A double supramolecular crosslinked polymer gel exhibiting macroscale expansion and contraction behavior and multistimuli responsiveness

2015 ◽  
Vol 6 (11) ◽  
pp. 1912-1917 ◽  
Author(s):  
Xiaofan Ji ◽  
Kecheng Jie ◽  
Steven C. Zimmerman ◽  
Feihe Huang
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Gel ◽  
Crosslinked Polymer

Here we report a novel supramolecular polymer gel containing two types of physical crosslinks that are orthogonal to each other. It shows macroscale expansion and contraction behavior and multistimuli responsiveness.

Freeze-etch TEM of aqueous polymer gel network morphology

1986 ◽  
Vol 44 ◽  
pp. 796-797
Author(s):  
J. A. N. Zasadzinski ◽  
R. K. Prud'homme
Keyword(s):  
Metal Ion ◽  
Polymer Network ◽  
Polymer Gels ◽  
Polymer Gel ◽  
Deformation History ◽  
Crosslinked Polymer ◽  
Aqueous Polymer ◽  
History Of ◽  
Gel Network ◽  
Network Morphology

The rheological and mechanical properties of crosslinked polymer gels arise from the structure of the gel network. In turn, the structure of the gel network results from: thermodynamically determined interactions between the polymer chain segments, the interactions of the crosslinking metal ion with the polymer, and the deformation history of the network. Interpretations of mechanical and rheological measurements on polymer gels invariably begin with a conceptual model of,the microstructure of the gel network derived from polymer kinetic theory. In the present work, we use freeze-etch replication TEM to image the polymer network morphology of titanium crosslinked hydroxypropyl guars in an attempt to directly relate macroscopic phenomena with network structure.

A novel long-alkyl-chained acylhydrazone-based supramolecular polymer gel for the ultrasensitive detection and separation of multianalytes

Soft Matter ◽  
2019 ◽  
Vol 15 (20) ◽  
pp. 4187-4191 ◽  
Author(s):  
Zhi-Yuan Yin ◽  
Jing-Han Hu ◽  
Qing-Qing Fu ◽  
Kai Gui ◽  
Ying Yao
Keyword(s):  
Polymer Material ◽  
Supramolecular Polymer ◽  
Ultrasensitive Detection ◽  
Polymer Gel ◽  
Detection And Separation

A novel supramolecular polymer material, OGV, based on long-alkyl-chained acylhydrazone was constructed. The OGV showed an ultrasensitive response for Hg2+ and Fe3+ in water by forming the metallogels HgG and FeG, which showed ultrasensitive detection and separation for CN− and H2PO4− in water, respectively.

A self-healing supramolecular polymer gel with stimuli-responsiveness constructed by crown ether based molecular recognition

2013 ◽  
Vol 4 (11) ◽  
pp. 3312 ◽  
Author(s):  
Xuzhou Yan ◽  
Donghua Xu ◽  
Jianzhuang Chen ◽  
Mingming Zhang ◽  
Bingjie Hu ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Crown Ether ◽  
Supramolecular Polymer ◽  
Self Healing ◽  
Polymer Gel

Synthesis of Copillar[5]arene by Co-oligomerization of Different Monomers and Its Application to Supramolecular Polymer Gel

2015 ◽  
Vol 33 (3) ◽  
pp. 373-378 ◽  
Author(s):  
Hui Li ◽  
Yuanrong Zhu ◽  
Bingbing Shi ◽  
Guiyuan Wu ◽  
Youming Zhang ◽  
...  
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Gel

Copillar[5]arene-based supramolecular polymer gel: controlling stimuli–response properties through a novel strategy with surfactant

RSC Advances ◽  
2015 ◽  
Vol 5 (74) ◽  
pp. 60273-60278 ◽  
Author(s):  
Taibao Wei ◽  
Hui Li ◽  
Yuanrong Zhu ◽  
Taotao Lu ◽  
Bingbing Shi ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Polymer ◽  
Polymer Gel ◽  
Response Properties ◽  
Assembly Pathway ◽  
Stimuli Response ◽  
Novel Strategy

Cartoon representation of self-assembly pathway of gelator DCP5-16 with G in CD3CN.

scholarly journals Fluorescent Metallacage-Core Supramolecular Polymer Gel Formed by Orthogonal Metal Coordination and Host–Guest Interactions

2018 ◽  
Vol 140 (24) ◽  
pp. 7674-7680 ◽  
Author(s):  
Chenjie Lu ◽  
Mingming Zhang ◽  
Danting Tang ◽  
Xuzhou Yan ◽  
ZeYuan Zhang ◽  
...  
Keyword(s):  
Metal Coordination ◽  
Supramolecular Polymer ◽  
Polymer Gel

Efficiency range of the Belousov–Zhabotinsky reaction to induce the self-organization of transient bonds in metallo-supramolecular polymeric systems

2020 ◽  
Vol 22 (26) ◽  
pp. 14965-14975
Author(s):  
Mostafa Ahmadi ◽  
Sebastian Seiffert
Keyword(s):  
The Self ◽  
Self Organization ◽  
Supramolecular Polymer ◽  
Network System ◽  
Polymer Gel ◽  
Reaction Parameters ◽  
Polymeric Systems ◽  
Chemical Oscillations ◽  
Belousov Zhabotinsky Reaction ◽  
Gel Network

Although reaction parameters offer control over chemical oscillations in a transient metallo-supramolecular polymer gel network system, this does not result in a pronounced self-organization of metallo-supramolecular bonds.

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