scholarly journals The role of carbonaceous deposits in the activity and stability of Ni-based catalysts applied in the dry reforming of methane

2014 ◽  
Vol 4 (9) ◽  
pp. 3317-3328 ◽  
Author(s):  
Hendrik Düdder ◽  
Kevin Kähler ◽  
Bastian Krause ◽  
Katharina Mette ◽  
Stefanie Kühl ◽  
...  

Highly stable Ni catalysts with varying Ni contents up to 50 mol% originating from hydrotalcite-like precursors were applied in the dry reforming of methane at 800 and 900 °C.

Chemistry ◽  
2018 ◽  
Vol 1 (1) ◽  
pp. 3-16 ◽  
Author(s):  
Cameron Price ◽  
Emily Earles ◽  
Laura Pastor-Pérez ◽  
Jian Liu ◽  
Tomas Reina

Encapsulation of metal nanoparticles is a leading technique used to inhibit the main deactivation mechanisms in dry reforming of methane reaction (DRM): Carbon formation and Sintering. Ni catalysts (15%) supported on alumina (Al2O3) and ceria (CeO2) have shown they are no exception to this analysis. The alumina supported catalysts experienced graphitic carbonaceous deposits, whilst the ceria showed considerable sintering over 15 h of DRM reaction. The effect of encapsulation compared to that of the performance of uncoated catalysts for DRM reaction has been examined at different temperatures, before conducting longer stability tests. The encapsulation of Ni/ZnO cores in silica (SiO2) leads to advantageous conversion of both CO2 and CH4 at high temperatures compared to its uncoated alternatives. This work showcases the significance of the encapsulation process and its overall effects on the catalytic performance in chemical CO2 recycling via DRM.


2014 ◽  
Vol 4 (11) ◽  
pp. 4100-4100
Author(s):  
Hendrik Düdder ◽  
Kevin Kähler ◽  
Bastian Krause ◽  
Katharina Mette ◽  
Stefanie Kühl ◽  
...  

Author(s):  
Rodolfo Andrade Schaffner ◽  
Carine Aline Schwengber ◽  
Rafaela Luisa Kowalski ◽  
Natalie Souto Gonçalves Assis ◽  
Roberta Carolina Pelissari Rizzo Domingues ◽  
...  

2020 ◽  
Vol 150 (8) ◽  
pp. 2180-2199 ◽  
Author(s):  
S. Dekkar ◽  
S. Tezkratt ◽  
D. Sellam ◽  
K. Ikkour ◽  
K. Parkhomenko ◽  
...  

2013 ◽  
Vol 34 (4) ◽  
pp. 764-768 ◽  
Author(s):  
Anis H FAKEEHA ◽  
Wasim U. KHAN ◽  
Ahmed S. AL-FATESH ◽  
Ahmed E. ABASAEED

RSC Advances ◽  
2016 ◽  
Vol 6 (13) ◽  
pp. 10372-10384 ◽  
Author(s):  
Faris A. J. Al-Doghachi ◽  
Umer Rashid ◽  
Yun Hin Taufiq-Yap

The DRM reaction on the Pt, Pd, Ni/Mg1−XCeXO catalyst was studied where the methane molecule was activated on the Ni metal to produce hydrogen gas. The role of the other metals like Pt and Pd impregnated on the surface of the catalyst was shown.


2020 ◽  
Vol 275 ◽  
pp. 119109 ◽  
Author(s):  
Jijiang Huang ◽  
Yong Yan ◽  
Syed Saqline ◽  
Wen Liu ◽  
Bin Liu

2008 ◽  
Vol 85 (6) ◽  
pp. 889-899 ◽  
Author(s):  
Jasmin Blanchard ◽  
Ana Julia Nsungui ◽  
Nicolas Abatzoglou ◽  
François Gitzhofer

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