One-pot transesterification and esterification of waste cooking oil via ethanolysis using Sr:Zr mixed oxide as solid catalyst

RSC Advances ◽  
2014 ◽  
Vol 4 (82) ◽  
pp. 43671-43681 ◽  
Author(s):  
Navjot Kaur ◽  
Amjad Ali
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Vegetable Oils ◽  
Mixed Oxide ◽  
Waste Cooking Oil ◽  
Solid Catalyst ◽  
One Pot ◽  
Basic Sites ◽  
Cooking Oil

Prepared 2Sr:Zr-650 catalyst possesses both acidic and basic sites, hence it was able to catalyze the simultaneous esterification and transesterification of free fatty acid containing vegetable oils.

scholarly journals Penentuan Kadar Asam Lemak Bebas Dan Kadar Air Pada Minyak Goreng Yang Digunakan Oleh Pedagang Gorengan Di Jalan Manyar Sabrangan, Mulyorejo, Surabaya

2018 ◽  
Vol 3 (2) ◽  
pp. 17-22
Author(s):  
Ika Fitri Ulfindrayani ◽  
Qurrota A’yuni
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Water Content ◽  
Oil Quality ◽  
Waste Cooking Oil ◽  
Good Choice ◽  
The Body ◽  
Fried Food ◽  
Cooking Oil

ABSTRAK Kebutuhan minyak goreng sawit di Indonesia terus meningkat dari tahun ke tahun. Kebutuhan terbesar didominasi oleh penggunaan minyak goreng sawit sebagai media untuk menggoreng makanan yang salah satunya yaitu jajanan goreng (gorengan). Mayoritas pedagang gorengan tidak memperhatikan kualitas dari minyak goreng yang digunakan. Banyak pedagang gorengan membeli minyak goreng bekas (jelantah) demi mendapatkan keuntungan yang besar. Pada minyak jelantah mengandung asam lemak bebas akibat pemanasan berkala yang berbahaya bagi tubuh. Oleh karena itu, pada penelitian ini dilakukan pengujian kualitas minyak goreng melalui dua parameter yaitu kadar asam lemak bebas dan kadar air. Hal ini bertujuan untuk mengetahui kualitas minyak goreng yang digunakan oleh para pedagang gorengan. Sampel minyak goreng didapatkan dari pedagang gorengan di sepanjang Jalan Manyar Sabrangan, Mulyorejo, Surabaya. Terdapat 7 pedagang gorengan yang menjual gorengannya dengan harga sekitar Rp. 1.000 – Rp 2.000. Metode yang digunakan yaitu metode titrasi alkalimetri dan metode gravimeteri. Hasil analisa kadar asam lemak bebas dan kadar air menunjukkan bahwa dari 7 sampel terdapat 4 sampel minyak goreng yang tidak layak dikonsumsi karena tidak sesuai dengan syarat mutu minyak goreng SNI 01-3741-2002. Kata kunci: Asam Lemak Bebas, Kadar Air, Minyak Goreng, Pedagang Gorengan. ABSTRACT The requirement of palm cooking oil in Indonesia increase from year to year. It was dominated by the use of palm cooking oil as a medium to fry. Fried food on street seller was one of foods that need oil in frying process. Many street fried food seller did not pay attention to the quality of cooking oil that used to fry. Waste cooking oil was the good choice for street fried food seller in order to get big profits. Waste cooking oil contains of free fatty acids due to periodic warming that is harmful to the body. It was important for us to know the quality of cooking oil which we used. Therefore, in this research, we did test the quality of cooking oil which used street fried food seller. Free fatty acid and water content were two parameters that can describe the quality of cooking oil. The samples of cooking oil were obtained from street fried food seller along Jalan Manyar Sabrangan, Mulyorejo, Surabaya. There are 7 street seller that selling fried food with price of about Rp. 1.000 - Rp 2.000. Alkalimetry titration and gravimetery method were used to determine free fatty acid and water content of samples. The result showed there are 4 samples of cooking oil that was not worthy to be consumed because not in accordance with requirement of cooking oil quality of SNI 01-3741-2002. Key Words: Free Fatty Acid, Water Content, Cooking Oil, Street Fried Food Seller.  

scholarly journals Analisis Minyak Jelantah Sebagai Bahan Bakar Biodiesel dengan Proses Transesterifikasi

2018 ◽  
Vol 1 (1) ◽  
pp. 16 ◽  
Author(s):  
Hadrah Hadrah ◽  
Monik Kasman ◽  
Fitria Mayang Sari
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Sodium Hydroxide Solution ◽  
Quality Standard ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Cooking Oil ◽  
Used Oil ◽  
Used Cooking Oil ◽  
Biodiesel Quality

