Tris-hydroxymethylaminomethane (THAM): a novel organocatalyst for a environmentally benign synthesis of medicinally important tetrahydrobenzo[b]pyrans and pyran-annulated heterocycles

2015 ◽  
Vol 39 (6) ◽  
pp. 4452-4463 ◽  
Author(s):  
Kapil S. Pandit ◽  
Pramod V. Chavan ◽  
Uday V. Desai ◽  
Makarand A. Kulkarni ◽  
Prakash P. Wadgaonkar
Keyword(s):  
Low Cost ◽  
Environmentally Benign ◽  
Green Catalyst ◽  
Benign Synthesis

Tris-hydroxymethylaminomethane (THAM): a novel, low cost, green catalyst for the synthesis of medicinally important pyrans and pyran-annulated heterocycles.

scholarly journals Isatin Aldazines Synthesis using A Proton Exchanged Algerian Montmorillonite Clay as Acid Eco-friendly Catalyst

2019 ◽  
Vol 14 (3) ◽  
pp. 551
Author(s):  
Boumadiene Benlahreche ◽  
Assya Taleb ◽  
Mokhtar B. Lahrech ◽  
Salih Hacini
Keyword(s):  
Low Cost ◽  
Aromatic Aldehydes ◽  
Significant Loss ◽  
Montmorillonite Clay ◽  
Environmentally Benign ◽  
Conventional Heating ◽  
Second Step ◽  
Hydrazine Monohydrate ◽  
Green Catalyst ◽  
Benign Process

An efficient and easy procedure is developed for the synthesis of isatin aldazines or bis-Schiff bases of isatin, catalyzed by a proton exchanged Algerian montmorillonite clay (MMT-H+) as green catalyst. The products were obtained in two catalyzed steps under conventional heating in ethanol. Isatin-3-hydrazone obtained from the reaction of isatin with hydrazine monohydrate reacts in the second step with the appropriate aromatic aldehydes to give the desired products in good yields. The main advantages of using this protonated solid non-toxic catalyst in this synthesis are its availability and low cost, the simplicity of its use, the recycling possibilities without significant loss of its catalytic activity and its environmentally benign process. Copyright © 2019 BCREC Group. All rights reserved

scholarly journals ChCl: Gly (DESs) Promote Environmentally Benign Synthesis of Xanthene Derivatives and Their Antitubercular Activity

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3667
Author(s):  
Mashooq A. Bhat ◽  
Ahmed M. Naglah ◽  
Siddique Akber Ansari ◽  
Hanaa M. Al-Tuwajiria ◽  
Abdullah Al-Dhfyan
Keyword(s):  
Reaction Times ◽  
Antitubercular Activity ◽  
Antimycobacterial Activity ◽  
Environmentally Benign ◽  
Reaction Yield ◽  
Benign Synthesis ◽  
Xanthene Derivatives ◽  
Wide Range ◽  
Major Application

A ChCl: Gly (DESs) promoted environmentally benign method was developed for the first time using the reaction of aryl aldehydes and dimedone to give excellent yields of xanthene analogues. The major application of this present protocol is the use of green solvent, a wide range of substrate, short reaction times, ease of recovery, the recyclability of the catalyst, high reaction yield, and ChCl: Gly as an alternative catalyst and solvent. In addition to this, all the synthesized compounds were evaluated for their in vitro antimycobacterial activity against M. tuberculosis H37Ra (MTB) and M. bovis BCG strains. The compounds 3d, 3e, 3f, and 3j showed significant antitubercular activity against MTB and M. bovis strains with minimum inhibitory concentration (MIC) values of 2.5−15.10 µg/mL and 0.26–14.92 µg/mL, respectively. The compounds 3e, 3f, and 3j were found to be nontoxic against MCF-7, A549, HCT 116, and THP-1 cell lines. All the prepared compounds were confirmed by 1H NMR and 13C NMR analysis.

scholarly journals Environmentally Benign Synthesis of Tetra-Substituted Imidazoles through 4-Components Strategy Mediated by (S)-3-Methyl-1, 1-Diphenylbutane-1, 2-Diamine

