Nanosheets of graphitic carbon nitride as metal-free environmental photocatalysts

2014 ◽  
Vol 4 (12) ◽  
pp. 4258-4264 ◽  
Author(s):  
Zhijun Huang ◽  
Fengbo Li ◽  
Bingfeng Chen ◽  
Guoqing Yuan

Nanosheets of g-C3N4 with a surface area of 109.9 m2 g−1 exhibit better optical properties and enhanced photocatalytic activity.

RSC Advances ◽  
2015 ◽  
Vol 5 (18) ◽  
pp. 14027-14033 ◽  
Author(s):  
Zhijun Huang ◽  
Fengbo Li ◽  
Bingfeng Chen ◽  
Guoqing Yuan

Nanostructured g-C3N4 with high surface area from heat treatment of guanidinium cyanurate exhibits better optical properties and enhanced photocatalytic activity.


RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 94496-94501 ◽  
Author(s):  
Lei Luo ◽  
Anfeng Zhang ◽  
Michael J. Janik ◽  
Chunshan Song ◽  
Xinwen Guo

Spherical urchin-like graphitic carbon nitride nanoparticles were fabricated and exhibited almost 12 times higher activity during RhB photodegradation.


2020 ◽  
Vol 277 ◽  
pp. 128277 ◽  
Author(s):  
Anita Sudhaik ◽  
Pankaj Raizada ◽  
Saloni Thakur ◽  
Adesh K. Saini ◽  
Pardeep Singh ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 7779-7789 ◽  
Author(s):  
Asmat Ullah Khan ◽  
Rasheed Ahmad Khera ◽  
Naveed Anjum ◽  
Rao Aqil Shehzad ◽  
Saleem Iqbal ◽  
...  

DFT calculations are carried out to investigate nonlinear optical (NLO) properties of superhalogen (BCl4) and superalkali (NLi4) doped graphitic carbon nitride (GCN).


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Yunyan Wu ◽  
Pan Xiong ◽  
Jianchun Wu ◽  
Zengliang Huang ◽  
Jingwen Sun ◽  
...  

AbstractGraphitic carbon nitride (g-C3N4)-based photocatalysts have shown great potential in the splitting of water. However, the intrinsic drawbacks of g-C3N4, such as low surface area, poor diffusion, and charge separation efficiency, remain as the bottleneck to achieve highly efficient hydrogen evolution. Here, a hollow oxygen-incorporated g-C3N4 nanosheet (OCN) with an improved surface area of 148.5 m2 g−1 is fabricated by the multiple thermal treatments under the N2/O2 atmosphere, wherein the C–O bonds are formed through two ways of physical adsorption and doping. The physical characterization and theoretical calculation indicate that the O-adsorption can promote the generation of defects, leading to the formation of hollow morphology, while the O-doping results in reduced band gap of g-C3N4. The optimized OCN shows an excellent photocatalytic hydrogen evolution activity of 3519.6 μmol g−1 h−1 for ~ 20 h, which is over four times higher than that of g-C3N4 (850.1 μmol g−1 h−1) and outperforms most of the reported g-C3N4 catalysts.


2021 ◽  
Author(s):  
Vellaichamy Balakumar ◽  
Manivannan Ramalingam ◽  
Chitiphon Chuaicham ◽  
KARTHIKEYAN SEKAR ◽  
K. Sasaki

Hollow porous graphitic carbon nitride (porous CN) was synthesized via a simple tactic method, and the resulting porous CN showed an effectively modified surface area, crystal structure and enhanced photocatalytic...


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