Electron transfer mediation by aqueous C60 aggregates in H2O2/UV advanced oxidation of indigo carmine

Nanoscale ◽  
2014 ◽  
Vol 6 (22) ◽  
pp. 13579-13585 ◽  
Author(s):  
Ling Ge ◽  
Kyle Moor ◽  
Bo Zhang ◽  
Yiliang He ◽  
Jae-Hong Kim

C60 fullerene has long been known to exhibit favorable electron accepting and shuttling properties, but little is known about the possibility of electron transfer mediation by fullerene aggregates (nC60) in water.

2004 ◽  
Vol 4 (2-4) ◽  
pp. 137-140 ◽  
Author(s):  
D.E. Tallman ◽  
M.P. Dewald ◽  
C.K. Vang ◽  
G.G. Wallace ◽  
G.P. Bierwagen

ChemPhysChem ◽  
2012 ◽  
Vol 13 (12) ◽  
pp. 2805-2805
Author(s):  
Wiphada Hongthani ◽  
Avinash J. Patil ◽  
Stephen Mann ◽  
David J. Fermín

ChemPhysChem ◽  
2012 ◽  
Vol 13 (12) ◽  
pp. 2956-2963 ◽  
Author(s):  
Wiphada Hongthani ◽  
Avinash J. Patil ◽  
Stephen Mann ◽  
David J. Fermín

Author(s):  
Xuan-Yuan Pei ◽  
Hong-Yu Ren ◽  
Defeng Xing ◽  
Guo-Jun Xie ◽  
Guangli Cao ◽  
...  

The exploration of efficient and economical persulfate activators in persulfate-based advanced oxidation process for wastewater treatment is in urgent need. In this work, sewage sludge from wastewater treatment plant was...


Author(s):  
Jian Hu ◽  
Binbin Qian ◽  
Xiangkang Zeng ◽  
Yu Qi ◽  
Yue Liu ◽  
...  

Peroxymonosulfate-based advanced oxidation processes (PMS-AOPs) have been regarded as one of the highly promising technologies for degrading pollutants in wastewater. To achieve effective PMS-AOPs, a PMS activator with a fast...


At a modified electrode, electrocatalysis is accomplished by an immobilized redox substance acting as an electron transfer mediator between the electrode and a reaction substrate. Such mediated electrocatalysis is possible with monomolecular and multimolecular layers of the redox substance. The electron transfer mediation can assume several special forms; these are identified and experimental examples are given. The differences between electrocatalytic behaviour of monomolecular and multimolecular layers are discussed; electrocatalysis in the latter circumstance can include reaction rate elements of electrochemical charge and substrate migration through the multilayer in addition to the chemical rate. Theoretical ideas are presented that interconnect these three rate elements, to show that either all of the multilayer sites can participate in the electrocatalytic reaction, or only about the equivalent of a monolayer, depending on the relative rates of the electrochemical charge transport, the diffusion of substrate, and the chemical reaction rate.


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