Iridium(iii) catalyzed trifluoroacetoxylation of aromatic hydrocarbons

RSC Advances ◽  
2014 ◽  
Vol 4 (67) ◽  
pp. 35639-35648 ◽  
Author(s):  
Steven M. Bischof ◽  
Brian G. Hashiguchi ◽  
Kapil S. Lokare ◽  
Niles Gunsalus ◽  
Mohammed Yousufuddin ◽  
...  
Keyword(s):  
Aromatic Hydrocarbons ◽  
Trifluoroacetic Acid ◽  
Ch Activation

A tridentate, NNC-tb (where NNC-tb = 2-(pyridin-2-yl)benzo[h]quinoline) ligated IrIII complex (NNC-tb)Ir(Ph)(4-MePy)(TFA), 11 along with analogues are very active for CH activation as evidenced by rapid catalytic H/D exchange between benzene and trifluoroacetic acid – d1 (DTFA).

Rates of protodetritiation of polycyclic aromatic hydrocarbons in trifluoroacetic acid

1970 ◽  
Vol 92 (22) ◽  
pp. 6525-6529 ◽  
Author(s):  
Andrew. Streitwieser ◽  
Adolphus. Lewis ◽  
Irving. Schwager ◽  
Richard W. Fish ◽  
Santokh. Labana
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Trifluoroacetic Acid ◽  
Polycyclic Aromatic
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