Ammonia-free coprecipitation synthesis of a Ni–Co–Mn hydroxide precursor for high-performance battery cathode materials

2015 ◽  
Vol 17 (2) ◽  
pp. 1127-1135 ◽  
Author(s):  
Kyoung-Mo Nam ◽  
Hyun-Jin Kim ◽  
Dong-Hyun Kang ◽  
Yong-Seok Kim ◽  
Seung-Wan Song

The ammonia-free coprecipitation process using citric acid as a new chelating agent successfully produced a micro-sized spherical Ni0.5Co0.2Mn0.3(OH)2 precursor and a well-performed cathode active material LiNi0.5Co0.2Mn0.3O2 for Li-ion batteries.

2016 ◽  
Vol 4 (1) ◽  
pp. 1600262 ◽  
Author(s):  
Yihui Zou ◽  
Xianfeng Yang ◽  
Chunxiao Lv ◽  
Tongchao Liu ◽  
Yanzhi Xia ◽  
...  

2019 ◽  
Vol 43 (47) ◽  
pp. 18943-18950 ◽  
Author(s):  
Zhao Li ◽  
Qiang Li ◽  
Anbang Zhang ◽  
Wen Wen ◽  
Lin Wang ◽  
...  

Li- and Mn-rich (LMR) layered materials with large specific capacities are one of the most promising cathodes for high-energy Li-ion batteries.


RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33544-33551 ◽  
Author(s):  
Ying Feng ◽  
Junjie Gu ◽  
Feng Yu ◽  
Chunfu Lin ◽  
Jinli Zhang ◽  
...  

This work first discloses the evolution of lattice parameters of the non-stoichiometric lithium iron phosphate crystals.


2018 ◽  
Vol 108 (2) ◽  
pp. 022011 ◽  
Author(s):  
Hao Zheng ◽  
Ting Wang ◽  
Rongfei Zhao ◽  
Jinsong Chen ◽  
Lin Li

2015 ◽  
Vol 278 ◽  
pp. 370-374 ◽  
Author(s):  
Jianqiu Deng ◽  
Jin Pan ◽  
Qingrong Yao ◽  
Zhongmin Wang ◽  
Huaiying Zhou ◽  
...  

2021 ◽  
Vol 58 (2) ◽  
pp. 211-219
Author(s):  
Ozan Toprakci

Since the commercialization of Li-ion batteries by Sony in 1990, the performance of cathode materials used in Li-ion batteries has improved significantly. However, Li-ion batteries cannot respond to the needs of the energy storage market in terms of energy density. In order to increase theoretical energy density of active materials, molar mass of the active material should be decreased, or electron number participating per reaction or reaction potential should be increased. In this study, it was aimed to produce cathode materials for Li-ion batteries in the form of composite nanofibers via electrospinning method. For this purpose, porous LiFexMn1-xPO4/C composite nanofibers (1 ] x ] 0) were synthesized with a scalable, two-step method (electrospinning and subsequent heat treatment). The morphological, structural and electrochemical properties of the LiFexMn1-xPO4/C composite nanofibers were determined by scanning electron microscope, X-ray diffraction and galvanostatic charge/discharge tests. Cathodes made of LiFexMn1-xPO4/C composite nanofibers showed various advantages such as long cycle life, improved electrochemical performance etc. due to the presence of carbon and LiFexMn1-xPO4 in the composite structure. With the addition of Mn to the structure of LiFePO4/C composite nanofibers, electrochemical performance was improved. LiFe0.8Mn0.2PO4/C composite nanofibers showed the best performance in terms of energy density among the samples. Further increment in Mn/Fe ratio resulted declining electrochemical capacity and energy density.


2014 ◽  
Vol 2 (18) ◽  
pp. 6368-6373 ◽  
Author(s):  
Qi Lu ◽  
Gregory S. Hutchings ◽  
Yang Zhou ◽  
Huolin L. Xin ◽  
Haimei Zheng ◽  
...  

The LiMg0.05Mn0.95PO4 embeded carbon nano-matraix exhibts flexibity and high-performance as cathode lihitum battery materials.


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