Rotating disk slurry electrodeposition of platinum at Y-zeolite/carbon Vulcan XC-72R for methanol oxidation in alkaline media

RSC Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 7637-7646 ◽  
Author(s):  
Amal Suleiman ◽  
Christian L. Menéndez ◽  
Ramón Polanco ◽  
Esteban Rosim Fachini ◽  
Yaritza Hernández-Lebrón ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Zeolite Y ◽  
Rotating Disk ◽  
Alkaline Media ◽  
Y Zeolite ◽  
Electrode Technique

Platinum was electrodeposited onto Y-zeolite and Y-zeolite (Y)/Vulcan XC-72R (V) to produce Pt/Y/V and Pt/Y catalysts using a rotating disk slurry electrode technique.

Mn-Mo-O Catalysts for Methanol Oxidation. I. Preparation and Characterization of the Catalysts

1992 ◽  
Vol 57 (12) ◽  
pp. 2529-2538 ◽  
Author(s):  
Krasimir Ivanov ◽  
Penka Litcheva ◽  
Dimitar Klissurski
Keyword(s):  
Methanol Oxidation ◽  
Solution Concentration ◽  
Alkaline Media ◽  
Acidic Media ◽  
Chemical Methods ◽  
X Ray ◽  
Ph Values ◽  
Precipitate Composition

Mn-Mo-O catalysts with a different Mo/Mn ratio have been prepared by precipitation. The precipitate composition as a function of solution concentration and pH was studied by X-ray, IR, thermal and chemical methods. Formation of manganese molybdates with MnMoO4.1.5H2O, Mn3Mo3O12.2.5H2O, and Mn3Mo4O15.4H2O composition has been supposed. It is concluded that pure MnMoO4 may be obtained in both acid and alkaline media, the pH values depending on the concentration of the initial solutions. The maximum Mo/Mn ratio in the precipitates is 1.33. The formation of pure Mn3Mo4O15.4H2O is possible in weakly acidic media. This process is favoured by increasing the concentration of initial solutions.

Ethanol: Tolerant Oxygen Reduction Reaction Catalysts in Alkaline Media

2018 ◽  
Vol 16 (2) ◽  
Author(s):  
Chakkrapong Chaiburi ◽  
Bernd Cermenek ◽  
Birgit Elvira Pichler ◽  
Christoph Grimmer ◽  
Viktor Hacker
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
State Of The Art ◽  
Rotating Disk ◽  
Reduction Reaction ◽  
Rotating Disk Electrode ◽  
Alkaline Media ◽  
Direct Ethanol Fuel Cells ◽  
X Ray ◽  
Transmission Electron

This paper describes electrocatalysts for the oxygen reduction reaction (ORR) in alkaline direct ethanol fuel cells (ADEFCs), using the non-noble metal electrocatalyst Ag/C, MnO2/C and AgMnO2/C. These electrocatalysts showed tolerance toward ethanol in alkaline media and therefore resistance to ethanol crossover in ADEFCs. Transmission electron microscopy, X-ray spectroscopy (EDX), cyclic voltammetry, and rotating disk electrode (RDE) were employed to determine the morphology, composition, and electrochemical activity of the catalysts. The herein presented results confirm that the AgMnO2/C electrocatalyst significantly outperforms the state-of-the art ORR catalyst platinum.

scholarly journals Ultra-sound assisted nano Y- zeolite /Mn adsorbent to removed sulfur from crude oil

2021 ◽  
Vol 12 (3) ◽  
pp. 5652-5657
Author(s):  
Dr.Tahseen Hameed khlaif Et. al.
Keyword(s):  
Crude Oil ◽  
Zeolite Y ◽  
Sulfur Compounds ◽  
Ultra Sound ◽  
Adsorption Efficiency ◽  
Y Zeolite ◽  
Industrial Materials ◽  
Oil Sector ◽  
Great Harm ◽  
Adsorbent Dose

