Towards a full understanding of the nature of Ni(ii) species and hydroxyl groups over highly siliceous HZSM-5 zeolite supported nickel catalysts prepared by a deposition–precipitation method

2016 ◽  
Vol 45 (6) ◽  
pp. 2720-2739 ◽  
Author(s):  
Bao-Hui Chen ◽  
Zi-Sheng Chao ◽  
Hao He ◽  
Chen Huang ◽  
Ya-Juan Liu ◽  
...  

A mechanism for the preparation of highly siliceous HZSM-5 zeolite supported nickel catalysts via a deposition–precipitation (D–P) method.

RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61536-61543 ◽  
Author(s):  
Ahmad Reza Keshavarz ◽  
Mansooreh Soleimani

In this work, steam pre-reforming of natural gas over magnesium aluminate-supported nickel catalysts (Ni/MgAl2O4) was studied.


2018 ◽  
Vol 55 (1B) ◽  
pp. 49
Author(s):  
Phuong P. H.

A series of 10 wt% Ni/Al2O3–MO (M = Mg, Ca, Ba) catalyst was prepared by impregnation method for applying in the combined steam and carbon dioxide reforming of methane (CSCRM). In this study, five supported nickel catalysts were impregnated on different supports. All of the supports have been obtained by co–precipitation method and also have been investigated. Several techniques, including N2 physisorption measurements, X–ray powder diffraction (XRD), temperature–programmed reduction using H2 (H2–TPR), and transmission electron microscopy (TEM) were used to investigate catalysts’ physicochemical properties. The results showed that MgO was the most suitable promoter comparing with CaO and BaO in CSCRM. The presence of MgO in Ni/Al2O3 changed catalysts’ characteristics leading to an increase in the catalytic activity and stability with time on stream (TOS). It was found that the suitable catalyst was Ni–based on Al2O3–MgO of mass ratio 2:1 which showed a high metal dispersion as well as dominated spinel structure. The CH4 and CO2 conversion at 800 °C reached 99.8 % and 51.7 %, respectively. Catalytic stability of this catalyst with TOS at 800 °C could reach to more than 20 hours until it started decreasing.


2013 ◽  
Vol 33 (7) ◽  
pp. 1176-1182
Author(s):  
Xinxing WANG ◽  
Xueguang WANG ◽  
Xingfu SHANG ◽  
Wangxin NIE ◽  
Xiujing ZOU ◽  
...  

2021 ◽  
Vol 23 (3) ◽  
pp. 1353-1360
Author(s):  
Xiaodong Liu ◽  
Xiaohao Liu ◽  
Ning Li ◽  
Peiyong Ma ◽  
Ying Zhang

A series of Ni/ZrPx catalysts with precisely regulated acid and hydrogenation sites were prepared to study the structure–activity relationship for sorbitol production directly from microcrystalline cellulose and raw biomass.


2021 ◽  
Vol 35 (4) ◽  
pp. 3307-3314
Author(s):  
Yahong Han ◽  
Jinxian Zhao ◽  
Yanhong Quan ◽  
Shunan Yin ◽  
Shiping Wu ◽  
...  

1989 ◽  
Vol 18 (5) ◽  
pp. 777-780 ◽  
Author(s):  
Yoshio Uemichi ◽  
Takeshi Sakai ◽  
Takaji Kanazuka

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