“Red-to-blue” colorimetric detection of cysteine via anti-etching of silver nanoprisms

Nanoscale ◽  
2014 ◽  
Vol 6 (18) ◽  
pp. 10631-10637 ◽  
Author(s):  
Yonglong Li ◽  
Zihou Li ◽  
Yuexia Gao ◽  
An Gong ◽  
Yujie Zhang ◽  
...  

A mechanistic scheme of the AgNPR system for Cys detection is presented. In the absence of Cys, I−could attach to the corners and edges of AgNPRsviathe Ag–I bond resulting in the morphology transition from nanoprism to nanodisk. Cys can prevent I−from attaching to the AgNPRs' surface and keep the shape frozen.

2016 ◽  
Vol 8 (36) ◽  
pp. 6625-6630 ◽  
Author(s):  
Lili Zhao ◽  
Julia Wiebe ◽  
Rabia Zahoor ◽  
Sladjana Slavkovic ◽  
Brian Malile ◽  
...  

The sensitivity of the formation of plasmonic silver nanoprisms to hydrogen peroxide is explored for the colorimetric detection of catalase activity in bacteria.


2017 ◽  
Vol 9 (21) ◽  
pp. 3151-3158 ◽  
Author(s):  
Thangarasu Sasikumar ◽  
Malaichamy Ilanchelian

In this work, we have developed a simple, rapid, sensitive and selective colorimetric method for the quantitative determination of hypochlorite (ClO−) ions by using triangular silver nanoprisms (AgNPRs) as a colorimetric probe.


2021 ◽  
Vol 21 (12) ◽  
pp. 6094-6100
Author(s):  
Avneesh Mittal ◽  
Komal Gupta ◽  
Balaram Pani ◽  
Gulshan Kumar ◽  
Gopala Ram Bhadu ◽  
...  

In this article, we propose high-performance colorimetric detection of Hg+2 using silver nanoprisms. The spherical and triangular AgNPs were synthesized using varied concentration of NaBH4. Pristine AgNPs without any further modification were used for the detection of various metal ions including Hg2+, Pb2+, Cl−, Cd2+, Co2+, Cu2+, Ba2+, Pb2+, Cr3+, Cr2O2−7 , Fe2+, Fe3+ etc. AgNPs were not only selective in detecting the ions of Cl− and Hg+2 ions but also highly sensitive. Minimum detection limit was observed to be as low as 10−7 ppm for both Hg+2 and Cl−. Water samples collected from various locations detected for the presence of various heavy metals. Silver nanoprisms owing to their surface plasmon resonance exhibit highly selective tendency towards detection against Hg+2.


2015 ◽  
Vol 221 ◽  
pp. 1433-1440 ◽  
Author(s):  
Dong Wu ◽  
Hai-Feng Lu ◽  
He Xie ◽  
Juan Wu ◽  
Cheng-Ming Wang ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Pei Li ◽  
Sang Mo Lee ◽  
Hyo Yong Kim ◽  
Soohyun Kim ◽  
Steve Park ◽  
...  

AbstractWe herein described a rapid, sensitive, and selective colorimetric sensing platform for biothiols in human serum, which relies on the dual functions of biothiols as anti-etching and aggregating agent for silver nanoprisms (AgNPRs). In principle, the target biothiols that bind to the surface of AgNPRs through Ag–S covalent interactions protect the AgNPRs from being etched by chloride ion (Cl−) in human serum, thus exhibiting the blue/purple color that is indicative of AgNPRs. On the other hand, the color of AgNPRs turned to yellow in the absence of biothiols or the presence of non-sulfur-containing amino acids, indicating the formation of small silver nanoparticles (AgNPs). Importantly, we found that individual biothiols (Hcy, Cys, and GSH) exert not only the anti-etching effect, but also the aggregating effect on AgNPRs, which can be modulated by simply tuning the pH conditions, and this consequently allows for the discriminative detection of each biothiol. Based on this simple and cost-effective strategy, we successfully determined the Hcy, Cys, and GSH in human serum with high sensitivity and selectivity within 10 min, demonstrating the diagnostic capability and potential in practical applications.


Author(s):  
Fouzia Tanvir ◽  
Atif Yaqub ◽  
Shazia Tanvir ◽  
Ran An ◽  
William A. Anderson

The emission of mercury (II) from coal combustion and other industrial processes continues to be a concern and have local impact on water resources.  The detection of these ions in water with sensitive but rapid testing methods is desirable for environmental screening and fieldwork.  Nanoparticles of various chemistries have shown promise for this purpose, as they can be used in simple colorimetric analyses. Silver nanoprisms were chemically synthesized resulting in a blue reagent solution, that transitioned towards yellow and colorless solutions when exposed to Hg2+ ions at various concentrations. A rapid galvanic reduction of Hg2+ onto the nanoprism surfaces is apparently responsible for a change in shape towards spherical nanoparticles, leading to the change in color. There were no interferences by other metal ions in solution, and pH had minimal effect in the range of 6.5 to 9.8. The silver nanoprism reagent provided a detection limit of approximately 0.5 µM (100 µg/L) for mercury (II), which compares favorably with other nanoparticle-based techniques. Further optimization may reduce this detection limit.


Sign in / Sign up

Export Citation Format

Share Document