scholarly journals Palladium(ii) complexes with chiral organoantimony(iii) ligands. Solution behaviour and solid state structures

RSC Advances ◽  
2014 ◽  
Vol 4 (51) ◽  
pp. 26569-26576 ◽  
Author(s):  
Dana Copolovici ◽  
Francesco Isaia ◽  
Hans J. Breunig ◽  
Ciprian I. Raţ ◽  
Cristian Silvestru
Keyword(s):  
Solid State ◽  
Chelating Ligand ◽  
Solid State Structures ◽  
Solution Behaviour

The stibines R(Ph)SbCl (1) and R(Mes)2Sb (2) (R = 2-Me2NCH2C6H4) were used to obtain [Me2NHCH2C6H5]+[PdCl3{SbCl(Ph)R}]¬ (3) and [PdCl2{Sb(Mes)2R-N,Sb}] (4). While in 3 the intramolecular N→Sb interaction is preserved, in compound 4 the stibine 2 acts as a (N,Sb)-chelating ligand.

scholarly journals Synthesis, Solid-state Structures, Solution Behaviour and Catalysis Studies of Nickel Complexes of Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligands

2012 ◽  
Vol 65 (7) ◽  
pp. 823 ◽  
Author(s):  
Karen D. M. MaGee ◽  
Guy Travers ◽  
Brian W. Skelton ◽  
Massimilliano Massi ◽  
Alan D. Payne ◽  
...  
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Nickel Complexes ◽  
Pincer Ligands ◽  
X Ray Diffraction ◽  
Nmr Studies ◽  
X Ray ◽  
Solution Studies ◽  
Solid State Structures ◽  
Solution Behaviour

N-Heterocyclic carbene–nickel complexes with five- and four-coordinate geometries [(CNC)NiBr2] and [(CNC)NiBr]X (X = PF6 or BPh4) have been prepared with the pincer ligands 2,6-bis(N-octylbenzimidazolin-2-ylidene)pyridine and 2,6-bis(N-butyl-5,6-dimethoxybenzimidazolin-2-ylidene)pyridine. The addition of the n-octyl substituent significantly extends the solubility of the complexes and has allowed UV-vis solution studies of the complexes in dichloromethane and methanol. The four- and five-coordinate species exist in equilibrium in solution and this equilibrium has been explored by UV-vis studies. The complexes have also been characterized by NMR studies, and single crystal X-ray diffraction studies have been performed on [(CNC)NiBr2] (where CNC = 2,6-bis(N-octylbenzimidazolin-2-ylidene)pyridine) and [(CNC)NiBr]BPh4 (where CNC = 2,6-bis(N-butyl-5,6-dimethoxybenzimidazolin-2-ylidene)pyridine).

New chiral organoantimony(iii) compounds containing intramolecular N → Sb interactions – solution behaviour and solid state structures

2010 ◽  
Vol 39 (28) ◽  
pp. 6410 ◽  
Author(s):  
Dana Copolovici ◽  
Vilma R. Bojan ◽  
Ciprian I. Raţ ◽  
Anca Silvestru ◽  
Hans J. Breunig ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Structures ◽  
Solution Behaviour

Synthesis and solid state structures of macromolecular cylindrical brushes with varying side chain length

Polymer ◽  
2004 ◽  
Vol 45 (12) ◽  
pp. 4009-4015 ◽  
Author(s):  
Bin Zhang ◽  
Shanju Zhang ◽  
Lidia Okrasa ◽  
Tadeusz Pakula ◽  
Tim Stephan ◽  
...  
Keyword(s):  
Solid State ◽  
Chain Length ◽  
Side Chain ◽  
Side Chain Length ◽  
Solid State Structures

Intramolecular London Dispersion Interaction Effects on Gas-Phase and Solid-State Structures of Diamondoid Dimers

2017 ◽  
Vol 139 (46) ◽  
pp. 16696-16707 ◽  
Author(s):  
Andrey A. Fokin ◽  
Tatyana S. Zhuk ◽  
Sebastian Blomeyer ◽  
Cristóbal Pérez ◽  
Lesya V. Chernish ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Interaction Effects ◽  
Dispersion Interaction ◽  
London Dispersion ◽  
Solid State Structures
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