scholarly journals Influence of the ionic liquid cation on the solvent extraction of trivalent rare-earth ions by mixtures of Cyanex 923 and ionic liquids

2015 ◽  
Vol 44 (3) ◽  
pp. 1379-1387 ◽  
Author(s):  
Alok Rout ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Rare Earth ◽  
Solvent Extraction ◽  
Rare Earth Ions ◽  
Trivalent Rare Earth ◽  
Cyanex 923

The mechanism for extraction of rare-earth ions by a solvating extractant to a bis(trifluoromethylsulfonyl)imide ionic liquid depends on the hydrophilicity of the ionic liquid cation.

scholarly journals Separation of rare-earth ions from ethylene glycol (+LiCl) solutions by non-aqueous solvent extraction with Cyanex 923

RSC Advances ◽  
2017 ◽  
Vol 7 (72) ◽  
pp. 45351-45362 ◽  
Author(s):  
Nagaphani Kumar Batchu ◽  
Tom Vander Hoogerstraete ◽  
Dipanjan Banerjee ◽  
Koen Binnemans
Keyword(s):  
Rare Earth ◽  
Solvent Extraction ◽  
Ethylene Glycol ◽  
Rare Earths ◽  
Rare Earth Ions ◽  
Aqueous Solvent ◽  
Cyanex 923

Mixtures of rare earths are separation by non-aqueous solvent extraction with two immiscible organic phases.

scholarly journals Liquid-liquid solvent extraction of rare earths: a crystallographic analysis.

2014 ◽  
Vol 70 (a1) ◽  
pp. C1006-C1006
Author(s):  
Jeroen Jacobs ◽  
Koen Binnemans ◽  
Luc Van Meervelt
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Rare Earth ◽  
Solvent Extraction ◽  
Aqueous Phase ◽  
Rare Earths ◽  
Structural Information ◽  
Side Chain ◽  
Anionic Complex

Liquid-liquid solvent extraction has become the primary research topic for separating mixtures of rare-earths. [1] Current research on this topic focuses on extraction processes involving ionic liquids as basic extracting agents. In the aqueous phase, the rare-earth is coordinated by the anionic entities of the ionic liquid, forming an anionic complex. The large organic cation of the ionic liquid neutralizes the complex (ion-pair complex) and migrates the entity to an organic phase. The choice of these agents is solely based on the calculation of thermodynamical extraction parameters, whilst structural information about these compounds is rare or even non-existent. Our research focuses on obtaining structural information via crystallography on the above-mentioned molecules and relating the interactions between anion and cation to the stability of the complexes. A difference in stability between the anionic complex and cation can give a different extractability. Different rare-earth chloride salts were dissolved in an aqueous phase, containing ionic liquids with β-diketonate anions and 1-alkyl-3-methylimidazolium cations. After the extraction, crystals of the formed compounds are grown from the organic phase and measured. Current results show us that an intermolecular non-classical C-H ... O hydrogen bond is persistent across the different molecules, whilst small interactions between the cation side chain and halogens on the β-diketonate add extra stability to the crystal structure. Structures formed with 2-thenolytrifluoroactylacetonate anions have no intention to form side chain interactions, leaving the alkyl chain of the 1-alkyl-3-methylimidazolium in a void, whilst structures formed with hexafluoroacetylactonate have strong side chain interactions, which leads to a better packing. The different solubility of both compounds can be related to the different interactions and stability in the crystal structure.

Solvent extraction of rare-earth ions based on functionalized ionic liquids

Talanta ◽  
2012 ◽  
Vol 90 ◽  
pp. 132-137 ◽  
Author(s):  
Xiaoqi Sun ◽  
Huimin Luo ◽  
Sheng Dai
Keyword(s):  
Ionic Liquids ◽  
Rare Earth ◽  
Solvent Extraction ◽  
Rare Earth Ions

Kathodo- und Photolumineszenz der Seltenerd-aktivierten Wirtsgitter Ba2La2B2+Te2O12 (B = Zn, Mg)

1986 ◽  
Vol 41 (6) ◽  
pp. 866-870 ◽  
Author(s):  
H.-D. Autenrieth ◽  
S. Kemmler-Sack
Keyword(s):  
Electronic Structure ◽  
Rare Earth ◽  
Visible Region ◽  
Host Lattice ◽  
Rare Earth Ions ◽  
New Host ◽  
Emission Efficiency ◽  
Transfer Processes ◽  
Trivalent Rare Earth ◽  
Host Lattices

By activation of the new host lattices Ba2La2B2+Te2O12 (B = Zn, Mg) with trivalent rare earth ions Ln3+ = Pr. Sm, Eu, Tb, Dy, Ho, Tm an emission in the visible region is observed. The influence of the electronic structure and concentration on the relative emission efficiency as well as the host lattice participation in the energy transfer processes are discussed.

Tunable emissions via the white region from Sr2Gd8(SiO4)6O2:RE3+ (RE3+: Dy3+, Tm3+, Eu3+) phosphors

2016 ◽  
Vol 40 (7) ◽  
pp. 6214-6227 ◽  
Author(s):  
Gattupalli Manikya Rao ◽  
G. Seeta Rama Raju ◽  
Sk. Khaja Hussain ◽  
E. Pavitra ◽  
P. S. V. Subba Rao ◽  
...  
Keyword(s):  
Rare Earth ◽  
White Light ◽  
Host Lattice ◽  
Rare Earth Ions ◽  
White Region ◽  
Light Region ◽  
Trivalent Rare Earth ◽  
Co Doped

Sr2Gd8(SiO4)6O2 is an excellent host lattice for tunable emissions via the white-light region when co-doped with suitable trivalent rare-earth ions.

Luminescence of trivalent rare earth ions in the yttrium aluminium borate non-linear laser crystal

2003 ◽  
Vol 102-103 ◽  
pp. 216-219 ◽  
Author(s):  
E. Cavalli ◽  
A. Speghini ◽  
M. Bettinelli ◽  
M.O. Ramírez ◽  
J.J. Romero ◽  
...  
Keyword(s):  
Rare Earth ◽  
Laser Crystal ◽  
Rare Earth Ions ◽  
Yttrium Aluminium ◽  
Aluminium Borate ◽  
Non Linear ◽  
Trivalent Rare Earth ◽  
Linear Laser
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