Photonic metal–organic framework composite spheres: a new kind of optical material with self-reporting molecular recognition

Nanoscale ◽  
2014 ◽  
Vol 6 (20) ◽  
pp. 11995-12001 ◽  
Author(s):  
Jiecheng Cui ◽  
Ning Gao ◽  
Chen Wang ◽  
Wei Zhu ◽  
Jian Li ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Metal Organic Framework ◽  
Colloidal Crystals ◽  
Spatial Arrangement ◽  
Optical Material ◽  
General Strategy ◽  
New Class ◽  
Metal Organic ◽  
Host Matrices ◽  
Organic Framework

By using spherical colloidal crystals as 3D-ordered host matrices, a general strategy for efficient spatial arrangement of MOF materials has been developed, affording a new class of highly tunable MOF composite spheres.

scholarly journals Quantification of gas-accessible microporosity in metal-organic framework glasses

2021 ◽  
Author(s):  
Louis Frentzel-Beyme ◽  
Pascal Kolodzeiski ◽  
Jan-Benedikt Weiß ◽  
Sebastian Henke
Keyword(s):  
Metal Organic Framework ◽  
Glassy State ◽  
Glass Network ◽  
Zeolitic Imidazolate Frameworks ◽  
Sorption Data ◽  
Design Concepts ◽  
New Class ◽  
Microporous Glass ◽  
Metal Organic ◽  
Organic Framework

Metal-organic framework (MOF) glasses are a new class of microporous glass materials with immense potential for applications ranging from gas separation to optics and solid electrolytes. Due to the inherent difficulty to determine the atomistic structure of amorphous glasses, the intrinsic structural porosity of MOF glasses is only poorly understood. In this work, the porosity features of a series of prototypical MOF glass formers from the family of zeolitic imidazolate frameworks (ZIFs) and their corresponding glasses is investigated comprehensively. CO2 gas sorption at 195 K allows to follow the evolution of microporosity when transforming from the crystalline to the glassy state of these materials. Based on these data, the pore volume and the real density of the ZIF glasses is quantified for the first time. Additional hydrocarbon sorption data (n-butane, propane and propylene) together with X-ray total scattering experiments prove that the porosity features (in particular the pore size and the pore limiting diameter) of the ZIF glasses depend on the types of organic linkers present in the glass network. This allows formulating first design principles for a targeted tuning of the intrinsic microporosity of MOF glasses. Importantly, these principles are counterintuitive and contrary to established porosity design concepts for crystalline MOFs but show similarities to strategies previously developed for porous polymers.

Functional Porphyrinic Metal‐Organic Framework as a New Class of Heterogeneous Halogen Bond Donor Catalyst

2021 ◽  
Author(s):  
Weijie Zhang ◽  
Ayman Nafady ◽  
Chuan Shan ◽  
Lukasz Wojtas ◽  
Yu-Sheng Chen ◽  
...  
Keyword(s):  
Halogen Bond ◽  
Metal Organic Framework ◽  
New Class ◽  
Metal Organic ◽  
Organic Framework

Hierarchical structuring of metal–organic framework thin-films on quartz crystal microbalance (QCM) substrates for selective adsorption applications

2015 ◽  
Vol 3 (46) ◽  
pp. 23385-23394 ◽  
Author(s):  
Suttipong Wannapaiboon ◽  
Min Tu ◽  
Kenji Sumida ◽  
Kira Khaletskaya ◽  
Shuhei Furukawa ◽  
...  
Keyword(s):  
Thin Films ◽  
Molecular Recognition ◽  
Quartz Crystal Microbalance ◽  
Quartz Crystal ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Hierarchical Structuring ◽  
Metal Organic ◽  
Organic Framework

Size selective adsorption of alcohols and molecular recognition of methanol over water are observed in the heterostructured Zn4O(3,5-dialkylcarboxypyrazolate)3 films.

Molecular separations with breathing metal–organic frameworks: modelling packed bed adsorbers

2016 ◽  
Vol 45 (10) ◽  
pp. 4416-4430 ◽  
Author(s):  
Tom R. C. Van Assche ◽  
Gino V. Baron ◽  
Joeri F. M. Denayer
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Packed Bed ◽  
Adsorption Behavior ◽  
General Strategy ◽  
Metal Organic ◽  
Column Separations ◽  
Molecular Separations ◽  
Organic Framework

This work proposes a general strategy to model the adsorption behavior of phase changing metal–organic framework (MOF) adsorbents during column separations.

Ferroelasticity in a metal–organic framework perovskite; towards a new class of multiferroics

2013 ◽  
Vol 61 (13) ◽  
pp. 4928-4938 ◽  
Author(s):  
Wei Li ◽  
Zhiying Zhang ◽  
Erica G. Bithell ◽  
Andrei S. Batsanov ◽  
Phillip T. Barton ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
New Class ◽  
Metal Organic ◽  
Organic Framework

Fabrication of Metal-Organic Framework-Containing Silica-Colloidal Crystals for Vapor Sensing

2011 ◽  
Vol 23 (38) ◽  
pp. 4449-4452 ◽  
Author(s):  
Guang Lu ◽  
Omar K. Farha ◽  
Lauren E. Kreno ◽  
Paul M. Schoenecker ◽  
Krista S. Walton ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Colloidal Crystals ◽  
Vapor Sensing ◽  
Metal Organic ◽  
Organic Framework ◽  
Silica Colloidal Crystals
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