Nano-structuring polymer/fullerene composites through the interplay of conjugated polymer crystallization, block copolymer self-assembly and complementary hydrogen bonding interactions

2015 ◽  
Vol 6 (5) ◽  
pp. 721-731 ◽  
Author(s):  
Fei Li ◽  
Kevin G. Yager ◽  
Noel M. Dawson ◽  
Ying-Bing Jiang ◽  
Kevin J. Malloy ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Block Copolymer ◽  
Supramolecular Chemistry ◽  
Self Assembly ◽  
Conjugated Polymer ◽  
Composite Nanofibers ◽  
Core Shell ◽  
Hydrogen Bonding Interactions ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Core–shell P3HT/fullerene composite nanofibers were obtained using supramolecular chemistry involving cooperative orthogonal non-covalent interactions.

scholarly journals Hybrid conjugated polymer/magnetic nanoparticle composite nanofibers through cooperative non-covalent interactions

2020 ◽  
Vol 2 (6) ◽  
pp. 2462-2470
Author(s):  
Lingyao Meng ◽  
Brad W. Watson ◽  
Yang Qin
Keyword(s):  
Conjugated Polymer ◽  
Magnetic Nanoparticle ◽  
Composite Nanofibers ◽  
Core Shell ◽  
Inorganic Hybrid ◽  
Hybrid Nanofibers ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Electronically and magnetically responsive core–shell organic–inorganic hybrid nanofibers.

scholarly journals Art, auto-mechanics, and supramolecular chemistry. A merging of hobbies and career

2016 ◽  
Vol 12 ◽  
pp. 362-376 ◽  
Author(s):  
Eric V Anslyn
Keyword(s):  
Supramolecular Chemistry ◽  
Self Assembly ◽  
Molecular Orbital Theory ◽  
High Complexity ◽  
Orbital Theory ◽  
Non Covalent Interactions ◽  
Definition Of ◽  
High Degree ◽  
Covalent Interactions ◽  
Strict Definition

While the strict definition of supramolecular chemistry is “chemistry beyond the molecule”, meaning having a focus on non-covalent interactions, the field is primarily associated with the creation of synthetic receptors and self-assembly. For synthetic ease, the receptors and assemblies routinely possess a high degree of symmetry, which lends them an aspect of aesthetic beauty. Pictures of electron orbitals similarly can be seen as akin to works of art. This similarity was an early draw for me to the fields of supramolecular chemistry and molecular orbital theory, because I grew up in a household filled with art. In addition to art, my childhood was filled with repairing and constructing mechanical entities, such as internal combustion motors, where many components work together to achieve a function. Analogously, the field of supramolecular chemistry creates systems of high complexity that achieve functions or perform tasks. Therefore, in retrospect a career in supramolecular chemistry appears to be simply an extension of childhood hobbies involving art and auto-mechanics.

Synergistic effect of hydrophobic and hydrogen bonding interaction-driven viologen–pyranine charge-transfer aggregates: adenosine monophosphate recognition

Soft Matter ◽  
2021 ◽  
Author(s):  
Redhills L. Narendran ◽  
Archita Patnaik
Keyword(s):  
Hydrogen Bonding ◽  
Charge Transfer ◽  
Self Assembly ◽  
Adenosine Monophosphate ◽  
Fine Tuning ◽  
Hydrogen Bonding Interaction ◽  
Stimuli Responsive ◽  
Bonding Interaction ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Synergy between non-covalent interactions directing and fine-tuning self-assembly of electronically and electrostatically complementary molecules in water into stimuli responsive microscale aggregates.

Controlling the supramolecular polymerization and metallogel formation of Pt(ii) complexes via delicate tuning of non-covalent interactions

2019 ◽  
Vol 10 (40) ◽  
pp. 5465-5472 ◽  
Author(s):  
Lihong Li ◽  
Na Zhou ◽  
Hao Kong ◽  
Xiaoming He
Keyword(s):  
Hydrogen Bonding ◽  
Platinum Complexes ◽  
Gel Formation ◽  
Direct Influence ◽  
Hydrogen Bonding Interactions ◽  
Non Covalent Interactions ◽  
Supramolecular Polymerization ◽  
Covalent Interactions

Direct influence of noncovalent ionic and hydrogen bonding interactions on supramolecular polymerization mechanisms and their impact on gel formation of luminescent platinum complexes have been comprehensively investigated.

