalcha ◽  
Chantu R. Saha-Möller ◽  
Veit R. Stegmann
Keyword(s):  
Carbonyl Compounds ◽  
Chromium Complex ◽  
Oxidation Of Alcohols
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