Waste cooking oil is used oil that has been used for domestic purposes and has undergone changes, both physically and chemically. One effort that can be done to reduce the adverse effects of used cooking oil is changed the material used cooking oil into biodiesel. In this study of biodiesel production from waste cooking oil is done by using biodiesel transesterification reaction as generally through a pretreatment in order to reduce the number of Free Fatty Acid in cooking oil. The high number of Free Fatty Acid will complicate the separation of glycerol from biodiesel so that production of biodiesel will be slight. Test parameters of biodiesel quality produced by  transesterification process refers to the Indonesian biodiesel quality standard ISO 7182: 2015. The production of biodiesel from used cooking oil in this experiment using variations methanol and sodium hydroxide solution ratio to the used cooking oil is 1: 2; 1: 4 and 1: 8. Test results showed that the quality of biodiesel is in compliance with ISO 7182: 2015 on the parameters of viscosity, density and flame test. While the Free Fatty Acids remained above the quality standard ISO 7182: 2015.Keywords :    Waste cooking oil, Transesterification, Biodiesel

scholarly journals ESTERIFIKASI DAN DEASIDIFIKASI MINYAK JELANTAH PADA PEMBUATAN BIODIESEL MENGGUNAKAN KATALIS ABU TONGKOL JAGUNG

Jurnal Kimia ◽  
2020 ◽  
pp. 161
Author(s):  
R. E. Y. Adu
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Free Fatty Acid ◽  
Free Fatty Acids ◽  
Volume Ratio ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Corn Cobs ◽  
Cooking Oil ◽  
Alkali Neutralization

Esterification and deacidification of waste cooking oil using alkali neutralization for biodiesel production using corncob ash as an alternative base catalyst was carried out. This study aimed to attainone of the desired transesterification conditionsby reducing free fatty acids content of waste cooking oil. Esterification was carried out by reacting waste cooking oil and methanol with certain volume ratio and acid catalyst (H2SO4) at 50oC for 4 hours. Deacidification was carried out by adding 0.5 N NaOH solution (15% excess alkali) at 60oC for 30 minutes. Esterification of waste cooking oil using acid catalyst before transesterification with corn cobs ash catalyst significantly increased the efficiency of free fatty acid conversion (92.69%) under volume ratio of 25% methanol /oil and 0.5% acid catalyst for 4 hours reaction. Deacidification of esterified oil with FFA content of 2.29 mg KOH /g oil through alkali neutralization at 55oC using alkaline content of 0.8 N reduces free fatty acid content to 0.47 mg KOH /g oil. Transesterification results showed that biodiesel component of waste cooking oil was dominated by polyunsaturated fatty acids (linoleic acid / C18-2), monounsaturated fatty acids (palmitic acid / C16-1 and oleic acid / C18-1) and saturated acids (palmitic / C16-0 and stearic acid / C18-0). Most of the biodiesel products were similar to those of the diesel physical characters. Biodiesel made of waste cooking oil meets the biodiesel quality standard (SNI 7182: 2015) for such parameters of density, viscosity, acid number, saponification value, iodine number and cetane. Esterification and neutralization process are effective in reducing free fatty acids content of waste cooking oil before being used in transesterification with corn cobs ash catalyst. Keywords: esterification, neutralization, alkali, waste cooking oil, biodiesel, corn cobs ash

scholarly journals PENGURANGAN KADAR ASAM LEMAK BEBAS (FREE FATTY ACID) DAN WARNA DARI MINYAK GORENG BEKAS DENGAN PROSES ADSORPSI MENGGUNAKAN CAMPURAN SERABUT KELAPA DAN SEKAM PADI

Konversi ◽  
2013 ◽  
Vol 2 (2) ◽  
pp. 28
Author(s):  
Chairul Irawan ◽  
Tiara Nur Awalia ◽  
Sherly Uthami W.P.H
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Rice Husk ◽  
Waste Cooking Oil ◽  
Batch Adsorption ◽  
Coconut Fiber ◽  
Cooking Oil ◽  
Magnetic Stirrer ◽  
Composition And Structure ◽  
Physical And Chemical

