E- or Z-Selective synthesis of 4-fluorovinyl-1,2,3-triazoles with fluorinated second-generation Julia–Kocienski reagents
2015 ◽
Vol 13
(5)
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pp. 1536-1549
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Second-generation Julia–Kocienski reagents from CuAAC reactions of α-fluoropropargyl benzothiazole sulfone with azides, react with aldehydes and ketones to give N-substituted 4-(1-fluorovinyl)triazoles. Reactions of aldehydes can be tuned towards E or Z-alkenes selectively.
1998 ◽
Vol 63
(23)
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pp. 8212-8216
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1975 ◽
Vol 40
(3)
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pp. 271-275
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