The first tritopic bridging ligand 1,3,5-tris(4-carboxyphenyl)-benzene (H3BTB) functionalized porous polyoxometalate-based metal–organic framework (POMOF): from design, synthesis to electrocatalytic properties

2015 ◽  
Vol 44 (3) ◽  
pp. 1435-1440 ◽  
Author(s):  
Bao-Xia Dong ◽  
Lu Chen ◽  
Shi-Yang Zhang ◽  
Jun Ge ◽  
Liang Song ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Organic Framework ◽  
Tripodal Ligand ◽  
Design Synthesis ◽  
Electrocatalytic Properties ◽  
Bridging Ligand ◽  
Metal Organic ◽  
Bromate Reduction ◽  
Organic Framework

A POMOF with substantial catalytic activity towards bromate reduction was isolated through the extension of transition-metal-grafted ε-Keggin by a tripodal ligand H3BTB.

A Mesoporous Indium Metal–Organic Framework: Remarkable Advances in Catalytic Activity for Strecker Reaction of Ketones

2016 ◽  
Vol 138 (29) ◽  
pp. 9089-9092 ◽  
Author(s):  
Daniel Reinares-Fisac ◽  
Lina María Aguirre-Díaz ◽  
Marta Iglesias ◽  
Natalia Snejko ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Strecker Reaction ◽  
Metal Organic ◽  
Indium Metal ◽  
Organic Framework

A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Selective Catalyst ◽  
Pyridinedicarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

Assembly of polyoxometalate-templated metal-organic framework with effective peroxidase-like catalytic activity

2019 ◽  
Vol 72 (2) ◽  
pp. 272-282 ◽  
Author(s):  
Fei Xie ◽  
Xiao Li ◽  
Yujing Li ◽  
Xusheng Jiang ◽  
Qi Rui ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

Colloidal Metal–Organic Framework Hexapods Prepared from Postsynthesis Etching with Enhanced Catalytic Activity and Rollable Packing

2018 ◽  
Vol 10 (48) ◽  
pp. 40990-40995 ◽  
Author(s):  
Zihao Ou ◽  
Xiaohui Song ◽  
Wen Huang ◽  
Xing Jiang ◽  
Subing Qu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Colloidal Metal ◽  
Organic Framework

H3O2 Bridging Ligand in a Metal–Organic Framework. Insight into the Aqua-Hydroxo↔Hydroxyl Equilibrium: A Combined Experimental and Theoretical Study

2013 ◽  
Vol 135 (15) ◽  
pp. 5782-5792 ◽  
Author(s):  
Richard F. D’Vries ◽  
Victor A. de la Peña-O’Shea ◽  
Natalia Snejko ◽  
Marta Iglesias ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Framework ◽  
Bridging Ligand ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework
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