Reversal of the enantioselectivity in aldol addition over immobilized di- and tripeptides: studies under continuous flow conditions

RSC Advances ◽  
2014 ◽  
Vol 4 (106) ◽  
pp. 61611-61618 ◽  
Author(s):  
András Gurka ◽  
Imre Bucsi ◽  
Lenke Kovács ◽  
György Szőllősi ◽  
Mihály Bartók

The reversal of the enantioselectivity in the heterogeneous asymmetric direct aldol reactions obtained over resin supported di- versus tripeptides was studied in a continuous-flow system.

2019 ◽  
Vol 21 (7) ◽  
pp. 1193-1203 ◽  
Author(s):  
Christopher K. Bartlett ◽  
Robin M. Slawson ◽  
Neil R. Thomson

Recovery of BTEX biodegradation, sulfate-reducing bacteria and associated community profile following exposure to persulfate in a continuous flow system.


2016 ◽  
Vol 7 (9) ◽  
pp. 5671-5679 ◽  
Author(s):  
Yi Shen ◽  
Adam Roberge ◽  
Rui Tan ◽  
Megan Y. Gee ◽  
Dylan C. Gary ◽  
...  

GPC provides a general approach to purification of a variety of nanocrystal types, and additionally achieves ligand exchange in a continuous flow system.


2020 ◽  
Vol 22 (21) ◽  
pp. 7398-7405 ◽  
Author(s):  
Jose Alirio Mendoza Mesa ◽  
Francesco Brandi ◽  
Irina Shekova ◽  
Markus Antonietti ◽  
Majd Al-Naji

The continuous flow synthesis of p-xylene (pXL) via Diels–Alder cycloaddition of lignocellulosic biomass-derivable 2,5-dimethylfuran (DMF) and acrylic acid (AA) was performed over different types of zeolites.


2017 ◽  
Vol 5 (6) ◽  
pp. 1148-1154 ◽  
Author(s):  
Hirokazu Seto ◽  
Makoto Shibuya ◽  
Hikaru Matsumoto ◽  
Yu Hoshino ◽  
Yoshiko Miura

Macroporous materials, called glycomonoliths, were prepared from saccharide-containing monomers, and applied for affinity bioseparation of proteins in a continuous-flow system.


2021 ◽  
Author(s):  
Caizhen Yue ◽  
Yasuhiro Yamashita ◽  
Shu Kobayashi

Catalytic enantioselective aldol reactions of trifluoroacetophenones with ketones under continuous-flow conditions have been developed for the first time by using polystyrene-supported prolinamides. The robustness of the flow system was demonstrated...


2021 ◽  
Author(s):  
David Jenkins

A stable microbial consortium capable of cellulose hydrolysis under initial aerobic conditions has been enriched in a continuous flow system. Anaerobic conditions were created and maintained within the flow system using only microbial metabolism. A DGGE community profile of samples taken throughout the enrichment process indicates that the community stabilized upon entry into the continuous flow system, and maintained function and members throughout. The effect of flow rate on cellulose degradation and end product production was assessed. The cellulose degradation rate was found to be notably faster at a flow rate of 0.1 ml/min (D 0.75/hr) than a flow rate of 0.2 ml/min (D1.50/hr). Furthermore, an ethanol to acetate ratio nearly 8 times higher than previously reported values in the literature was also observed at 0.1 ml/min (D0.75/hr). With reduced flow rate and high ethanol to acetate ratios, the enriched community may be well suited for consolidate bioprocessing.


2017 ◽  
Vol 5 (8) ◽  
pp. 3792-3797 ◽  
Author(s):  
Wei Huang ◽  
Beatriz Chiyin Ma ◽  
Di Wang ◽  
Zi Jun Wang ◽  
Run Li ◽  
...  

Here, we report on a fixed-bed photoreactor containing conjugated nanoporous polymer-coated glass fibers for visible light-promoted, heterogeneous photoredox reactions in a continuous flow system.


2021 ◽  
Author(s):  
David Jenkins

A stable microbial consortium capable of cellulose hydrolysis under initial aerobic conditions has been enriched in a continuous flow system. Anaerobic conditions were created and maintained within the flow system using only microbial metabolism. A DGGE community profile of samples taken throughout the enrichment process indicates that the community stabilized upon entry into the continuous flow system, and maintained function and members throughout. The effect of flow rate on cellulose degradation and end product production was assessed. The cellulose degradation rate was found to be notably faster at a flow rate of 0.1 ml/min (D 0.75/hr) than a flow rate of 0.2 ml/min (D1.50/hr). Furthermore, an ethanol to acetate ratio nearly 8 times higher than previously reported values in the literature was also observed at 0.1 ml/min (D0.75/hr). With reduced flow rate and high ethanol to acetate ratios, the enriched community may be well suited for consolidate bioprocessing.


2020 ◽  
Vol 5 (7) ◽  
pp. 1300-1310 ◽  
Author(s):  
Florian Menzel ◽  
Thomas Klein ◽  
Thomas Ziegler ◽  
Jochen M. Neumaier

This paper presents the development of milli- and microfluidic reactors made of polyether ether ketone (PEEK) and 3D-printed equipment for a complete continuous flow system.


2019 ◽  
Vol 4 (5) ◽  
pp. 919-926
Author(s):  
Zheng Fang ◽  
Yuhang Yang ◽  
Jiajia Gu ◽  
Zhao Yang ◽  
Feiyang Dai ◽  
...  

A novel, simple, power-saving and effective method for the synthesis and scale-up of cationic water-soluble polyelectrolytes represented by dimethyldiallylammonium chloride (DMDAAC) with commercially available reagents in a two-step continuous flow system has been developed.


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