Hydroformylation of olefins and reductive carbonylation of aryl halides with syngas formed ex situ from dehydrogenative decarbonylation of hexane-1,6-diol

2015 ◽  
Vol 13 (3) ◽  
pp. 938-945 ◽  
Author(s):  
Stig Holden Christensen ◽  
Esben P. K. Olsen ◽  
Jascha Rosenbaum ◽  
Robert Madsen
Keyword(s):  
Carbon Monoxide ◽  
Molecular Hydrogen ◽  
Aryl Halides ◽  
Ex Situ ◽  
Reductive Carbonylation

Carbon monoxide and molecular hydrogen are liberated from hexane-1,6-diol in a two-chamber reactor and employed for either a hydroformylation of olefins or a reductive carbonylation of aryl halides.

Palladium-catalysed reductive carbonylation of aryl halides with iron pentacarbonyl for synthesis of aromatic aldehydes and deuterated aldehydes

2015 ◽  
Vol 29 (11) ◽  
pp. 719-724 ◽  
Author(s):  
Nasser Iranpoor ◽  
Habib Firouzabadi ◽  
Elham Etemadi-Davan ◽  
Abed Rostami ◽  
Khashayar Rajabi Moghadam
Keyword(s):  
Aromatic Aldehydes ◽  
Iron Pentacarbonyl ◽  
Aryl Halides ◽  
Reductive Carbonylation

Strahlenchemie von Alkoholen XVII

1972 ◽  
Vol 27 (1) ◽  
pp. 41-46 ◽  
Author(s):  
C. v. Sonntag
Keyword(s):  
Carbon Monoxide ◽  
Molecular Hydrogen ◽  
Reaction Scheme ◽  
Quantum Yields ◽  
Effect Of Water ◽  
Formed Hydrogen

In the 185 nm photolysis of liquid O2-free isopropanol the following products (quantum yields) are formed: hydrogen (0.75), acetone (0.72), pinacol (0.036), methane (0.046), acetaldehyde (0.04), propane (0.02β), ane (0.0023) and carbon monoxide (0.0015). A detailed reaction scheme is proposed. The major primary processes are the formation of H-atoms by homolytic scission of the O —H-bond (61 — 69%), elimination of molecular hydrogen (21%) and molecular methane (5%). Φ(Η2) is strongly decreased by adding water which does not absorb an appreciable portion of the 185 nm light in the mixtures down to 1 mole/l isopropanol (Φ(Η2) =0.21). In contrast to the strong effect of water there is no effect on Φ(Η2) by diluting isopropanol with n-hexane. From experiments with isopropanol-OD and 2-deutero-isopropanol it is tentatively concluded that H-atoms stemming from the O—H-group of the alcohol are to about 65% the precursors of the hydrogen in these mixtures.

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