Template free construction of a hollow Fe3O4 architecture embedded in an N-doped graphene matrix for lithium storage

2015 ◽  
Vol 44 (12) ◽  
pp. 5735-5745 ◽  
Author(s):  
Guohui Qin ◽  
Zewei Fang ◽  
Chengyang Wang
Keyword(s):  
Rational Design ◽  
Electrode Materials ◽  
Lithium Storage ◽  
Free Construction ◽  
Doped Graphene ◽  
Template Free

The rational design and fabrication of electrode materials is a significant, yet highly challenging task.

Rational design of MoS2@graphene nanocables: towards high performance electrode materials for lithium ion batteries

2014 ◽  
Vol 7 (10) ◽  
pp. 3320-3325 ◽  
Author(s):  
Debin Kong ◽  
Haiyong He ◽  
Qi Song ◽  
Bin Wang ◽  
Wei Lv ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Contact Model ◽  
Lithium Storage

A unique MoS2@graphene nanocable with a novel contact model between MoS2 nanosheets and graphene has been developed for high-performance lithium storage.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

scholarly journals N-doped graphene foam obtained by microwave-assisted exfoliation of graphite

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Malgorzata Skorupska ◽  
Anna Ilnicka ◽  
Jerzy P. Lukaszewicz
Keyword(s):  
Electron Microscopy ◽  
Electrode Materials ◽  
Elemental Content ◽  
Research Approach ◽  
Pristine Graphene ◽  
Active Electrode ◽  
Graphene Foam ◽  
Practical Applications ◽  
Microwave Reactor ◽  
Doped Graphene

AbstractThe synthesis of metal-free but electrochemically active electrode materials, which could be an important contributor to environmental protection, is the key motivation for this research approach. The progress of graphene material science in recent decades has contributed to the further development of nanotechnology and material engineering. Due to the unique properties of graphene materials, they have found many practical applications: among others, as catalysts in metal-air batteries, supercapacitors, or fuel cells. In order to create an economical and efficient material for energy production and storage applications, researchers focused on the introduction of additional heteroatoms to the graphene structure. As solutions for functionalizing pristine graphene structures are very difficult to implement, this article presents a facile method of preparing nitrogen-doped graphene foam in a microwave reactor. The influence of solvent type and microwave reactor holding time was investigated. To characterize the elemental content and structural properties of the obtained N-doped graphene materials, methods such as elemental analysis, high-resolution transmission electron microscopy, scanning electron microscopy, and Raman spectroscopy were used. Electrochemical activity in ORR of the obtained materials was tested using cyclic voltamperometry (CV) and linear sweep voltamperometry (LSV). The tests proved the materials’ high activity towards ORR, with the number of electrons reaching 3.46 for tested non-Pt materials, while the analogous value for the C-Pt (20 wt% loading) reference was 4.

Vacancies-engineered MoO3 and Na+-preinserted MnO2 in-situ grown N-doped graphene nanotubes as electrode materials for high-performance asymmetric supercapacitor

2021 ◽  
Author(s):  
Jian Zhao ◽  
He Cheng ◽  
Huanyu Li ◽  
Yan-Jie Wang ◽  
Qingyan Jiang ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
High Energy ◽  
Cooperative Effect ◽  
Electrochemical Energy Storage ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Doped Graphene ◽  
Power Densities

Developing advanced negative and positive electrode materials for asymmetric supercapacitors (ASCs) as the electrochemical energy storage can enable the device to reach high energy/power densities resulting from the cooperative effect...

Engineering flexible carbon nanofibers concatenated MOFs-derived hollow octahedral CoFe2O4 as anode materials for enhanced lithium storage

2021 ◽  
Author(s):  
Fangfang Xue ◽  
Yangyang Li ◽  
Chen Liu ◽  
Zhigang Zhang ◽  
Jun Lin ◽  
...  
Keyword(s):  
Mechanical Property ◽  
Anode Materials ◽  
Electrode Materials ◽  
Electronic Devices ◽  
High Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Excellent Mechanical Property ◽  
Wearable Electronic ◽  
Wearable Electronic Devices

Constructing suitable electrode materials with high capacity and excellent mechanical property is indispensable for flexible lithium-ion batteries (LIBs) to satisfy the growing flexible and wearable electronic devices. Herein, a necklace-like...

Rational design of flower-like Co–Zn LDH@Co(H2PO4)2 heterojunctions as advanced electrode materials for supercapacitors

2021 ◽  
Vol 50 (13) ◽  
pp. 4643-4650
Author(s):  
Miao He ◽  
Yi He ◽  
Xinyi Zhou ◽  
Qiang Hu ◽  
Shixiang Ding ◽  
...  
Keyword(s):  
Energy Storage ◽  
Specific Capacitance ◽  
Rational Design ◽  
Electrode Materials ◽  
Storage Capacity ◽  
Energy Storage Capacity

The device exhibits 95.3% retention in specific capacitance after 5000 cycles and possesses superior energy-storage capacity.

Hierarchically 3D Nanoporous Structured Co9S8@Nix:Moy–Se Core–shell Nanowire Arrays Electrode for the High-performance Asymmetric Supercapacitors

2021 ◽  
Author(s):  
Dai Jiu Yi ◽  
Soram Bobby Singh ◽  
Nam Hoon Kim ◽  
Joong Hee Lee
Keyword(s):  
Energy Conversion ◽  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Storage Systems ◽  
Nanowire Arrays ◽  
Core Shell ◽  
Good Strategy ◽  
Free Standing ◽  
Asymmetric Supercapacitors

The rational design of free-standing hierarchic core–shell nanoporous architectures is a good strategy for fabricating next-generation electrode materials for application to electrochemical energy conversion/storage systems. Herein, hierarchical core–shell 3D Co9S8@Nix:Moy–Se...

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