Synthesis and characterization of new heterometallic cyanido complexes based on [Co(CN)6]3− building blocks: crystal structure of [Cu2(N-bishydeten)2Co(CN)6]·3H2O having a strong antiferromagnetic exchange

2014 ◽  
Vol 38 (11) ◽  
pp. 5402-5410 ◽  
Author(s):  
Şengül Aslan Korkmaz ◽  
Ahmet Karadağ ◽  
Yusuf Yerli ◽  
Mustafa Serkan Soylu
Keyword(s):  
Crystal Structure ◽  
Coordination Compounds ◽  
Lattice Spacing ◽  
Building Blocks ◽  
Antiferromagnetic Interaction ◽  
Synthesis And Characterization ◽  
Antiferromagnetic Exchange ◽  
Strong Antiferromagnetic Interaction

The hexacyanidocobalt(iii)-based four new coordination compounds have been synthesized and characterized by various techniques. The polymeric C2 having 148.3 Å3 lattice spacing among these complexes have shown very strong antiferromagnetic interaction.

Coordination Compounds of Some 3d-Transition Metal Ions with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)- thiosemicarbazide

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Madalina Angelusiu ◽  
Maria Negoiu ◽  
Stefania-Felicia Barbuceanu ◽  
Tudor Rosu
Keyword(s):  
Coordination Compounds ◽  
Magnetic Moments ◽  
Thermo Gravimetric Analysis ◽  
Electronic Spectroscopy ◽  
Transition Metal Ions ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
New Compounds

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

Synthesis and characterization of monomeric siloxo palladium(II) complexes: crystal structure of [Pd(tmeda)(C6F5)(OSiPh3)]

2004 ◽  
Vol 689 (11) ◽  
pp. 1872-1875 ◽  
Author(s):  
José Ruiz ◽  
Consuelo Vicente ◽  
Venancio Rodrı́guez ◽  
Natalia Cutillas ◽  
Gregorio López ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Synthesis And Characterization

Synthesis and characterization of isocyanide containing rhenium(III) complexes trans-[ReCl3(CNR)(PPh3)2] and crystal structure of trans-[ReCl3(CN-t-C4H9)(PPh3)2]

1995 ◽  
Vol 232 (1-2) ◽  
pp. 235-239 ◽  
Author(s):  
Hartmut Spies ◽  
Matthias Glaser ◽  
F.Ekkehardt Hahn ◽  
Thomas Lügger ◽  
Dieter Scheller
Keyword(s):  
Crystal Structure ◽  
Synthesis And Characterization
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