There are some types of crude oil that contains large quantities of various sulfur compounds that have great harm on the environment, oil economy, oil sector facilities such as fields and refineries.So developing ways to get rid of it is one of the most important goals of researchers in this sector. In this study, nanotechnology was used for environmentally friendly and available industrial materials (nano-zeolite Y), which can adsorb sulfur from crude oil, especially when it impregnated with manganese metals with ultrasound to increase the adsorption efficiency.  The effect (temperature, adsorbent dose, Samples PH) was studied with ultrasound and without ultrasound.On the efficiency of removal had best results with ultrasound andit was found that this material is highly efficient in removing sulfur compounds, especially at a temperature of 100 C, and at a dose of 13 g, and PH 7 it found the best adsorption efficiency about 99 %. The change in the properties of the adsorbent material is almost non-existent, with a change in the surface area and pore size.

scholarly journals Sustainable Production of Hydrogen by Steam Reforming of Ethanol Using Cobalt Supported on Nanoporous Zeolitic Material

Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1934
Author(s):  
Javier Francisco da Costa-Serra ◽  
Maria Teresa Navarro ◽  
Fernando Rey ◽  
Antonio Chica
Keyword(s):  
Steam Reforming ◽  
Zeolite Y ◽  
Cobalt Catalysts ◽  
Coke Deposition ◽  
Bet Surface Area ◽  
Ethanol Conversion ◽  
Y Zeolite ◽  
Steam Reforming Of Ethanol ◽  
Production Of Hydrogen ◽  
Hydrogen Selectivity

Cobalt catalysts supported on Y zeolite and mesoporized Y zeolite (Y-mod) have been studied in steam reforming of ethanol (SRE). Specifically, the effect of the mesoporosity and the acidity of the y zeolite as a support has been explored. Mesoporous were generated on Y zeolite by treatment with NH4F and the acidity was neutralized by Na incorporation. Four cobalt catalysts supported on Y zeolite have been prepared, two using Y zeolite without mesoporous (Co/Y, Co/Y-Na), and two using Y zeolite with mesoporous (Co/Y-mod and Co/Y-mod-Na). All catalysts showed a high activity, with ethanol conversion values close to 100%. The main differences were found in the distribution of the reaction products. Co/Y and Co/Y-mod catalysts showed high selectivity to ethylene and low hydrogen production, which was explained by their high acidity. On the contrary, neutralization of the acid sites could explain the higher hydrogen selectivity and the lower ethylene yields exhibited by the Co/Y-Na and Co/Y-mod-Na. In addition, the physicochemical characterization of these catalysts by XRD, BET surface area, temperature-programmed reduction (TPR), and TEM allowed to connect the presence of mesoporous with the formation of metallic cobalt particles with small size, high dispersion, and with high interaction with the zeolitic support, explaining the high reforming activity exhibited by the co/y-mod-Na sample as well as its higher hydrogen selectivity. It has been also observed that the formation of coke is affected by the presence of mesoporous and acidity. Both properties seem to have an opposite effect on the reforming catalyst, decreasing and increasing the coke deposition, respectively.

scholarly journals Cellulose nanocrystals (CNCs) as hard templates for preparing mesoporous zeolite Y assemblies with high catalytic activity

2020 ◽  
Vol 22 (15) ◽  
pp. 5115-5122 ◽  
Author(s):  
Samer Abdulridha ◽  
Jiuxing Jiang ◽  
Shaojun Xu ◽  
Zhaoxia Zhou ◽  
He Liang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cellulose Nanocrystals ◽  
Zeolite Y ◽  
Synthesis Method ◽  
High Catalytic Activity ◽  
Mesoporous Zeolite ◽  
Y Zeolite ◽  
Directed Synthesis

Faujasite (FAU) Y zeolite assemblies with high mesoporosity (Sext = 347 m2 g−1 and Vmeso = 0.52 cm3 g−1) were synthesised using sustainable and economic cellulose nanocrystals (CNCs) via a template-directed synthesis method.

Simple synthesis of Pt-Ag/SnO2-C for use as a catalyst of methanol oxidation in alkaline media

2017 ◽  
Vol 21 (8) ◽  
pp. 2449-2456 ◽  
Author(s):  
B. Ruiz-Camacho ◽  
A. Medina-Ramírez ◽  
R. Fuentes-Ramírez ◽  
Claudia M. Gómez
Keyword(s):  
Methanol Oxidation ◽  
Simple Synthesis ◽  
Alkaline Media
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