A novel methacrylate with a bisphosphonate group: RAFT polymerization and flame retardant property of the resultant polymers

2015 ◽  
Vol 6 (12) ◽  
pp. 2283-2289 ◽  
Author(s):  
Tianchi Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Flame Retardant ◽  
Raft Polymerization ◽  
Flame Retardant Property ◽  
Methacrylate Monomer ◽  
Flame Retardant Properties

In this work, a novel methacrylate monomer with a bisphosphonate group was synthesized and then polymerized by RAFT polymerization to obtain well-defined polymers with better thermal and flame-retardant properties.

Preparation and Properties of PA66/PP/MOS Whisker Composites

2011 ◽  
Vol 311-313 ◽  
pp. 20-25
Author(s):  
Jian Peng ◽  
You Ming Cao
Keyword(s):  
Flame Retardant ◽  
Coupling Agents ◽  
Melt Blending ◽  
Screw Extruder ◽  
Standard Samples ◽  
Scanning Calorimetry ◽  
Flame Retardant Property ◽  
Twin Screw ◽  
Magnesium Oxysulfate ◽  
Flame Retardant Properties

The composites composed of polyamide66（PA66）, polypropylene（PP）, and magnesium oxysulfate whisker(MOS) were prepared by means of melt blending through co-rotation twin screw extruder. The standard samples were prepared by injection machine. The effect of coupling agents on the whisker surface, and the influence of MOS content on mechanical properties, heat properties, flame-retardant properties and the microstructure of the composites were investigated by scanning electron microscopy(SEM), thermogravimetry(TG) and differential scanning calorimetry(DSC) techniques, respectively. The results showed that the MOS whisker modified with coupling agents KH570 possesses better activation exponential and dispersity, and the tensile strength, flexural strength and toughness of PA66/PP/MOS composite were firstly increased and then decreased with the MOS content increasing, the optimum adding amount of MOS was 25phr. The flame retardant property was improved remarkable by adding of MOS.

scholarly journals Thermal and Flame Retardant Properties of Shaped Polypropylene Fibers Containing Modified-Thai Bentonite

2018 ◽  
Vol 18 (1) ◽  
pp. 13-19 ◽  
Author(s):  
Chureerat Prahsarn ◽  
Nanjaporn Roungpaisan ◽  
Wattana Klinsukhon ◽  
Natthaphop Suwannamek ◽  
Sirada Padee
Keyword(s):  
Thermal Stability ◽  
Flame Retardant ◽  
High Thermal Stability ◽  
Hollow Fibers ◽  
Polypropylene Fibers ◽  
Cross Sectional ◽  
Flame Retardant Property ◽  
C Fibers ◽  
Flame Retardant Properties ◽  
Shaped Fibers

Abstract Tetraphenyl phosphonium-modified organoclay (TPP-Mt) was prepared by modifying montmorillonite-rich Thai bentonite via ion exchange. TGA results revealed that TPP-Mt possessed high thermal stability, where degradation occurred at a temperature range of 418-576°C. The obtained TPP-Mt/PP nanocomposites exhibited degradation at higher temperatures than PP (410-420°C vs. 403°C). Fibers of different cross-sectional shapes (circular, circular hollow, and cross) containing 1, 2 and 3%wt TPP-Mt were prepared and characterized. Nonwovens of 3%wt TPPMt/PP fibers were fabricated for flame retardant test. From results, nonwovens of TPP-Mt/PP fibers exhibited self-extinguishing characteristic and the areas of burning were less than that of PP nonwoven (14.5-31.6% vs. 95.6%). Nonwovens of cross-shaped fibers showed the best flame retardant property, followed by those of circular hollow and circular fibers. The flame retardant properties observed in nonwovens were explained due to the inter-fiber spaces between cross-shaped fibers and center hole in circular hollow fibers, which could trap initiating radicals inside, thus reducing flame propagation. In addition, large surface area in cross-shaped fibers could help in increasing the flame retardant effectiveness due to more exposure of TPP-Mt particles to the flame. Knowledge obtained in this study offered an approach to produce flame retardant nonwovens via a combination of modified organolcay and fiber shape.

