New 1-D and 3-D thiocyanatocadmates modified by various amine molecules and Cl−/CH3COO− ions: synthesis, structural characterization, thermal behavior and photoluminescence properties

2015 ◽  
Vol 44 (11) ◽  
pp. 5095-5105 ◽  
Author(s):  
Bing Guo ◽  
Xiao Zhang ◽  
Yan-Ning Wang ◽  
Jing-Jing Huang ◽  
Jie-Hui Yu ◽  
...  

Reactions of CdCl2/Cd(CH3COO)2, SCN− and various organic amines yielded five new thiocyanatocadmates; structural, thermal and photoluminescence properties are reported.

2019 ◽  
Vol 9 (23) ◽  
pp. 5211 ◽  
Author(s):  
Liu ◽  
Li ◽  
Yao ◽  
He ◽  
Liu ◽  
...  

Two-dimensional (2D) layered hybrid organic–inorganic perovskites have potential applications in solar cells, electroluminescent devices and radiation detection because of their unique optoelectronic properties. In this paper, four 2D layered hybrid organic–inorganic halide perovskites of (C6H5CH2NH3)2PbCl4, (C6H5CH2NH3)2PbBr4, (C6H5CH2NH3)2PbI4 and (C4H9NH3)2PbBr4 were synthesized by solvent evaporation. Their crystal structure and surface morphology were studied. The effects of different halogens and organic amines on perovskites’ absorption spectra were investigated, and the photoluminescence (PL) properties were studied by femtosecond ultrafast spectroscopy. The experimental results show that the four perovskites are well crystallized and oriented. With the increase of halogen atom number (Cl, Br, I) in turn, the UV-Vis absorption spectra peaks of perovskites redshift due to the increasing of the layer spacing, but organic amines have little effect on the spectra of perovskites. The PL intensity increases with increasing laser power, but the lifetime decreases with increasing laser power, which is mainly due to the non-geminate recombination. This research is of great significance for realizing the spectral regulation of organic–inorganic hybrid perovskites and promoting their application in nano-photonics and optoelectronic devices.


2020 ◽  
Vol 227 ◽  
pp. 117591
Author(s):  
Yu Ma ◽  
Guoying Zhao ◽  
Yanyan Guo ◽  
Jingshan Hou ◽  
Yufeng Liu ◽  
...  

2015 ◽  
Vol 1088 ◽  
pp. 129-137 ◽  
Author(s):  
Muhammet Köse ◽  
Gökhan Ceyhan ◽  
Emine Atcı ◽  
Vickie McKee ◽  
Mehmet Tümer

2014 ◽  
Vol 26 (4) ◽  
pp. 1413-1424
Author(s):  
Sami Soukrata ◽  
Mohamed Belhouchet ◽  
Karim Adil ◽  
Tahar Mhiri

2014 ◽  
Vol 43 (48) ◽  
pp. 18104-18116 ◽  
Author(s):  
Irina G. Fomina ◽  
Zhanna V. Dobrokhotova ◽  
Andrey B. Ilyukhin ◽  
Valery I. Zhilov ◽  
Artem S. Bogomyakov ◽  
...  

The PL color evidently changes from red at 300 K to bright green at 77 K.


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