Mixed-metal chalcogenide tetrahedral clusters with an exo-polyhedral metal fragment
Mixed-metal chalcogenide tetrahedral clusters, [Cp*Ru(CO)2(μ-H){Os3(CO)9}S] and [Cp*Ru(CO)2(μ-H){Ru3(CO)9}S], have been isolated from arachno-[(Cp*RuCO)2B2H6] and [(Cp*Mo)2B5H9] respectively, in which the [Cp*Ru(CO)2] fragment is attached in an exo-polyhedral manner.
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