Diindenocarbazole-based large bandgap copolymers for high-performance organic solar cells with large open circuit voltages

2014 ◽  
Vol 5 (23) ◽  
pp. 6847-6856 ◽  
Author(s):  
Lixin Wang ◽  
Dongdong Cai ◽  
Zhigang Yin ◽  
Changquan Tang ◽  
Shan-Ci Chen ◽  
...  

Diindenocarbazole-based large bandgap copolymers exhibit a power conversion efficiency of 7.26% with a high open-circuit voltage of 0.93 V.

2018 ◽  
Vol 54 (76) ◽  
pp. 10770-10773 ◽  
Author(s):  
Jianfeng Li ◽  
Jing Yang ◽  
Junyi Hu ◽  
You Chen ◽  
Bo Xiao ◽  
...  

The first thieno[3,4-b]pyrazine (TP) based non-fullerene acceptor was designed and synthesized, which could realize a moderate power conversion efficiency (PCE) of 5.81% with a high open-circuit voltage (Voc) of 1.05 V by using J61 as a donor polymer.


2017 ◽  
Vol 5 (44) ◽  
pp. 23067-23077 ◽  
Author(s):  
Keisuke Ogumi ◽  
Takafumi Nakagawa ◽  
Hiroshi Okada ◽  
Ryohei Sakai ◽  
Huan Wang ◽  
...  

Acceptor–donor–acceptor conjugated magnesium porphyrins showed a power conversion efficiency of 5.73%, high open-circuit voltage of 0.79 V, or an extended incident photon-to-current conversion efficiency spectrum to 1100 nm, depending on the substituents.


2017 ◽  
Vol 1 (4) ◽  
pp. 749-756 ◽  
Author(s):  
Chen Zhang ◽  
Tao Liu ◽  
Weixuan Zeng ◽  
Dongjun Xie ◽  
Zhenghui Luo ◽  
...  

Two new thienobenzene-fused perylene bisimide dimers were designed and synthesized as non-fullerene acceptors with good device performances.


2015 ◽  
Vol 17 (40) ◽  
pp. 26580-26588 ◽  
Author(s):  
Thaksen Jadhav ◽  
Rajneesh Misra ◽  
S. Biswas ◽  
Ganesh D. Sharma

The power conversion efficiency of an optimized3a:PC71BM active layer based device is 5.05%.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenrong Jia ◽  
Shucheng Qin ◽  
Lei Meng ◽  
Qing Ma ◽  
Indunil Angunawela ◽  
...  

AbstractTandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.


1981 ◽  
Vol 59 (6) ◽  
pp. 727-732 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Cheng-Kuo Hsiao

The effect of temperature on the photovoltaic properties of indium/metal-free phthalocyanine Schottky barrier solar cells was investigated in the range 260–350 K. In general, the short circuit photocurrent, Jsc, and fill factor, ff, increased with increasing temperature (in contrast to inorganic photocells). The device series resistance and open circuit photovoltage, Voc, decreased (similar to inorganic photocells) as temperature was raised. An increase in the overall power conversion efficiency, η, has been observed with increase of temperature. In the case of x-H2Pc, the power conversion efficiency increased by 2.5 times due to a temperature rise of 60 °C above ambient. Thus, for operation at temperatures above ambient, organic solar cells may offer a significant advantage over inorganic cells.Analysis of the variation of the photovoltage with temperature showed that the decrease in Voc is mainly due to variation injunction impedance, which is controlled by thermionic current at high temperature and ionized impurity at low temperature.


2020 ◽  
Vol 8 (44) ◽  
pp. 23239-23247
Author(s):  
Andy Man Hong Cheung ◽  
Han Yu ◽  
Siwei Luo ◽  
Zhen Wang ◽  
Zhenyu Qi ◽  
...  

This is the first time alkylthio chains are employed on Y6-like NFAs to achieve organic solar cells of power conversion efficiency higher than 16%.


2019 ◽  
Vol 55 (30) ◽  
pp. 4315-4318 ◽  
Author(s):  
Shengfan Wu ◽  
Zhen Li ◽  
Jie Zhang ◽  
Tiantian Liu ◽  
Zonglong Zhu ◽  
...  

We present a strategy for suppressing the open-circuit voltage (Voc) loss of perovskite solar cells by incorporating large guanidinium cations (Gua+) into a perovskite lattice, leading to a significantly improved Voc of 1.19 V and an impressive power conversion efficiency of >21%.


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