2018 ◽  
Vol 10 (1) ◽  
pp. 39-50
Author(s):  
M. Rana ◽  
A. Rahman ◽  
P. K. Roy ◽  
H. N. Roy
Keyword(s):  
Cost Effectiveness ◽  
Environmentally Benign ◽  
One Pot ◽  
Benign Synthesis

(S)-3-Methyl-1, 1-diphenylbutane-1, 2-diamine has been found to be a mild and effective organocatalyst for one-pot 4-components synthesis of 1, 2, 4, 5-tetra-substituted imidazoles. The key benefits of this protocol is high yielding, cost effectiveness, easy purification and above all, environmentally benign.

scholarly journals Environmentally benign synthesis of CuInS2/ZnO heteronanorods: visible light activated photocatalysis of organic pollutant/bacteria and study of its mechanism

2017 ◽  
Vol 16 (12) ◽  
pp. 1792-1800 ◽  
Author(s):  
Minki Baek ◽  
Eun-Ju Kim ◽  
Seok Won Hong ◽  
Wooyul Kim ◽  
Kijung Yong
Keyword(s):  
Visible Light ◽  
Organic Pollutant ◽  
Organic Dye ◽  
Environmentally Benign ◽  
Controlled Experiments ◽  
Photocatalytic Mechanism ◽  
Benign Synthesis

CuInS2(CIS)/ZnO is a superb photocatalyst for organic dye and bacteria decomposition. In this paper, photocatalytic mechanism of the heterostructure is investigated through controlled experiments under various scavenging conditions.

Iron Phosphates as Cathodes of Lithium-Ion Batteries

2006 ◽  
Vol 973 ◽  
Author(s):  
Shijun Wang ◽  
M. Stanley Whittingham
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Iron Phosphate ◽  
Low Cost ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Environmentally Benign ◽  
Iron Phosphates ◽  
Electrochemical Capacity ◽  
High Theoretical Capacity ◽  
Olivine Structure

ABSTRACTThis study focusses on optimizing the parameters of the hydrothermal synthesis to produce iron phosphates for lithium ion batteries, with an emphasis on pure LiFePO4 with the olivine structure and compounds containing a higher iron:phosphate ratio. Lithium iron phosphate (LiFePO4) is a promising cathode candidate for lithium ion batteries due to its high theoretical capacity, environmentally benign and the low cost of starting materials. Well crystallized LiFePO4 can be successfully synthesized at temperatures above 150 °C. The addition of a reducing agent, such as hydrazine, is essential to minimize the oxidation of ferrous (Fe2+) to ferric (Fe3+) in the final compound. The morphology of LiFePO4 is highly dependent on the pH of the initial solution. This study also investigated the lipscombite iron phosphates of formula Fe1.33PO4OH. This compound has a log-like structure formed by Fe-O octahedral chains. The chains are partially occupied by the Fe3+ sites, and these iron atoms and some of the vacancies can be substituted by other cations. Most of the protons can be ion-exchanged for lithium, and the electrochemical capacity is much increased.

Environmentally Benign Synthesis of Bi2S3 Quantum Dot Using Microwave-Assisted Approach

2013 ◽  
Vol 13 (3) ◽  
pp. 2189-2192 ◽  
Author(s):  
Chalermchai Pilapong ◽  
Somchai Thongtem ◽  
Titipun Thongtem
Keyword(s):  
Quantum Dot ◽  
Environmentally Benign ◽  
Microwave Assisted ◽  
Benign Synthesis

scholarly journals Tris-hydroxymethylaminomethane (THAM): An efficient organocatalyst in diversity-oriented and environmentally benign synthesis of spirochromenes

2018 ◽  
Vol 21 (9) ◽  
pp. 814-821 ◽  
Author(s):  
Supriya S. Khot ◽  
Prashant V. Anbhule ◽  
Uday V. Desai ◽  
Prakash P. Wadgaonkar
Keyword(s):  
Environmentally Benign ◽  
Benign Synthesis
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