Neodymium isotope ratio measurements by LC-MC-ICPMS for nuclear applications: investigation of isotopic fractionation and mass bias correction

2015 ◽  
Vol 30 (2) ◽  
pp. 443-452 ◽  
Author(s):  
Florence Guéguen ◽  
Hélène Isnard ◽  
Anthony Nonell ◽  
Laurent Vio ◽  
Thomas Vercouter ◽  
...  
Keyword(s):  
Bias Correction ◽  
Isotope Ratio ◽  
Isotopic Fractionation ◽  
Chromatographic Column ◽  
Time Lags ◽  
Faraday Cup ◽  
Mass Bias ◽  
Mass Dependent ◽  
Nuclear Applications ◽  
Isotope Ratio Measurements

The causes of isotope ratio drifts observed in LC-MC-ICPMS experiments could be explained by both mass dependent isotopic fractionation on the chromatographic column and distinct time lags between amplifier responses of the Faraday cup configuration.

Precise Mo isotope ratio measurements of low-Mo (ng g−1) geological samples using MC-ICP-MS

2016 ◽  
Vol 31 (6) ◽  
pp. 1287-1297 ◽  
Author(s):  
Jie Liu ◽  
Hanjie Wen ◽  
Yuxu Zhang ◽  
Haifeng Fan ◽  
Chuanwei Zhu
Keyword(s):  
Bias Correction ◽  
Isotope Ratio ◽  
Geological Samples ◽  
Mass Bias ◽  
Geological Processes ◽  
Icp Ms ◽  
Wide Range ◽  
Isotope Ratio Measurements

The double-spike (DS) mass bias correction approach was the method of choice for geological samples with <0.5 μg g−1 Mo; both the double-spike and the sample-standard bracketing (SSB) approaches could be applied for samples with >0.5 μg g−1 Mo. This method provided a wide range of applications for most Mo reservoirs in geological processes.

Use of Zr for mass bias correction in strontium isotope ratio determinations using MC-ICP-MS

2008 ◽  
Vol 23 (9) ◽  
pp. 1269 ◽  
Author(s):  
Lu Yang ◽  
Charlotte Peter ◽  
Ulrich Panne ◽  
Ralph E. Sturgeon
Keyword(s):  
Bias Correction ◽  
Isotope Ratio ◽  
Strontium Isotope ◽  
Mass Bias ◽  
Strontium Isotope Ratio ◽  
Icp Ms

Innovative Detection Strategies on Large Geometry SIMS open new challenging applications for light isotope ratio analyses

2020 ◽  
Author(s):  
Paula Peres ◽  
Emilie Thomassot ◽  
Etienne Deloule ◽  
Nordine Bouden ◽  
Firmino Fernandes
Keyword(s):  
Isotope Ratio ◽  
Pulse Counting ◽  
Faraday Cup ◽  
Mass Independent Fractionation ◽  
Mass Fractionation ◽  
Full Separation ◽  
Mass Dependent ◽  
Instrumental Mass Fractionation ◽  
Signal Intensities ◽  
Better Than

