Anion influence on transformations of a nonporous 3D to porous 3D coordination polymer

2014 ◽  
Vol 38 (7) ◽  
pp. 3187-3192 ◽  
Author(s):  
Lida Hashemi ◽  
Ali Morsali ◽  
Orhan Büyükgüngor
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Solid State Reaction ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
New Strategy ◽  
Metal Organic ◽  
Organic Framework

This work is a new strategy for the preparation of a porous metal–organic framework from a nonporous coordination polymer by a solid state reaction.

Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

CrystEngComm ◽  
2012 ◽  
Vol 14 (12) ◽  
pp. 4105 ◽  
Author(s):  
Marie Savonnet ◽  
Jérôme Canivet ◽  
Serge Gambarelli ◽  
Lionel Dubois ◽  
Delphine Bazer-Bachi ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Solid-state thermal conversion of a nanoporous metal–organic framework to a nonporous coordination polymer

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 50778-50782 ◽  
Author(s):  
Fatemeh Shahangi Shirazi ◽  
Kamran Akhbari
Keyword(s):  
Solid State ◽  
Thermal Treatment ◽  
Coordination Polymer ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Thermal Conversion ◽  
Grid Network ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Organic Framework

A nanoporous metal–organic framework with pillared 2D square-grid network, converts to a nonporous three-dimensional coordination polymer of upon thermal treatment at 350 °C.

scholarly journals Solid state organic amine detection in a photochromic porous metal organic framework

2015 ◽  
Vol 6 (2) ◽  
pp. 1420-1425 ◽  
Author(s):  
Arijit Mallick ◽  
Bikash Garai ◽  
Matthew A. Addicoat ◽  
Petko St. Petkov ◽  
Thomas Heine ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Organic Amine ◽  
Metal Organic ◽  
Amine Detection ◽  
Organic Framework

A new Mg(ii) based porous metal–organic framework (MOF) has been synthesized from naphthalenediimide (NDI) chromophoric unit containing linker. This MOF (Mg–NDI) shows instant and reversible photochromism as well as solvatochromic behavior. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state.

Crystalline bilayers unzipped and rezipped: solid-state reaction cycle of a metal–organic framework with triple rearrangement of intralayer bonds

CrystEngComm ◽  
2017 ◽  
Vol 19 (22) ◽  
pp. 2987-2995 ◽  
Author(s):  
Dariusz Matoga ◽  
Kornel Roztocki ◽  
Manuel Wilke ◽  
Franziska Emmerling ◽  
Marcin Oszajca ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Metal Organic Framework ◽  
Reaction Cycle ◽  
Metal Organic ◽  
Organic Framework

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

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