Investigation of the light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co2Fe2] complex by X-ray diffraction and absorption measurements

2014 ◽  
Vol 1 (7) ◽  
pp. 540-543 ◽  
Author(s):  
Yoshihiro Sekine ◽  
Masayuki Nihei ◽  
Reiji Kumai ◽  
Hironori Nakao ◽  
Youichi Murakami ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Crystal ◽  
Spin Transition ◽  
X Ray Diffraction ◽  
Tetranuclear Complex ◽  
X Ray ◽  
Absorption Measurements

The light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co2Fe2] tetranuclear complex has been investigated by single-crystal X-ray diffraction and absorption measurements.

scholarly journals A New Non-Centrosymmetricorganotin (IV) Hybrid Compound C5H14N2 [SnCl6] 2H2O: Crystal Structure And Optical Study Characterization

2021 ◽  
Author(s):  
Nejeh Hannachi ◽  
Thierry ROISNEL ◽  
Faouzi HLEL
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Optical Band Gap ◽  
X Ray Diffraction ◽  
Absorption Bands ◽  
Hybrid Compound ◽  
Visible Absorption ◽  
X Ray ◽  
Uv Visible ◽  
Absorption Measurements

Abstract A new non-centrosymmetricorganotin (IV) hybrid compoundC5H14N2 [SnCl6] 2H2O was determined by single crystal X-ray diffraction at 150(2) K. Its crystal structure was solved by single crystal X-ray diffraction reveling that compound crystallizes in the orthorhombic system with Pbca space group with the following lattice parameters: a = 12.1486 (15) Å, b= 15.4571 (17) Å, c = 16.7610 (18) Å with Z = 8. The bonding between inorganic and organic entities in the compounds is realized by hydrogen bonding O−H…O ,O−H…Cl , NH • • • Cl, N-H…Cl and O−H…Cl. Finally,UV-visible absorption measurements exhibit two absorption bands (226 nm and 262 nm).The optical band gap (Eg) is deduced to be 3.46 Ev.

Macrocyclic tetrakis-phosphines and their copper(I) complexes

2017 ◽  
Vol 89 (3) ◽  
pp. 331-339 ◽  
Author(s):  
Elvira I. Musina ◽  
Tatiana I. Wittmann ◽  
Alexey B. Dobrynin ◽  
Peter Lönnecke ◽  
Evamarie Hey-Hawkins ◽  
...  
Keyword(s):  
Single Crystal ◽  
Phosphine Ligands ◽  
X Ray Diffraction ◽  
Tetranuclear Complex ◽  
X Ray

AbstractA series of mono-, di- and tetranuclear copper(I) complexes with macrocyclic 14-, 16-, 18- and 20-membered tetrakis-phosphine ligands (P4N2) was obtained and fully characterized including single crystal X-ray diffraction. The 14-membered P4N2 macrocycles form very stable cationic mononuclear tetraphospha-coordinated copper(I) complexes, whereas their higher 16-, 18- and 20-membered homologues give neutral dinuclear [Cu2I2L] complexes under the same conditions. An unusual tetranuclear complex with two three- and two four-coordinated copper(I) atoms was obtained from 16-PMes4NCH2CH2Py-22 and copper(I) iodide. This is the first example of N-coordination of cyclic aminomethylphosphines towards “soft” copper(I).

Electron Microscopy of Shock Loaded Polycrystalline Beryllium

1974 ◽  
Vol 32 ◽  
pp. 506-507 ◽  
Author(s):  
J. M. Galbraith ◽  
L. E. Murr ◽  
A. L. Stevens
Keyword(s):  
Electron Microscopy ◽  
Wave Propagation ◽  
Structural Change ◽  
Single Crystal ◽  
Diffraction Pattern ◽  
Shock Loading ◽  
Slip Systems ◽  
Compression Tests ◽  
X Ray Diffraction ◽  
X Ray

Uniaxial compression tests and hydrostatic tests at pressures up to 27 kbars have been performed to determine operating slip systems in single crystal and polycrystal1ine beryllium. A recent study has been made of wave propagation in single crystal beryllium by shock loading to selectively activate various slip systems, and this has been followed by a study of wave propagation and spallation in textured, polycrystal1ine beryllium. An alteration in the X-ray diffraction pattern has been noted after shock loading, but this alteration has not yet been correlated with any structural change occurring during shock loading of polycrystal1ine beryllium.This study is being conducted in an effort to characterize the effects of shock loading on textured, polycrystal1ine beryllium. Samples were fabricated from a billet of Kawecki-Berylco hot pressed HP-10 beryllium.

Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(–)-1-phenyl-ethyl ammonium percholorate

2003 ◽  
Vol 218 (5) ◽  
Author(s):  
Süheyla Özbey ◽  
F. B. Kaynak ◽  
M. Toğrul ◽  
N. Demirel ◽  
H. Hoşgören
Keyword(s):  
Crystal Structure ◽  
Inclusion Complex ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
New Type

AbstractA new type of inclusion complex, S(–)-1 phenyl ethyl ammonium percholorate complex of R-(–)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group

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