Self-assembly mode and supramolecular framework of cyclopentanocucurbit[6]uril and aromatic amines

2021 ◽  
Vol 25 ◽  
Author(s):  
Jun Zheng ◽  
Yan Mei Jin ◽  
Xi Nan Yang ◽  
Lin Zhang ◽  
Dao Fa Jiang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Functional Materials ◽  
Supramolecular Interactions ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
Characterization Methods ◽  
Potential Applications ◽  
Non Covalent Interactions ◽  
Multi Level ◽  
Covalent Interactions

: Single-crystal X-ray diffraction analysis, nuclear magnetic resonance (NMR), and other characterization methods are used to characterize the complexes formed by cyclopentano-cucurbit[6]uril (abbreviated as CyP6Q[6]) as a host interacting with p-aminobenzenesulfonamide (G1), 4,4'-diaminobiphenyl (G2), and (E)-4,4'-diamino-1,2-diphenylethene (G3) as guests, respectively. The experimental results show that these three aromatic amine molecules have the same interaction mode with CyP6Q[6], interacting with its negatively electric potential portals. The supramolecular interactions include non-covalent interactions of hydrogen bonding and ion-dipole between host and guest molecules. CdCl2 acts as a structureinducing agent to form self-assemblies of multi-dimensional and multi-level supramolecular frameworks that may have potential applications in various functional materials.

Halide ion-driven self-assembly of Zn(ii) compounds derived from an asymmetrical hydrazone building block: a combined experimental and theoretical study

2016 ◽  
Vol 40 (12) ◽  
pp. 10116-10126 ◽  
Author(s):  
Ghodrat Mahmoudi ◽  
Farhad Akbari Afkhami ◽  
Himanshu Sekhar Jena ◽  
Parisa Nematollahi ◽  
Mehdi D. Esrafili ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Block ◽  
Theoretical Study ◽  
Counter Ion ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Self-assembly of Zn(ii) compounds is influenced by a counter ion and non-covalent interactions.

Mesoporous Block Copolymer Nanoparticles with Tailored Structures by Hydrogen-Bonding-Assisted Self-Assembly

2012 ◽  
Vol 24 (14) ◽  
pp. 1889-1893 ◽  
Author(s):  
Renhua Deng ◽  
Shanqin Liu ◽  
Jingyi Li ◽  
Yonggui Liao ◽  
Juan Tao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Block Copolymer ◽  
Self Assembly

Self-assembly of the sodium salts of fatty acids into limpid hydrogels through non-covalent interactions with peptides

RSC Advances ◽  
2015 ◽  
Vol 5 (76) ◽  
pp. 61719-61724 ◽  
Author(s):  
Kai Zhou ◽  
Senpei Yang ◽  
Guanghua Zhao ◽  
Yong Ning ◽  
Chuanshan Xu
Keyword(s):  
Fatty Acids ◽  
Self Assembly ◽  
High Selectivity ◽  
Sodium Salts ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Sodium salts of fatty acids (SFA) self-assemble into a limpid hydrogel in the presence of poly(α,l-lysine) with a high selectivity for the size of SFA and poly(α,l-lysine).

Carbodiimide-fueled catalytic reaction cycles to regulate supramolecular processes

2022 ◽  
Author(s):  
Patrick Schwarz ◽  
Marta Tena-Solsona ◽  
Kun Dai ◽  
Job Boekhoven
Keyword(s):  
Catalytic Reaction ◽  
Self Assembly ◽  
Non Covalent Interactions ◽  
Reaction Cycles ◽  
Covalent Interactions

Using molecular self-assembly, supramolecular chemists can create Gigadalton-structures with angstrom precision held together by non-covalent interactions. However, despite relying on the same molecular toolbox for self-assembly, these synthetic structures lack...

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