Synthesis of allylated quinolines/isoquinolines via palladium-catalyzed cyclization–allylation of azides and allyl methyl carbonate

2015 ◽  
Vol 13 (11) ◽  
pp. 3227-3235 ◽  
Author(s):  
Jiang Luo ◽  
Zhibao Huo ◽  
Jun Fu ◽  
Fangming Jin ◽  
Yoshinori Yamamoto
Keyword(s):  
Efficient Strategy ◽  
Palladium Catalyzed ◽  
One Step ◽  
Methyl Carbonate ◽  
First Time

A novel and efficient strategy for one-step synthesis of allylated quinolines and isoquinolines via palladium-catalyzed cyclization–allylation of azides and allyl methyl carbonate is developed for the first time.

Dual Nickel/Palladium-Catalyzed Reductive Cross-Coupling Reactions Between Two Phenol Derivatives

2020 ◽  
Author(s):  
Baojian Xiong ◽  
Yue Li ◽  
Yin Wei ◽  
Søren Kramer ◽  
Zhong Lian
Keyword(s):  
Functional Group ◽  
Low Cost ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Phenol Derivatives ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
One Step ◽  
Aryl Tosylates ◽  
Low Sensitivity

Cross-coupling between substrates that can be easily derived from phenols is highly attractive due to the abundance and low cost of phenols. Here, we report a dual nickel/palladium-catalyzed reductive cross-coupling between aryl tosylates and aryl triflates; both substrates can be accessed in just one step from readily available phenols. The reaction has a broad functional group tolerance and substrate scope (>60 examples). Furthermore, it displays low sensitivity to steric effects demonstrated by the synthesis of a 2,2’disubstituted biaryl and a fully substituted aryl product. The widespread presence of phenols in natural products and pharmaceuticals allow for straightforward late-stage functionalization, illustrated with examples such as Ezetimibe and tyrosine. NMR spectroscopy and DFT calculations indicate that the nickel catalyst is responsible for activating the aryl triflate, while the palladium catalyst preferentially reacts with the aryl tosylate.

scholarly journals Electrochromic Performance and Capacitor Performance of α-MoO3 Nanorods Fabricated by a One-Step Procedure

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 783
Author(s):  
Ying Duan ◽  
Chen Wang ◽  
Jian Hao ◽  
Yang Jiao ◽  
Yanchao Xu ◽  
...  
Keyword(s):  
Growth Parameters ◽  
Average Diameter ◽  
Fast Response ◽  
Cycle Stability ◽  
Electrochromic Devices ◽  
Step Procedure ◽  
One Step ◽  
Supercapacitor Performance ◽  
First Time ◽  
Prepared Nanorods

In this paper, we propose for the first time the synthesis of α-MoO3 nanorods in a one-step procedure at mild temperatures. By changing the growth parameters, the microstructure and controllable morphology of the resulting products can be customized. The average diameter of the as-prepared nanorods is about 200 nm. The electrochromic and capacitance properties of the synthesized products were studied. The results show that the electrochromic properties of α-MoO3 nanorods at 550 nm have 67% high transmission contrast, good cycle stability and fast response time. The MoO3 nanorods also exhibit a stable supercapacitor performance with 98.5% capacitance retention after 10,000 cycles. Although current density varies sequentially, the nanostructure always exhibits a stable capacitor to maintain 100%. These results indicate the as-prepared MoO3 nanorods may be good candidates for applications in electrochromic devices and supercapacitors.

One-step synthesis of well-dispersed polypyrrole copolymers under gamma-ray irradiation

2021 ◽  
Vol 12 (5) ◽  
pp. 645-649
Author(s):  
Yu Gu ◽  
Yuqing Qiao ◽  
Yusen Meng ◽  
Ming Yu ◽  
Bowu Zhang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Gamma Ray ◽  
Gamma Ray Irradiation ◽  
One Step ◽  
First Time

Herein, we report for the first time the synthesis of polypyrrole copolymers with good solvent-dispersibility under gamma-ray irradiation at room temperature in air.

The application of inexpensive and synthetic simple electrocatalyst CuFe-MoC@NG in immunosensor

The Analyst ◽  
2021 ◽  
Author(s):  
Lisha Mei ◽  
Wentang Zhao ◽  
Yiju Song ◽  
Li Zhang ◽  
Mengmeng Zhang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Precious Metal ◽  
Doped Graphene ◽  
One Step ◽  
Metal Materials ◽  
First Time

In this study, we used inexpensive and synthetic simple electrocatalysts replacement conventional precious metal materials to reduce hydrogen peroxide (H2O2). We first time developed N-doped graphene-coated CuFe@MoC using one-step calcination...

