scholarly journals Speciation of iron in mouse liver during development, iron deficiency, IRP2 deletion and inflammatory hepatitis

Metallomics ◽  
2015 ◽  
Vol 7 (1) ◽  
pp. 93-101 ◽  
Author(s):  
Mrinmoy Chakrabarti ◽  
Allison L. Cockrell ◽  
Jinkyu Park ◽  
Sean P. McCormick ◽  
Lora S. Lindahl ◽  
...  

Mössbauer spectroscopy was used to evaluate the Fe content of 57Fe-enriched livers during development, Fe-deficient conditions, in mice suffering from inflammatory hepatitis, and in mice lacking an iron regulatory protein.

Clay Minerals ◽  
2002 ◽  
Vol 37 (3) ◽  
pp. 517-529 ◽  
Author(s):  
S. Letaïef ◽  
B. Casal ◽  
N. Kbir-ariguib ◽  
M. Trabelsi–Ayadi ◽  
E. Ruiz-hitzky

AbstractThree raw samples of Fe-rich smectites from Gafsa (Jebels Shemsi and Hammadi, Tunisia) have been characterized by different techniques which indicate that they contain (15 – 20%) illite, probably interstratified and to a lesser extent they also contain kaolinite, calcite, quartz and Fe oxides. These samples present a relatively high Fe content (∼9%) in the <2 μm fraction. From EPR and Mössbauer spectroscopy it is deduced that Fe is mainly present as Fe(III) in the octahedral environment of smectites and also in Fe-oxyhydroxides associated with the clays. Aluminium-pillared clays have been prepared from the Na+-purified samples, and their thermal stability and acidity have been studied.


2013 ◽  
Vol 168 ◽  
pp. 1-6 ◽  
Author(s):  
Jacek Gurgul ◽  
Kazimierz Łątka ◽  
Izabela Hnat ◽  
Jacek Rynkowski ◽  
Stanislaw Dzwigaj

Clay Minerals ◽  
2008 ◽  
Vol 43 (1) ◽  
pp. 107-115 ◽  
Author(s):  
P. Komadel ◽  
A. S. Anastácio ◽  
S. Andrejkovičová ◽  
J. W. Stucki

AbstractThe clay-mineral fraction of samples from a bentonite deposit in the Zvolenská kotlina Basin (Slovakia), formed by the alteration of andesitic pyroclastics, was dominated by Fe-bearing montmorillonite of relatively low charge. The total Fe content of the samples ranged from 3.58 to 5.81 wt.% Fe. Variable-temperature Mössbauer spectroscopy revealed that structural Fe(III) in smectite accounts for 70–90% of the total Fe in the unfractionated samples. No structural Fe(II) was observed by Mössbauer spectroscopy, but a small amount was detected by wet chemical analysis. The remainder of the Fe is present in oxide and/or oxyhydroxide phases dominated by poorly ordered goethite and hematite. The hyperfine parameters of the Mössbauer spectra for the raw bentonite are consistent with structural Fe(III) in an aluminosilicate phase mixed with varying quantities of hematite, goethite and possibly maghemite. Except in the fine fraction of sample L28, the hematite failed to undergo the Morin transition, as shown by the negative values for quadrupole splitting at 298 K and 6 K.


1997 ◽  
Vol 58 (2) ◽  
pp. 361-364 ◽  
Author(s):  
I.L. KORSUNSKII ◽  
V.V. LOMONOSOV ◽  
Yu.F. PAZHIN ◽  
P.F. SAMARIN ◽  
R.S. SILAKOV

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-14-C2-16
Author(s):  
T. Toriyama ◽  
K. Saneyoshi ◽  
K. Hisatake

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-534-C6-534
Author(s):  
J. H. HOLLOWAY ◽  
G. J. SCHROBILGEN ◽  
S. BUKSHPAN ◽  
W. HILBRANTS ◽  
H. DE WAARD

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