Liquid-assisted vortex grinding supports the single-step solid-state construction of a [2.2]paracyclophane

2014 ◽  
Vol 170 ◽  
pp. 35-40 ◽  
Author(s):  
Jelena Stojaković ◽  
Brian S. Farris ◽  
Leonard R. MacGillivray
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Vortex Method ◽  
Single Step ◽  
Quantitative Yield ◽  
Organic Solid ◽  
State Construction ◽  
Organic Solid State

We employ vortex grinding to generate a [2.2]paracyclophane in the organic solid state. The vortex grinding is aided with the addition of a small amount of liquid phase to facilitate topochemical [2 + 2] photodimerizations that generate the cyclophane stereoselectively and in up to quantitative yield. The use of the liquid phase increases the scope of the vortex method.

scholarly journals Single‐Step Spray Printing of Symmetric All‐Organic Solid‐State Batteries Based on Porous Textile Dye Electrodes

2019 ◽  
Vol 9 (39) ◽  
pp. 1901418 ◽  
Author(s):  
Puiki Leung ◽  
Junfu Bu ◽  
Pablo Quijano Velasco ◽  
Matthew R. Roberts ◽  
Nicole Grobert ◽  
...  
Keyword(s):  
Solid State ◽  
Single Step ◽  
Textile Dye ◽  
Organic Solid ◽  
Solid State Batteries ◽  
Organic Solid State

Supramolecular Catalysis in the Organic Solid State through Dry Grinding

2010 ◽  
Vol 49 (25) ◽  
pp. 4273-4277 ◽  
Author(s):  
Anatoliy N. Sokolov ◽  
Dejan-Krešimir Bučar ◽  
Jonas Baltrusaitis ◽  
Sean X. Gu ◽  
Leonard R. MacGillivray
Keyword(s):  
Solid State ◽  
Supramolecular Catalysis ◽  
Organic Solid ◽  
Dry Grinding ◽  
Organic Solid State

Photopumped Organic Solid-State Dye Laser with a Second-Order Distributed Feedback Cavity

2001 ◽  
Vol 40 (Part 2, No. 8A) ◽  
pp. L799-L801 ◽  
Author(s):  
Musubu Ichikawa ◽  
Yuji Tanaka ◽  
Naotoshi Suganuma ◽  
Toshiki Koyama ◽  
Yoshio Taniguchi
Keyword(s):  
Solid State ◽  
Dye Laser ◽  
Second Order ◽  
Distributed Feedback ◽  
Organic Solid ◽  
Solid State Dye Laser ◽  
Organic Solid State

MoS2 nano-flower incorporation for improving organic-organic solid state electrochromic device performance

2021 ◽  
pp. 111502
Author(s):  
Suchita Kandpal ◽  
Tanushree Ghosh ◽  
Chanchal Rani ◽  
Sonam Rani ◽  
Devesh K. Pathak ◽  
...  
Keyword(s):  
Solid State ◽  
Electrochromic Device ◽  
Device Performance ◽  
Organic Solid ◽  
Organic Solid State

F8BT Oligomers for Organic Solid-State Lasers

2020 ◽  
Vol 12 (25) ◽  
pp. 28383-28391
Author(s):  
Masashi Mamada ◽  
Ryutaro Komatsu ◽  
Chihaya Adachi
Keyword(s):  
Solid State ◽  
Solid State Lasers ◽  
Organic Solid ◽  
Organic Solid State

Several Derivatives of 6-(Tert-Butyl)-4H-Pyran-4-Ylidene Malononitrile with Different Amorphous Phase Promoting Substituents for Light-Amplification Systems

2019 ◽  
Vol 800 ◽  
pp. 275-279
Author(s):  
Elmars Zarins ◽  
Deins Alksnis ◽  
Julija Pervenecka ◽  
Patricija Paulsone ◽  
Kristine Lazdovica ◽  
...  
Keyword(s):  
Solid State ◽  
Glass Structure ◽  
Threshold Energy ◽  
Amorphous State ◽  
Excitation Threshold ◽  
Laser Applications ◽  
Tert Butyl ◽  
Organic Solid ◽  
Light Amplification ◽  
Organic Solid State

A series of glassy 6-(tert-butyl)-4H-pyran-4-ylidene malononitrile (DCM) derivatives with covalently attached amorphous state promoting bulky 1,1,1-triphenylmethyl (trityl) moieties through several chemical design approaches have been synthesized and investigated for suitability in organic solid state laser applications. Results showed that the bonding type of such functional groups had a considerable influence on glass structure forming dye thermal properties and a slight influence on their optical properties. Thermal stability up to 346 °C was achieved with glass transitions in the range from 39 to 138 °C. Incorporation of bulky triphenyl substituents via ester groups showed remarkable amplified spontaneous emission (ASE) threshold energy value reduction by 1.7 times in comparison to other bonding approaches with excitation threshold energy density up to 91 µJ/cm2. Synthesized dyes show potential as the light-amplification medium component in organic solid state lasers.

Sign in / Sign up

Export Citation Format

Share Document