Exploiting verdazyl radicals to assemble 2p–3d–4f one-dimensional chains

2015 ◽  
Vol 44 (12) ◽  
pp. 5364-5368 ◽  
Author(s):  
Chao Wang ◽  
Shuang-Yan Lin ◽  
Wei Shi ◽  
Peng Cheng ◽  
Jinkui Tang
Keyword(s):  
Transition Metal ◽  
One Dimensional ◽  
Efficient Approach ◽  
Verdazyl Radicals ◽  
Verdazyl Radical

Exploiting the coordination abilities of an isopropyl substituted verdazyl radical to transition metal and lanthanide(iii) ions represents an efficient approach to produce a system incorporating 2p, 3d and 4f spin carriers.

Synergistic effect of carbon nanotubes and graphitic carbon nitride on the enhanced supercapacitor performance of cobalt diselenide-based composites

2021 ◽  
Author(s):  
Mingjie Li ◽  
Xuan Zheng ◽  
Xiang Li ◽  
Youjun Yu ◽  
Jinlong Jiang
Keyword(s):  
Carbon Nanotubes ◽  
Transition Metal ◽  
Synergistic Effect ◽  
Hydrothermal Method ◽  
High Performance ◽  
Carbon Nitride ◽  
Electrode Materials ◽  
One Dimensional ◽  
Supercapacitor Performance ◽  
Metal Selenides

Recently, transition metal selenides have been investigated extensively as promising electrode materials for high-performance supercapacitors. Herein, the multi-component CoSe2/CNTs@g-C3N4 composites are prepared using a two-step hydrothermal method by incorporating one-dimensional...

Symmetry Violations in Partially Oxidized One-Dimensional (1D)Transition Metal Polymers. Metal-Ligand-Metal(M-L-M) Bridged Systems

1984 ◽  
Vol 39 (9) ◽  
pp. 807-829
Author(s):  
Michael C. Böhm
Keyword(s):  
Transition Metal ◽  
Density Wave ◽  
Tight Binding ◽  
Mean Field ◽  
Valence Bond ◽  
Hole State ◽  
One Dimensional ◽  
Metal Derivatives ◽  
A Charge ◽  
Metal Ligand

The band structure of the metal-ligand-metal (M-L-M) bridged quasi one-dimensional (1D) cyclopentadienylmanganese polymer, MnCp 1, has been studied in the unoxidized state and in a partly oxidized modification with one electron removed from each second MnCp fragment. The tight-binding approach is based on a semiempirical self-consistent-field (SCF) Hartree-Fock (HF) crystal orbital (CO) model of the INDO-type (intermediate neglect of differential overlap) combined with a statistical averaging procedure which has its origin in the grand canonical ensemble. The latter approximation allows for an efficient investigation of violations of the translation symmetries in the oxidized 1D material. The oxidation process in 1 is both ligand- and metal-centered (Mn 3d-2 states). The mean-field minimum corresponds to a charge density wave (CDW) solution with inequivalent Mn sites within the employed repeat-units. The symmetry adapted solution with electronically identical 3d centers is a maximum in the variational space. The coupling of this electronic instability to geometrical deformations is also analyzed. The ligand amplitudes encountered in the hole-state wave function prevent extremely large charge separations between the 3d centers which are found in ID systems without bridging moieties (e.g. Ni(CN)2-5 chain). The symmetry reduction in oxidized 1 is compared with violations of spatial symmetries in finite transition metal derivatives and simple solids. The stabilization of the valence bond-type (VB) solution is physically rationalized (i.e. left-right correlations between the 3d centers). The computational results derived for 1 are generalized to oxidized transition metal chains with band occupancies that are simple fractions of the number of stacking units and to 1D systems that deviate from this relation. The entropy-influence for temperatures T ≠ 0 is shortly discussed (stabilization of domain or cluster structures).

Three-to-One Dimensional Crossover of Growth Mode in Transition Metal Cyanide Film

2011 ◽  
Vol 50 (8) ◽  
pp. 085602 ◽  
Author(s):  
Yutaka Moritomo ◽  
Mitsuhiro Ito ◽  
Takayuki Shibata
Keyword(s):  
Transition Metal ◽  
Growth Mode ◽  
Dimensional Crossover ◽  
One Dimensional ◽  
Metal Cyanide
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