Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes

2014 ◽  
Vol 1 (7) ◽  
pp. 549-552 ◽  
Author(s):  
Song-De Han ◽  
Xiao-Hong Miao ◽  
Sui-Jun Liu ◽  
Xian-He Bu

We report two (3,12)-connected complexes with distorted cubic [Ln4O4] (Ln = Gd (1), Dy (2)) units as nodes bridged by in situ generated sulfate. 1 features a large magnetocaloric effect with −ΔSmaxm = 51.29 J kg−1 K−1, and 2 displays slow magnetic relaxation behavior.

2019 ◽  
Vol 48 (4) ◽  
pp. 1392-1403 ◽  
Author(s):  
Dong-Fang Wu ◽  
Zhen Liu ◽  
Peng Ren ◽  
Xiao-He Liu ◽  
Ning Wang ◽  
...  

Gd/Dy complexes based on 8-hydroxiquinoline derivatives display a magnetocaloric effect and slow magnetic relaxation behavior.


2020 ◽  
Vol 44 (41) ◽  
pp. 18025-18030
Author(s):  
Wen-Min Wang ◽  
Cai-Long Xue ◽  
Ru-Yi Jing ◽  
Xin Ma ◽  
Lu-Na Yang ◽  
...  

Two novel hexanuclear lanthanide clusters (1 and 2) were successfully prepared. Magnetic investigations reveal that 1 exhibits remarkable magnetocaloric effect and 2 displays interesting slow magnetic relaxation behaviors.


2017 ◽  
Vol 46 (30) ◽  
pp. 10023-10028 ◽  
Author(s):  
Song-De Han ◽  
Jin-Hua Li ◽  
Hao-Hao Liu ◽  
Guo-Ming Wang

We report two isostructural lanthanide hybrid complexes. The Gd-compound exhibits a large magnetocaloric effect with −ΔSmaxm = 51.29 J kg−1 K−1, and the Dy-compound displays slow magnetic relaxation.


Polyhedron ◽  
2019 ◽  
Vol 157 ◽  
pp. 292-296
Author(s):  
Ying Shi ◽  
Ya-Xin Zhang ◽  
Meng Li ◽  
Yue-Hua Zhang ◽  
Bi-Ying Liu ◽  
...  

2018 ◽  
Vol 536 ◽  
pp. 401-404 ◽  
Author(s):  
V. Tkáč ◽  
R. Tarasenko ◽  
A. Orendáčová ◽  
M. Orendáč ◽  
V. Sechovský ◽  
...  

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