Facile one-step mechanochemical synthesis of [Cu(tu)]Cl·1/2H2O nanobelts for high-performance supercapacitor

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38527-38532 ◽  
Author(s):  
Di Guo ◽  
Hongxu Guo ◽  
Yingchang Ke ◽  
Dongfang Wang ◽  
Jianhua Chen ◽  
...  
Keyword(s):  
Mechanochemical Synthesis ◽  
Electrode Material ◽  
High Performance ◽  
Mechanochemical Process ◽  
One Step ◽  
First Time

A facile one-step mechanochemical process from CuCl2·2H2O and thiourea to fabricate novel [Cu(tu)]Cl·1/2H2O nanobelts has been observed for the first time, and the nanobelts were used as an electrode material for a supercapacitor.

scholarly journals Isolation and Identification of Vibrio cholerae causes Epidemic cholera 2007 in Iraq by Rapid Method (Immunochromatographic one step rapid visual test) and comparing it with the traditional Bacterlogical Methods

2011 ◽  
Vol 8 (1) ◽  
pp. 29-34
Author(s):  
Baghdad Science Journal
Keyword(s):  
Vibrio Cholerae ◽  
Rapid Method ◽  
Fast Method ◽  
Visual Test ◽  
Cultural Characteristics ◽  
Isolation And Identification ◽  
One Step ◽  
Anti Body ◽  
First Time ◽  
Cultural Media

This study was for searching for Cholera Bacteria serotype which causes epidemiology Cholera in the 2007 in a fast method which contains (Rapid Visual Test) (Crystal V.C.) which was used for the first time in Iraq to diagnosis of Cholera Bacteria & compared with the traditional bacteriology method. The Cholera disease is one of the most dangerous epidemiological diseases which lead to death with a percentage of (50 – 70) % in the severe cases for untreated patients . For this purpose, 100 samples of stool from the patients from a (13) hospitals in Baghdad Governorate in the period from August to the end of December. The Cholera was diagnosis in two methods, 1st method was the fast method using the nitrocellulose which is coated with anti-body of Cholera Bacteria .The results was compared with the 2nd method which depends on the cultural characteristics of the cultural media, also the bacteria was diagnosis using the biochemical inspects by the system of API 20E in addition to the using of antisera to specify serotype& sub-serotype ( Monovalent, Polyvalent(O1) . Also, the relation between the disease & the months in the year in which the disease appear was studied. The results show the ability to isolate & identifecate (78) isolate for the serotype (01) in the fast method ( Rapid Visual Test ) ( Crystal V-C ) , & after the bacteriology inspects on these (78) isolate the all isolates were belongs for Cholera Bacteria of the serotype (01) till the sub-serotype , all the (78) isolates were belongs to the sub-serotype (Inaba). The results show, the most infection was in September (36) , & October (22).

Lawyers in the Field

2002 ◽  
Vol 26 (3) ◽  
pp. 248-253
Author(s):  
Neil Hasser
Keyword(s):  
Drinking Water ◽  
Heat Waves ◽  
Heat Exhaustion ◽  
Physical Limit ◽  
One Step ◽  
First Time ◽  
Provide Drinking Water

The weather during the harvest season in Virginia can be brutal. During one of the worst heat waves in decades, with temperatures soaring above 100 degrees, we were notified about a farmworker named Juan who had died in the field. We left immediately for the camp to speak with other workers about the circumstances. The day before, the grower had been visited and warned by an official about failing to provide drinking water and cups for the workers, not the first time he had received warnings of field negligence. Even on days when water was available, access could be difficult. When the water truck would drive by, workers in the field had to quickly grab one of the vegetables they were picking, cut it in half to use as a drinking cup, and run after the water truck before it left for the adjoining field. We also learned about the implicit understanding between this man's crewleader and the workers: choosing when to take a rest on your own meant no work the following day. You would also be one step closer to being blacklisted from future employment. When Juan had finally reached his physical limit that day, he asked for some time to rest inside the bus, but it was too late. He later died at the hospital from what appeared to be the effects of heat exhaustion. It remains to be seen whether Juan's family will receive any compensation.

Preparation of a Diverse Purine-Scaffold Library via One-Step Palladium Catalyzed Cross-Coupling

Heterocycles ◽  
2013 ◽  
Vol 87 (1) ◽  
pp. 91 ◽  
Author(s):  
Tony Taldone ◽  
Danuta Zatorska ◽  
Hardik J. Patel ◽  
Weilin Sun ◽  
Maulik R. Patel ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Palladium Catalyzed ◽  
One Step

Facile, One-Step Synthesis of 5-Substituted Thieno[3,4-c]pyrrole-4,6-dione by Palladium-Catalyzed Carbonylative Amidation

2015 ◽  
Vol 2015 (16) ◽  
pp. 3430-3434 ◽  
Author(s):  
Shinichiro Fuse ◽  
Ryota Takahashi ◽  
Takashi Takahashi
Keyword(s):  
Palladium Catalyzed ◽  
One Step
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