Penggunaan  minyak goreng yang berulang- ulang dapat merubah struktur fisik dan kimia tersebut sesuai dengan komposisi dan jenis minyak. Beberapa perubahan yang terjadi pada minyak  setelah  penggorengan yaitu perubahan  warna dan  terurainya  komponen  penyusun  minyak menjadi senyawa lain yaitu Free Fatty Acid. Penelitian ini bertujuan untuk mengetahui pengaruh pemakaian  campuran adsorben dalam mengurangi kadar FFA dan warna pada minyak jelantah. Adsorben yang digunakan berupa sekam padi dan serabut kelapa yang sudah diaktivasi. Adsorben dibuat dengan membakar masing-masing bahan yaitu sekam dan serabut kelapa dan diaktivasi menggunakan H3PO4 1 M. Adsorben yang diperoleh digunkan untuk mengadsorpsi minyak jelantah sebanyak 5, 10 dan 20% dari berat minyak dengan variasi komposisi campuran sekam dan serabut kelapa dengan perbandingan  30:70 ; 70:30 ; 50:50 ; 100:0 dan 0:100. Adsorben yang telah disiapkan dimasukkan ke dalam gelas beker yang berisi minyak jelatah kemudian dilakukan proses adsorpsi minyak menggunakan pemanas dan magnetic stirrer. Proses adsorpsi berlangsung secara batch selama 60 menit pada suhu 80oC dengan kecepatan pengadukan 100 rpm. Setelah disaring, minyak jelantah  dianalisa kadar FFA, warna, densitas dan kadar air. Hasil penelitian yang maksimum untuk kondisi yang dijalankan didapatkan dengan menggunakan berat adsorben sebanyak 20%  dari berat minyak dengan perbandingan komposisi sekam dan serabut kelapa 30:70 dengan kadar FFA 0,294% dan warna 295 PtCo dengan penurunan sebesar 57,07% serta penurunan nilai warna sebesar 37,04%.Kata kunci: adsorbsi, sekam padi, serabut kelapa, FFA, dan warna minyakCooking oils that used frequently will be destructed the physical and chemical of its composition and  structure. The treatment of waste cooking oil is challenging due to the pressure of undesirable component such as FFA and colour degradation. This research  aims are investigated  the ability of mixed adsorbent  from rice husk and coir coconut fiber to reduce FFA and colour of  waste cooking oil. The adsorbent was activated with H3PO4 1 M. This adsorben use about 5, 10, and 20% of weight waste cooking oil with composition mixing adsorbent of rice husk and coir coconut fiber 30:70 ; 70:30 ; 50:50 ; 100:0 and 0:100  have  prepared. Adsorben put into beaker glass of waste cooking oil then batch adsorption  proccess  was going on about 1 hour use heater and magnetic stirrer with mixing speed 100 rpm and temperature 80oC, then  filtered  and analyzed in order of FFA, colour, density, and water content. As the result, the best dose adsorben  for maximum reduce FFA was 20% of weight waste cooking oil with composition mixing adsorbent of rice husk and coir coconut fiber 30:70 which gave FFA was 0,294% and value of colour was 295 PtCo.The effectivity reduce for FFA was 57,07% and value of colour was 37,04%.Keywords : Adsorption, Rice Husk, Coir Coconut Fiber, FFA, and Colour

scholarly journals PENINGKATAN KUALITAS MINYAK JELANTA MENGGUNAKAN KARBON AKTIF DAN EKSTRAK PUCUK IDAT (Cratoxylum glaucum)

2018 ◽  
Vol 1 (1) ◽  
pp. 17
Author(s):  
Robby Gus Mahardika ◽  
Sito Enggiwanto ◽  
Ary Samsiar
Keyword(s):  
Fatty Acids ◽  
Activated Carbon ◽  
Free Radicals ◽  
Fatty Acid ◽  
Free Fatty Acid ◽  
Oil Quality ◽  
Waste Cooking Oil ◽  
Acid Number ◽  
Cooking Oil

Silica Waste cooking oil can be used as a soap or biodiesel. Good soaps or biodiesel should be from oils that have low levels of fatty acids and free radicals. However, waste cooking oil has high free fatty acid and free radical, it is necessary to increase the quality of waste cooking oil. One effort to improve the quality of waste cooking oil can use activated carbon as an adsorbent. Decrease in free radicals in cooking oil can use antioxidants from extract pucuk idat (Cratoxylum glaucum). This study aims to see the effect of extract pucuk idat on the process of improving the quality of waste cooking oil. The process of improvement by adding activated carbon and varying the concentration of ethanol extract pucuk idat. Activated carbon used 10% with variation of extract 0,25%; 0,5% and 0,75%. This process followed by stirring for 15 minutes at 80°C, then soaked for 3 days. Oil quality are identified by the method of determining the levels of free fatty acids and acid numbers. The results of this study indicate that extract pucuk idat in ethanol with 0,75% concentration has the lowest free fatty acid and acid number. Extract pucuk idat can improve the quality of waste cooking oil.

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