Solvent-free oxidation of ethylbenzene over hierarchical flower-like core–shell structured Co-based mixed metal oxides with significantly enhanced catalytic performance

2015 ◽  
Vol 5 (1) ◽  
pp. 540-548 ◽  
Author(s):  
Renfeng Xie ◽  
Guoli Fan ◽  
Lan Yang ◽  
Feng Li

Hierarchical flower-like core–shell structured Co-based mixed metal oxides exhibited excellent catalytic performance in solvent-free oxidation of ethylbenzene.

2013 ◽  
Vol 42 (40) ◽  
pp. 14498 ◽  
Author(s):  
Junting Feng ◽  
Chao Ma ◽  
Peter J. Miedziak ◽  
Jennifer K. Edwards ◽  
Gemma L. Brett ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (65) ◽  
pp. 39922-39930
Author(s):  
Shuangming Li ◽  
Yongwei Liu ◽  
Yaoxin Fan ◽  
Zixuan Lu ◽  
Yunong Yan ◽  
...  

Nanoflake MoVTeNbOx prepared by sub-/supercritical water exhibit excellent catalytic performance in the selective oxidation of propylene to acrylic acid.


Catalysts ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 71
Author(s):  
Yuxin Chen ◽  
Dan Dang ◽  
Binhang Yan ◽  
Yi Cheng

Composite catalysts of mixed metal oxides were prepared by mixing a phase-pure M1 MoVNbTeOx with anatase-phase TiO2. Two methods were used to prepare the composite catalysts (the simple physically mixed or sol-gel method) for the improvement of the catalytic performance in the oxidative dehydrogenation of ethane (ODHE) process. The results showed that TiO2 particles with a smaller particle size were well dispersed on the M1 surface for the sol-gel method, which presented an excellent activity for ODHE. At the same operating condition (i.e., the contact time of 7.55 gcat·h/molC2H6 and the reaction temperature of 400 °C), the M1-TiO2-SM and M1-TiO2-PM achieved the space time yields of 0.67 and 0.52 kgC2H4/kgcat/h, respectively, which were about ~76% and ~35% more than that of M1 catalyst (0.38 kgC2H4/kgcat/h), respectively. The BET, ICP, XRD, TEM, SEM, H2-TPR, C2H6-TPSR, and XPS techniques were applied to characterize the catalysts. It was noted that the introduction of TiO2 raised the V5+ abundance on the catalyst surface as well as the reactivity of active oxygen species, which made contribution to the promotion of the catalytic performance. The surface morphology and crystal structure of used catalysts of either M1-TiO2-SM or M1-TiO2-PM remained stable as each fresh catalyst after 24 h time-on-stream tests.


2008 ◽  
Vol 9 (5) ◽  
pp. 639-644 ◽  
Author(s):  
Sameer S. Deshpande ◽  
Sachin U. Sonavane ◽  
Radha V. Jayaram

2021 ◽  
Vol 57 (29) ◽  
pp. 3587-3590
Author(s):  
Beili Yi ◽  
Haojie Zhao ◽  
Yue Zhang ◽  
Xiaomeng Si ◽  
Guanqun Zhang ◽  
...  

We propose a novel solvent-free conversion strategy of Pt–ZnO to Pt-ZIF-8. This synthesis strategy may facilitate the discovery of MMOFs that have not been reported previously.


ChemCatChem ◽  
2021 ◽  
Author(s):  
Ruobing Sun ◽  
Feng Yu ◽  
Yinji Wan ◽  
Keke Pan ◽  
Wenjian Li ◽  
...  

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