Synthesis and characterization of μ-nitrido, μ-carbido and μ-oxo dimers of iron octapropylporphyrazine

2015 ◽  
Vol 44 (5) ◽  
pp. 2240-2251 ◽  
Author(s):  
Cédric Colomban ◽  
Evgeny V. Kudrik ◽  
Dmitry V. Tyurin ◽  
Florian Albrieux ◽  
Sergei E. Nefedov ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Macrocyclic Complexes ◽  
Single Atom ◽  
Synthesis And Characterization ◽  
Structural And Electronic Properties

The structural and electronic properties of single-atom bridged diiron macrocyclic complexes are determined by the nature of the bridge.

Synthesis of metallophthalocyanines with four oxy-2,2-diphenylacetic acid substituents and their structural and electronic properties

2016 ◽  
Vol 22 (5) ◽  
Author(s):  
Sakar Mübarak Abdalrazaq ◽  
Beyza Cabir ◽  
Selçuk Gümüş ◽  
Mehmet Salih Ağırtaş
Keyword(s):  
Electronic Properties ◽  
Synthesis And Characterization ◽  
Cobalt Phthalocyanine ◽  
Diphenylacetic Acid ◽  
Structural And Electronic Properties

AbstractThe synthesis and characterization of new copper-, magnesium- and cobalt- phthalocyanine complexes are reported. It appears that these complexes are not aggregated in THF in the concentration range of 1×10

scholarly journals Synthesis and Optoelectronic Properties of Iptycene–Naphthazarin Dyes

Synlett ◽  
2018 ◽  
Vol 30 (01) ◽  
pp. 54-58 ◽  
Author(s):  
Timothy Swager ◽  
Cagatay Dengiz ◽  
You-Chi Wu
Keyword(s):  
Single Crystal ◽  
Electronic Properties ◽  
Diels Alder ◽  
Optoelectronic Properties ◽  
Synthesis And Characterization ◽  
Nmr Analysis ◽  
X Ray ◽  
Vis Spectroscopy

We report the synthesis and characterization of iptycene–naphthazarin dyes by using a sequential Diels–Alder approach. The tautomerization of naphthazarin was used as the key step in the synthesis, with structures confirmed by single-crystal X-ray and NMR analysis. The systematic trends in electronic properties were investigated by UV/Vis spectroscopy. BF2 complexes of the dyes were prepared by reaction with BF3·OEt2 in CH2Cl2.

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