4-(4-Carboxyphenoxy)phthalate-based coordination polymers and their application in sensing nitrobenzene

2015 ◽  
Vol 44 (4) ◽  
pp. 1655-1663 ◽  
Author(s):  
Yan-Ning Wang ◽  
Ping Zhang ◽  
Jie-Hui Yu ◽  
Ji-Qing Xu
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Structural Characterization

Structural characterization of 4-(4-carboxyphenoxy)phthalate-based Cd2+ and Mn2+ coordination polymers are reported, and Cd2+ coordination polymer can serve as probe to sense nitrobenzene.

scholarly journals Coordination Polymers in Dicyanamido-Cadmium(II) with Diverse Network Dimensionalities

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 181
Author(s):  
Franz A. Mautner ◽  
Patricia V. Jantscher ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Klaus Reichmann ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Structural Characterization ◽  
Mononuclear Complex ◽  
3D Network ◽  
Polymeric Chains ◽  
1D Chains ◽  
3D Networks

The synthesis and structural characterization of six dicyanamido-cadmium(II) complexes are reported: catena-[Cd(μ1,3-dca)(μ1,5-dca)(3-ampy)] (1), catena-[Cd3(μ1,3,5-dca)2(μ1,5-dca)4(pyNO)2(H2O)2] (2), catena-{Cd(H2O)2(μ1,5-dca)2](2,6-lut-NO)} (3), catena-[Cd(Me2en)(μ1,5-dca)2] (4), catena-[Cd(Me4en)(μ1,5-dca)2] (5), and [Cd(1,8-damnp)2(dca)2] (6), where dca = dicyanamide anion, 3-ampy = 3-aminopyridine, pyNO = pyridine-N-oxide, 2,6-lut-NO = 2,6-lutidine-N-oxide, Me2en = N,N-dimethyl-ethylenediamine, Me4en = N,N,N′,N′-tetramethyl-ethylenediamine, and 1,8-damnp = 1,8-diaminonaphthaline. The coordination polymers have different dimensionalities: 1 and 5 form 3D networks structures; 3 and 4 form polymeric 1D chains and 1DD double chains, respectively. Ribbons of three fused polymeric chains are observed in 2. In 6, the mononuclear complex units form a hydrogen-bonded supramolecular 3D network. In the coordination polymer compounds, the dca linkers display three bonding modes: the most common μ1,5-dca and the least popular μ1,3- and μ1,3,5-dca bonding. The luminescence emission and thermal properties of the complexes were investigated.

scholarly journals Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

2014 ◽  
Vol 43 (4) ◽  
pp. 1519-1523 ◽  
Author(s):  
Yuyang Tian ◽  
Phoebe K. Allan ◽  
Catherine L. Renouf ◽  
Xiang He ◽  
Laura J. McCormick ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Characterization

scholarly journals Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations

CrystEngComm ◽  
2019 ◽  
Vol 21 (9) ◽  
pp. 1423-1432 ◽  
Author(s):  
Oscar Castillo ◽  
Esther Delgado ◽  
Diego Hernández ◽  
Elisa Hernández ◽  
Avelino Martín ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Transition Metal ◽  
Structural Characterization ◽  
Metal Cations ◽  
Magnetic Behaviour ◽  
Divalent Metal ◽  
Divalent Metals ◽  
Divalent Metal Cations ◽  
1D Coordination Polymer

Complexes containing [Fe2(SC6H2Cl2S)4]2− or [Ni(SC6H2Cl2S)2]− entities and divalent metal cations as well as an 1D-coordination polymer K/Zn have been obtained and their magnetic behaviour studied.

Synthesis and structural characterization of homochiral coordination polymers with imidazole-based monocarboxylate ligands

2019 ◽  
Vol 48 (24) ◽  
pp. 8731-8739 ◽  
Author(s):  
Elena Borrego ◽  
Antonio I. Nicasio ◽  
Eleuterio Álvarez ◽  
Francisco Montilla ◽  
José Manuel Córdoba ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization ◽  
Two Dimensional ◽  
Bridging Ligands ◽  
Silver Copper ◽  
Copper And Zinc

Two-dimensional homochiral coordination polymers of sodium, silver, copper and zinc were obtained with 2alkyl,2-(1H-imidazol-1-yl)acetate anions as bridging ligands.

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