Relationship between Flame-Retardant Property and Structure of Cyclomatrix Phosphazene Polymer

2006 ◽  
Vol 11-12 ◽  
pp. 395-398 ◽  
Author(s):  
Teng Zhang ◽  
Ri Guang Jin
Keyword(s):  
Thermal Properties ◽  
Flame Retardant ◽  
Structural Unit ◽  
Oxygen Index ◽  
Network Polymer ◽  
Limiting Oxygen Index ◽  
Flame Retardant Property ◽  
Nucleophilic Displacement ◽  
Pyrolysis Residue ◽  
Flame Retardant Properties

A novel phosphazene cyclomatrix network polymer was synthesized via nucleophilic displacement of activated nitro groups of tri(4-nitrophenoxy)tri(phenoxy) cyclotriphosphazene with the hydroxyls of bisphenol A. Then, thermal properties of the polymer was investigated using dynamic thermogravimetric analysis (TGA) in air, pyrolysis and combustion experiments. According to the relation among the pyrolysis residue (CR) at 850°C, the char-forming tendency (CFT) of every structural unit in polymer and the limiting oxygen index (LOI), CFT of the structural unit (-P=N-)3 and the LOI of the polymer were calculated as 35.04 and 34.3 respectively, which provided theoretical parameter for designing the cyclomatrix- or cyclo- phosphazene polymers with highly thermal and flame-retardant properties.

scholarly journals Flame resistant cellulosic substrate using banana pseudostem sap

2015 ◽  
Vol 17 (1) ◽  
pp. 123-133 ◽  
Author(s):  
S. Basak ◽  
Kartick. K. Samanta ◽  
S. Saxena ◽  
S.K. Chattopadhyay ◽  
R. Narkar ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Oxygen Index ◽  
Propagation Rate ◽  
Cotton Fabrics ◽  
Limiting Oxygen Index ◽  
Flame Retardant Property ◽  
Flammability Test ◽  
Flame Retardant Properties ◽  
Mechanical Strengths

Abstract Flame retardancy was imparted in cellulosic cotton textile using banana pseudostem sap (BPS), an eco-friendly natural product. The extracted sap was made alkaline and applied in pre-mordanted bleached and mercerized cotton fabrics. Flame retardant properties of both the control and the treated fabrics were analysed in terms of limiting oxygen index (LOI), horizontal and vertical flammability. Fabrics treated with the non-diluted BPS were found to have good flame retardant property with LOI of 30 compared to the control fabric with LOI of 18, i.e., an increase of 1.6 times. In the vertical flammability test, the BPS treated fabric showed flame for a few seconds and then, got extinguished. In the horizontal flammability test, the treated fabric showed no flame, but was burning only with an afterglow with a propagation rate of 7.5 mm/min, which was almost 10 times lower than that noted with the control fabric. The thermal degradation and the pyrolysis of the fabric samples were studied using a thermogravimetric analysis (TGA), and the chemical composition by FTIR, SEM and EDX, besides the pure BPS being characterized by EDX and mass spectroscopy. The fabric after the treatment was found to produce stable natural khaki colour, and there was no significant degradation in mechanical strengths. Based on the results, the mechanism of imparting flame retardancy to cellulosic textile and the formation of natural colour on it using the proposed BPS treatment have been postulated.

Synergistic Effect and Flame-retardant Properties of Small Molecular Organic Amines and Phosphates

2021 ◽  
Author(s):  
Xin Chen ◽  
Junkang Guo ◽  
Limei Ren ◽  
Shenyong Ren ◽  
Baojian Shen ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Flame Retardant ◽  
Flame Retardant Properties ◽  
Organic Amines

Oxa-Michael polyaddition of vinylsulfonylethanol for aliphatic polyethersulfones

2021 ◽  
Author(s):  
Nicole Ziegenbalg ◽  
Ruth Lohwasser ◽  
Giovanni D’Andola ◽  
Torben Adermann ◽  
Johannes Christopher Brendel
Keyword(s):  
Refractive Index ◽  
High Temperature ◽  
Flame Retardant ◽  
Chemical Resistance ◽  
High Refractive Index ◽  
Industrial Applications ◽  
Interesting Class ◽  
The Common ◽  
Flame Retardant Properties

Polyethersulfones are an interesting class of polymers for industrial applications due to their unusual properties such as a high refractive index, flame-retardant properties, high temperature and chemical resistance. The common...

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