Novel lithium and sodium salts of sulfonamides and bis(sulfonyl)imides: synthesis and electrical conductivity

2014 ◽  
Vol 38 (12) ◽  
pp. 6193-6197 ◽  
Author(s):  
Vincent Morizur ◽  
Sandra Olivero ◽  
Jean Roger Desmurs ◽  
Philippe Knauth ◽  
Elisabet Duñach
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
Conductivity Measurements ◽  
Sodium Salts

Ionic conductivity measurements were performed on a series of lithium and sodium salts and conductivities of 0.20 to 0.51 mS cm−1 were obtained.

Electrical Conductivity in (Gdl-xCax)2Sn2O7±δ Pyrochlore System

1994 ◽  
Vol 369 ◽  
Author(s):  
Tae-Hwan Yu ◽  
Harry L. Tuller
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
Oxygen Vacancy ◽  
Doping Concentration ◽  
Migration Energy ◽  
Conductivity Measurements ◽  
Ca Doping ◽  
Pyrochlore Compounds ◽  
Cation Radius ◽  
High Level

AbstractElectrical conductivity measurements were performed on Gd2Sn207 as a function of temperature, P02 and Ca doping concentration. An effective frenkel constant and oxygen vacancy mobility were derived. The high level of intrinsic anion disorder found in this study is consistent with expectations based on the cation radius ratio (rA/rB) which was earlier found to be important in determining anion disorder in A2B207 pyrochlore compounds [1]. The magnitude of the ionic conductivity in Gd2Sn2O7 was found to be depressed relative to Gd2(Til-xZrx)207 based systems due to a high oxygen vacancy migration energy.

Total Body Electrical Conductivity Measurements in the Neonate

1991 ◽  
Vol 18 (3) ◽  
pp. 611-627 ◽  
Author(s):  
Marta L. Fiorotto ◽  
William J. Klish
Keyword(s):  
Electrical Conductivity ◽  
Conductivity Measurements ◽  
Total Body

Characterization of New Ionically Conducting Peo-Based Networks by Diffusion, Elasticity Modulus and Ionic Conductivity Measurements

1992 ◽  
Vol 293 ◽  
Author(s):  
Herve Cheradame ◽  
F. Desbat ◽  
P. Mercier-Niddam ◽  
S. Boileau
Keyword(s):  
Diffusion Coefficient ◽  
Ionic Conductivity ◽  
Elasticity Modulus ◽  
Sol Gel ◽  
Cation Transport ◽  
Lithium Cation ◽  
Conductivity Measurements ◽  
Conducting Materials ◽  
Diffusion Studies

AbstractIonically conducting materials containing PEO were prepared from telechelic di(methyl-diethoxy-silane) PEO, synthesized by the hydrosilylation of telechelic diallyl-PEO with methyldiethoxysilane. The network is obtained by the usual sol-gel chemistry. Then, it is filled with LiClO4 by diffusion of the salt and further drying. A comparison is made with the same kind of materials crosslinked using urethane chemistry. Diffusion studies show that the diffusion coefficient of solvent is similar for both types of materials, whilst the ionic conductivity is higher for the networks crosslinked with siloxane bonds. An experiment of diffusion of LiClO4 without solvent showed that this salt has a diffusion coefficient of the order of 2.10-8 cm2.sec-1 at 34°C. The conductivity calculated from this determination is compatible with the mechanism of lithium cation transport by the diffusion of salt molecules. Elasticity modulus measurements show that the salt aggregates are essentially located within the crosslinks at low concentration, but also in the PEO chains for salt concentrations higher than 1 mol/l.

