Enhanced photocatalytic properties of biomimetic Ag/AgCl heterostructures

RSC Advances ◽  
2014 ◽  
Vol 4 (60) ◽  
pp. 31795-31798 ◽  
Author(s):  
Hongyan Hu ◽  
Zhengbo Jiao ◽  
Gongxuan Lu ◽  
Jinhua Ye ◽  
Yingpu Bi

Hierarchical Ag/AgCl hetero-structures have been fabricated in high-yield by copying the natural architecture of a branch with green leaves, and exhibit higher photocatalytic activities than Ag/AgCl nanowires, AgCl nanoparticles, Ag nanowires, and N-doped TiO2 for the degradation of organic contaminants under visible light irradiation.

2014 ◽  
Vol 955-959 ◽  
pp. 2267-2275 ◽  
Author(s):  
Rong Liu ◽  
Shi Duo Zhao ◽  
Xue Lin

Ba0.6Mg0.4TiO3 (BMT) particles with different morphologies were synthesized through hydrothermal method and their optical and photocatalytic properties were investigated. Their crystal structure and microstructures were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). XRD patterns demonstrate that the as-prepared samples are tetragonal structure. FESEM shows that BMT crystals can be fabricated in different morphologies by simply manipulating the reaction parameters of hydrothermal process. The UV-visible diffuse reflectance spectra (UV-vis DRS) reveal that the band gaps of BMT photocatalysts are about 2.37 - 2.51 eV. The as-prepared BMT photocatalysts exhibite higher photocatalytic activities in the degradation of methyl orange (MO) under visible light irradiation (λ > 420 nm) compared with traditional N-doped TiO2 (N-TiO2) and pure BaTiO3 (BTO). The high photocatalytic performance of BMT photocatalysts could be attributed to the recombination restraint of the e-/h+ pairs resulting from doping of Mg2+ ions. The influence of morphologies upon the photocatalytic properties of BMT was studied. Furthermore, BMT nanowires reveal the highest photocatalytic activity. Up to 94.0% MO is decolorized after visible light irradiation for 360 min.


CrystEngComm ◽  
2016 ◽  
Vol 18 (3) ◽  
pp. 427-436 ◽  
Author(s):  
Xiao-Wu Lei ◽  
Cheng-Yang Yue ◽  
Li-Juan Feng ◽  
Yong-Fang Han ◽  
Rong-Rong Meng ◽  
...  

Four new hybrid iodoargentates have been solvothermally prepared and structurally characterized. The title compounds possess semiconductor characterizations and efficient photocatalytic activities under visible light irradiation.


RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103289-103295 ◽  
Author(s):  
Yonggang Hu ◽  
Hong Zheng ◽  
Tongzhou Xu ◽  
Ning Xu ◽  
Hongwen Ma

Ag6Si2O7/WO3 (1 : 1) heterojunction photocatalyst shows highly efficient and significant potential for photocatalytic degradation of organic contaminants under visible light irradiation.


2015 ◽  
Vol 51 (30) ◽  
pp. 6655-6658 ◽  
Author(s):  
Ying Ma ◽  
Yulong Jia ◽  
Zhengbo Jiao ◽  
Min Yang ◽  
Yanxing Qi ◽  
...  

We demonstrate a simple and effective strategy for rationally fabricating one-dimensional (1D) Bi2MoO6 nanosheet-built frameworks, which exhibit much higher photocatalytic performances than conventional Bi2MoO6 nanoplates and nanoparticles for the degradation of organic contaminants under visible light irradiation.


RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.


2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Xiangchao Meng ◽  
Zisheng Zhang

In photocatalysis, the recombination of electron-hole pairs is generally regarded as one of its most serious drawbacks. The synthesis of various composites with heterojunction structures has increasingly shed light on preventing this recombination. In this work, a BiOBr-Bi2WO6photocatalytic heterojunction semiconductor was synthesized by the facile hydrothermal method and applied in the photocatalytic degradation process. It was determined that both reaction time and temperature significantly affected the crystal structure and morphologies of the photocatalysts. BiOBr (50 at%)-Bi2WO6composites were prepared under optimum synthesis conditions (120°C for 6 h) and by theoretically analyzing the DRS results, it was determined that they possessed the suitable band gap (2.61 eV) to be stimulated by visible-light irradiation. The photocatalytic activities of the as-prepared photocatalysts were evaluated by the degradation ofRhodamine B (RhB)under visible-light irradiation. The experimental conditions, including initial concentration, pH, and catalyst dosage, were explored and the photocatalysts in this system were proven stable enough to be reused for several runs. Moreover, the interpreted mechanism of the heterojunction enhancement effect proved that the synthesis of a heterojunction structure provided an effective method to decrease the recombination rate of the electron-hole pairs, thereby improving the photocatalytic activity.


2021 ◽  
pp. 122235
Author(s):  
Diana G. Fukina ◽  
Andrey V. Koryagin ◽  
Aleksandra V. Koroleva ◽  
Evgeny V. Zhizhin ◽  
Eugeny V. Suleimanov ◽  
...  

2021 ◽  
Author(s):  
Jingjing Xu ◽  
Yang liu ◽  
xueping li ◽  
Mindong Chen

Direct Z-scheme Bi3TaO7/Zn0.5Cd0.5S composite photocatalysts were successfully prepared via an in-situ growth hydrothermal method. The photocatalytic activities of composites were investigated by the degradation of levofloxacin under visible light. And...


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