scholarly journals Unraveling the origins of catalyst degradation in non-heme iron-based alkane oxidation

2014 ◽  
Vol 43 (45) ◽  
pp. 17108-17119 ◽  
Author(s):  
Michaela Grau ◽  
Andrew Kyriacou ◽  
Fernando Cabedo Martinez ◽  
Irene M. de Wispelaere ◽  
Andrew J. P. White ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Heme Iron ◽  
Alkane Oxidation ◽  
Non Heme Iron ◽  
Amine Ligands ◽  
Iron Based

A series of iron(ii) complexes with tetradentate and pentadentate pyridyl amine ligands has been used for the oxidation of cyclohexane with hydrogen peroxide. Ligand degradation is observed under oxidising conditions via oxidative N-dealkylation.

ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

2005 ◽  
pp. 5301 ◽  
Author(s):  
Sonia Taktak ◽  
Margaret Flook ◽  
Bruce M. Foxman ◽  
Lawrence Que, Jr. ◽  
Elena V. Rybak-Akimova
Keyword(s):  
Hydrogen Peroxide ◽  
Heme Iron ◽  
Benzoic Acids ◽  
Non Heme Iron ◽  
Iron Center

Iron-Decorated, Guanidine Functionalized Metal-Organic Framework as a Non-heme Iron-Based Enzyme Mimic System for Catalytic Oxidation of Organic Substrates

2019 ◽  
Vol 149 (5) ◽  
pp. 1237-1249 ◽  
Author(s):  
Ahmad Shaabani ◽  
Reza Mohammadian ◽  
Hassan Farhid ◽  
Masoumeh Karimi Alavijeh ◽  
Mostafa M. Amini
Keyword(s):  
Catalytic Oxidation ◽  
Metal Organic Framework ◽  
Enzyme Mimic ◽  
Heme Iron ◽  
Organic Substrates ◽  
Non Heme Iron ◽  
Metal Organic ◽  
Iron Based ◽  
Organic Framework

The Active Intermediates of Non-Heme-Iron-Based Systems for Catalytic Alkene Epoxidation with H2O2/CH3COOH

2007 ◽  
Vol 2007 (6) ◽  
pp. 852-857 ◽  
Author(s):  
Eduard A. Duban ◽  
Konstantin P. Bryliakov ◽  
Evgenii P. Talsi
Keyword(s):  
Heme Iron ◽  
Non Heme Iron ◽  
Iron Based ◽  
Active Intermediates

[FeIII(PMA)]2+:  A Mononuclear Non-Heme Iron Complex That Catalyzes Alkane Oxidation

1996 ◽  
Vol 35 (21) ◽  
pp. 6273-6281 ◽  
Author(s):  
Cattien Nguyen ◽  
Richard J. Guajardo ◽  
Pradip K. Mascharak
Keyword(s):  
Iron Complex ◽  
Heme Iron ◽  
Alkane Oxidation ◽  
Non Heme Iron

Hydrogen Peroxide Decomposition by a Non-Heme Iron(III) Catalase Mimic: A DFT Study

2007 ◽  
Vol 13 (15) ◽  
pp. 4230-4245 ◽  
Author(s):  
Willi Sicking ◽  
Hans-Gert Korth ◽  
Georg Jansen ◽  
Herbert de Groot ◽  
Reiner Sustmann
Keyword(s):  
Hydrogen Peroxide ◽  
Heme Iron ◽  
Dft Study ◽  
Hydrogen Peroxide Decomposition ◽  
Non Heme Iron ◽  
Peroxide Decomposition

Unusual efficiency of a non-heme iron complex as catalyst for the hydroxylation of aromatic compounds by hydrogen peroxide: comparison with iron porphyrins

2002 ◽  
Vol 5 (4) ◽  
pp. 263-266 ◽  
Author(s):  
Jean-François Bartoli ◽  
François Lambert ◽  
Irène Morgenstern-Badarau ◽  
Pierrette Battioni ◽  
Daniel Mansuy
Keyword(s):  
Hydrogen Peroxide ◽  
Aromatic Compounds ◽  
Iron Complex ◽  
Heme Iron ◽  
Iron Porphyrins ◽  
Non Heme Iron
Sign in / Sign up

Export Citation Format

Share Document