Synthesis of well-defined α,ω-telechelic multiblock copolymers in aqueous medium: in situ generation of α,ω-diols

2015 ◽  
Vol 6 (12) ◽  
pp. 2226-2233 ◽  
Author(s):  
Alexandre Simula ◽  
Vasiliki Nikolaou ◽  
Athina Anastasaki ◽  
Fehaid Alsubaie ◽  
Gabit Nurumbetov ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Multiblock Copolymers ◽  
In Situ Generation

The synthesis of well-defined α,ω-dihydroxyl telechelic multiblock copolymers by sequential in situ chain extensions via aqueous Cu(0) mediated living radical polymerization (SET-LRP) is reported.

scholarly journals Correction: Synthesis of well-defined α,ω-telechelic multiblock copolymers in aqueous medium: in situ generation of α,ω-diols

2017 ◽  
Vol 8 (47) ◽  
pp. 7416-7416 ◽  
Author(s):  
Alexandre Simula ◽  
Vasiliki Nikolaou ◽  
Athina Anastasaki ◽  
Fehaid Alsubaie ◽  
Gabit Nurumbetov ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Multiblock Copolymers ◽  
In Situ Generation

Correction for ‘Synthesis of well-defined α,ω-telechelic multiblock copolymers in aqueous medium: in situ generation of α,ω-diols’ by Alexandre Simula et al., Polym. Chem., 2015, 6, 2226–2233.

Visible-light-induced living radical polymerization using in situ bromine-iodine transformation as an internal boost

2017 ◽  
Vol 8 (16) ◽  
pp. 2538-2551 ◽  
Author(s):  
Xiaodong Liu ◽  
Qinghua Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization

A new visible-light-induced methodology, termed as “bromine-iodine transformation activated living radical polymerization”, was successfully established to build a “bridge” between ATRP and iodine-mediated LRP techniques.

Cationic quaternary ammonium salt-catalyzed LED-induced living radical polymerization with in situ halogen exchange

2020 ◽  
Vol 11 (23) ◽  
pp. 3876-3883
Author(s):  
Feifei Li ◽  
Wanting Yang ◽  
Mengmeng Li ◽  
Lin Zhou ◽  
Lin Lei
Keyword(s):  
Radical Polymerization ◽  
Quaternary Ammonium ◽  
Light Emitting Diode ◽  
Quaternary Ammonium Salts ◽  
Living Radical Polymerization ◽  
Ammonium Salts ◽  
Light Emitting ◽  
Halogen Exchange ◽  
Methacrylate Monomers

Cationic quaternary ammonium salts were employed as organocatalysts for light-emitting diode (LED)-induced living radical polymerization (LRP) with the in situ halogen exchange of methacrylate monomers.

Synthesis of fluorinated gradient copolymers via in situ transesterification with fluoroalcohols in tandem living radical polymerization

2017 ◽  
Vol 8 (15) ◽  
pp. 2299-2308 ◽  
Author(s):  
Yusuke Ogura ◽  
Takaya Terashima ◽  
Mitsuo Sawamoto
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Titanium Alkoxide ◽  
Tandem Catalysis ◽  
In Situ Transesterification ◽  
Gradient Copolymers

Fluorinated gradient copolymers were synthesized by the tandem catalysis of ruthenium-catalyzed living radical polymerization and titanium alkoxide-mediated transesterification of methyl methacrylate (MMA) with fluoroalcohols.

SET-LRP of NIPAM in water via in situ reduction of Cu(ii) to Cu(0) with NaBH4

2016 ◽  
Vol 7 (4) ◽  
pp. 933-939 ◽  
Author(s):  
Mikhail Gavrilov ◽  
Timothy J. Zerk ◽  
Paul V. Bernhardt ◽  
Virgil Percec ◽  
Michael J. Monteiro
Keyword(s):  
Electron Transfer ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Water Soluble ◽  
New Method ◽  
Single Electron Transfer ◽  
In Situ Reduction ◽  
Water Soluble Polymers ◽  
Soluble Polymers

The direct and quantitative reduction of the air-stable Cu(ii)Br2/Me6TREN to Cu(0) by NaBH4 represents a new method for the aqueous single electron transfer-living radical polymerization (SET-LRP) of water soluble polymers.

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