Electrical conductivity studies on silica phases and the effects of phase transformation

2019 ◽  
Vol 104 (12) ◽  
pp. 1800-1805
Author(s):  
George M. Amulele ◽  
Anthony W. Lanati ◽  
Simon M. Clark
Keyword(s):  
Electrical Conductivity ◽  
Activation Volume ◽  
Activation Enthalpy ◽  
Hydrogen Charge ◽  
Charge Compensation ◽  
Composition Analysis ◽  
Conductivity Measurements ◽  
Pressure System ◽  
Electrical Conductivities ◽  
Silica Phases

Abstract Starting with the same sample, the electrical conductivities of quartz and coesite have been measured at pressures of 1, 6, and 8.7 GPa, respectively, over a temperature range of 373–1273 K in a multi-anvil high-pressure system. Results indicate that the electrical conductivity in quartz increases with pressure as well as when the phase change from quartz to coesite occurs, while the activation enthalpy decreases with increasing pressure. Activation enthalpies of 0.89, 0.56, and 0.46 eV, were determined at 1, 6, and 8.7 GPa, respectively, giving an activation volume of –0.052 ± 0.006 cm3/mol. FTIR and composition analysis indicate that the electrical conductivities in silica polymorphs is controlled by substitution of silicon by aluminum with hydrogen charge compensation. Comparing with electrical conductivity measurements in stishovite, reported by Yoshino et al. (2014), our results fall within the aluminum and water content extremes measured in stishovite at 12 GPa. The resulting electrical conductivity model is mapped over the magnetotelluric profile obtained through the tectonically stable Northern Australian Craton. Given their relative abundances, these results imply potentially high electrical conductivities in the crust and mantle from contributions of silica polymorphs. The main results of this paper are as follows:The electrical conductivity of silica polymorphs is determined by impedance spectroscopy up to 8.7 GPa.The activation enthalpy decreases with increasing pressure indicating a negative activation volume across the silica polymorphs.The electrical conductivity results are consistent with measurements observed in stishovite at 12 GPa.

Structure and Conductivity of Iodine-Doped C60 Thin Films

1994 ◽  
Vol 359 ◽  
Author(s):  
Jun Chen ◽  
Haiyan Zhang ◽  
Baoqiong Chen ◽  
Shaoqi Peng ◽  
Ning Ke ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Conductivity ◽  
Room Temperature ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
X Ray ◽  
Thermally Activated ◽  
Order Of Magnitude

ABSTRACTWe report here the results of our study on the properties of iodine-doped C60 thin films by IR and optical absorption, X-ray diffraction, and electrical conductivity measurements. The results show that there is no apparent structural change in the iodine-doped samples at room temperature in comparison with that of the undoped films. However, in the electrical conductivity measurements, an increase of more that one order of magnitude in the room temperature conductivity has been observed in the iodine-doped samples. In addition, while the conductivity of the undoped films shows thermally activated temperature dependence, the conductivity of the iodine-doped films was found to be constant over a fairly wide temperature range (from 20°C to 70°C) exhibiting a metallic feature.

Synthesis of New Chalcogenide Materials. The Novel One-Dimensional Semiconductor K4 Ti3 S14

1987 ◽  
Vol 97 ◽  
Author(s):  
Steven A. Sunshine ◽  
Doris Kang ◽  
James A. Ibers
Keyword(s):  
Electrical Conductivity ◽  
Solid State ◽  
Alkali Metal ◽  
The Novel ◽  
Conductivity Measurements ◽  
One Dimensional ◽  
General Utility ◽  
Solid State Materials ◽  
Chalcogenide Materials

ABSTRACTThe use of A2 Q/Q melts (A - alkali metal, Q - S or Se) for the synthesis of new one-dimensional solid-state materials is found to be of general utility and is illustrated here for the synthesis of K4 Ti3 SI4. Reaction of Ti metal with a K2 S/S melt at 375°C for 50 h affords K4 Ti3 SI4. The structure possesses one-dimensional chains of seven and eightcoordinate Ti atoms with each chain isolated from all others by surrounding K atoms. There are six S-S pairs (dave - 2.069(3) Å) so that the compound is one of TiIV and may be described as K4 [Ti3 (S)2 (S2)6]. Electrical conductivity measurements indicate that this material is a semiconductor.

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