&lt;p&gt;Large Geometry Secondary Ion Mass Spectrometry (LG-SIMS), operating in multicollection mode, allows high precision light isotope ratio measurements at high lateral resolution (tens of &amp;#956;m down to sub-&amp;#956;m range). For some challenging applications involving fine scale analysis of low abundance isotopes (i.e. &lt;sup&gt;17&lt;/sup&gt;O or &lt;sup&gt;36&lt;/sup&gt;S) or low-concentration elements (i.e. nitrogen in diamonds) measurement of low signal intensities is required. Traditionally, count rates between the upper level of pulse counting systems ~10&lt;sup&gt;5&lt;/sup&gt; c/s and the lower level of Faraday Cup (FC) measurements ~10&lt;sup&gt;6&lt;/sup&gt; c/s are considered to be in a &amp;#8220;gap area&amp;#8221; where neither detection protocol can achieve performance better than the 1&amp;#8240; level.&lt;/p&gt;&lt;p&gt;Faraday Cup detectors (FC) offer high precision with no need for gain monitoring, however the uncertainty of FC measurements depends on the signal to noise ratio. One approach for measuring low signal intensities is to use FCs coupled to electrometers with high ohmic resistors. CAMECA LG-SIMS can now be equipped with low noise 10&lt;sup&gt;12&lt;/sup&gt; &amp;#937; resistor FC preamplifier boards for measuring signal intensities down to the ~ 3 x 10&lt;sup&gt;5&lt;/sup&gt; c/s range with precision better than the 0.5&amp;#8240; level (1SD).&lt;/p&gt;&lt;p&gt;For measurement of low-abundance isotopes, a complementary approach consists of using discrete-dynode pulse counting electron multiplier (EM) detectors, for which drift and aging effects are minimized using a fast automated EM high voltage adjustment routine.&lt;/p&gt;&lt;p&gt;During this PICO presentation, we will discuss the relevance of the detector choice (FC 10&lt;sup&gt;12&lt;/sup&gt; &amp;#937; vs EM) for few examples of innovative applications.&lt;/p&gt;&lt;p&gt;Example of mass independent fractionation:&lt;/p&gt;&lt;p&gt;In addition to classical isotopic ratio measurements (e.g. &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C, &amp;#948;&lt;sup&gt;15&lt;/sup&gt;N, &amp;#948;&lt;sup&gt;18&lt;/sup&gt;O or &amp;#948;&lt;sup&gt;34&lt;/sup&gt;S), for which the instrumental mass fractionation (IMF) correction is mostly limited by the natural heterogeneity (chemical and isotopic) of the reference material, SIMS is particularly well suited for the measurement of mass independent fractionation (MIF, e.g. &amp;#8710;&lt;sup&gt;33&lt;/sup&gt;S, &amp;#8710;&lt;sup&gt;36&lt;/sup&gt;S and &amp;#8710;&lt;sup&gt;17&lt;/sup&gt;O). Along with classical geochemical processes, the degree of isotopic fractionation scales with the difference in mass of the isotopes involved (i.e. &amp;#948;&lt;sup&gt;33&lt;/sup&gt;S &amp;#8776; 0.515 * &amp;#948;&lt;sup&gt;34&lt;/sup&gt;S). MIF refers to non-conventional ratios that depart from these mass dependent rules. As instrumental mass fractionation has been shown to be strictly mass dependent, MIF measurements are not subject to IMF correction and are therefore measured directly. The use of SIMS in this specific case is particularly well suited and allows to fully explore the rich phenomenology of MIF source processes. We will discuss the advantages and disadvantages of using FC 10&lt;sup&gt;12&lt;/sup&gt; &amp;#937; for the minor Sulphur isotope (&lt;sup&gt;36&lt;/sup&gt;S) measurement.&lt;/p&gt;&lt;p&gt;Carbon and Nitrogen in diamond:&lt;/p&gt;&lt;p&gt;We will also show a recent analytical development aiming to measure &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C in diamonds at mass resolution of ~5000 (allowing the full separation of &lt;sup&gt;13&lt;/sup&gt;C- and &lt;sup&gt;12&lt;/sup&gt;CH-) as well as N-content and N-isotopes in diamonds at a mass resolution of ~9000 (full separation of &lt;sup&gt;12&lt;/sup&gt;C&lt;sup&gt;14&lt;/sup&gt;N- and &lt;sup&gt;13&lt;/sup&gt;C&lt;sup&gt;13&lt;/sup&gt;C-). &amp;#160;For this purpose, the use of FC 10&lt;sup&gt;12&lt;/sup&gt; &amp;#937; greatly improves the data quality and allows the simultaneous measurement of N-content and &amp;#948;&lt;sup&gt;15&lt;/sup&gt;N.&lt;/p&gt;

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