A polymerized ionic liquid-supported B12 catalyst with a ruthenium trisbipyridine photosensitizer for photocatalytic dechlorination in ionic liquids

2014 ◽  
Vol 43 (37) ◽  
pp. 13972-13978 ◽  
Author(s):  
Wei Zhang ◽  
Hisashi Shimakoshi ◽  
Noriyuki Houfuku ◽  
Xi-Ming Song ◽  
Yoshio Hisaeda

A visible light-driven catalytic reaction efficiently proceeded in ionic liquids using a PIL-supported B12 catalyst with a Ru(ii) trisbipyridine photosensitizer.

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 788
Author(s):  
Beibei Zhang ◽  
Lu Zhang ◽  
Yulong Zhang ◽  
Chao Liu ◽  
Jiexiang Xia ◽  
...  

In this work, a simple chemical precipitation method was employed to prepare spherical-like Ag3PO4 material (IL-Ag3PO4) with exposed {111} facet in the presence of reactive ionic liquid 1-butyl-3-methylimidazole dihydrogen phosphate ([Omim]H2PO4). The crystal structure, microstructure, optical properties, and visible-light photocatalytic performance of as-prepared materials were studied in detail. The addition of ionic liquids played a crucial role in forming spherical-like morphology of IL-Ag3PO4 sample. Compared with traditional Ag3PO4 material, the intensity ratio of {222}/{200} facets in XRD pattern of IL-Ag3PO4 was significantly enhanced, indicating the main {111} facets exposed on the surface of IL-Ag3PO4 sample. The presence of exposed {111} facet was advantageous for facilitating the charge carrier transfer and separation. The light-harvesting capacity of IL-Ag3PO4 was larger than that of Ag3PO4. The photocatalytic activity of samples was evaluated by degrading rhodamine B (RhB) and p-chlorophenol (4-CP) under visible light. The photodegradation efficiencies of IL-Ag3PO4 were 1.94 and 2.45 times higher than that of Ag3PO4 for RhB and 4-CP removal, respectively, attributing to a synergy from the exposed {111} facet and enhanced photoabsorption. Based on active species capturing experiments, holes (h+), and superoxide radical (•O2−) were the main active species for visible-light-driven RhB photodegradation. This study will provide a promising prospect for designing and synthesizing ionic liquid-assisted photocatalysts with a high efficiency.


RSC Advances ◽  
2018 ◽  
Vol 8 (15) ◽  
pp. 7956-7962 ◽  
Author(s):  
Zhidong Wei ◽  
Ruishuo Li ◽  
Rui Wang

In this study, hierarchical BiOBr microspheres were synthesized via a one-pot solvothermal method in the presence of imidazole ionic liquids.


2012 ◽  
Vol 87 (12) ◽  
pp. 1626-1633 ◽  
Author(s):  
Hui Xu ◽  
Yanhua Song ◽  
Ling Liu ◽  
Huaming Li ◽  
Yuanguo Xu ◽  
...  

RSC Advances ◽  
2013 ◽  
Vol 3 (42) ◽  
pp. 19624 ◽  
Author(s):  
Jun Di ◽  
Jiexiang Xia ◽  
Sheng Yin ◽  
Hui Xu ◽  
Minqiang He ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42354-42362
Author(s):  
Francesco Secundo ◽  
Yutaka Amao

Visible-light-driven CO2 reduction to formate with water-soluble zinc tetraphenylporphyrin tetrasulfonate, formate dehydrogenase from Candida boidinii and methylviologen in the presence of triethanolamine as an electron donor in an ionic liquid.


2015 ◽  
Vol 3 (48) ◽  
pp. 24187-24194 ◽  
Author(s):  
Kelly M. Meek ◽  
Yossef A. Elabd

Polymerized ionic liquid (PIL) block copolymers are an emerging class of polymers that synergistically combine the benefits of both ionic liquids (ILs) and block copolymers into one, where the former possesses a unique set of physiochemical properties and the latter self assembles into a range of nanostructures.


2020 ◽  
Vol 8 (24) ◽  
pp. 9088-9094
Author(s):  
Yu Chen ◽  
Yanfei Zhao ◽  
Bo Yu ◽  
Yunyan Wu ◽  
Xiaoxiao Yu ◽  
...  

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