Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes
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We report two (3,12)-connected complexes with distorted cubic [Ln4O4] (Ln = Gd (1), Dy (2)) units as nodes bridged by in situ generated sulfate. 1 features a large magnetocaloric effect with −ΔSmaxm = 51.29 J kg−1 K−1, and 2 displays slow magnetic relaxation behavior.
2012 ◽
Vol 18
(47)
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pp. 15086-15091
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2018 ◽
Vol 536
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pp. 401-404
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