scholarly journals Synthesis and functionalization of SSZ-13 as an NH3-SCR catalyst

2014 ◽  
Vol 4 (11) ◽  
pp. 3917-3926 ◽  
Author(s):  
Alexander Shishkin ◽  
Hannes Kannisto ◽  
Per-Anders Carlsson ◽  
Hanna Härelind ◽  
Magnus Skoglundh
Keyword(s):  
Hydrothermal Synthesis ◽  
Ion Exchange ◽  
Structure Directing Agent ◽  
Scr Catalyst ◽  
Low Concentration ◽  
Nh3 Scr

Hydrothermal synthesis of Na-SSZ-13 using a low concentration of the structure-directing agent N,N,N-trimethyl-1-adamantanimonium hydroxide and functionalization of the SSZ-13 framework through the introduction of Cu and Fe via ion exchange have been carried out.

scholarly journals AFX Zeolite for Use as a Support of NH3-SCR Catalyst Mining through AICE Joint Research Project of Industries–Academia–Academia

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 163
Author(s):  
Masaru Ogura ◽  
Yumiko Shimada ◽  
Takeshi Ohnishi ◽  
Naoto Nakazawa ◽  
Yoshihiro Kubota ◽  
...  
Keyword(s):  
High Performance ◽  
Ionic Species ◽  
Research Project ◽  
Joint Research ◽  
Structure Directing Agent ◽  
Scr Catalyst ◽  
Organic Structure ◽  
Nh3 Scr ◽  
Joint Research Project ◽  
The One

This paper introduces a joint industries–academia–academia research project started by researchers in several automobile companies and universities working on a single theme. Our first target was to find a zeolite for NH3-SCR, that is, zeolite mining. Zeolite AFX, having the same topology of SSZ-16, was found to be the one of the zeolites. SSZ-16 can be synthesized by using an organic structure-directing agent such as 1,1′-tetramethylenebis(1-azonia-4-azabicyclo[2.2.2]octane; Dab-4, resulting in the formation of Al-rich SSZ-16 with Si/Al below five. We found that AFX crystallized by use of N,N,N′,N′-tetraethylbicyclo[2.2.2]oct-7-ene-2,3:5,6-dipyrrolidinium ion, called TEBOP in this study, had the same analog as SSZ-16 having Si/Al around six and a smaller particle size than SSZ-16. The AFX demonstrated a high performance for NH3-SCR as the zeolitic support to load a large number of divalent Cu ionic species with high hydrothermal stability.

Redistributing Cu species in Cu-SSZ-13 zeolite as NH3-SCR catalyst via a simple ion-exchange

2021 ◽  
Author(s):  
Ben Liu ◽  
Nangui Lv ◽  
Chan Wang ◽  
Hongwei Zhang ◽  
Yuanyuan Yue ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Scr Catalyst ◽  
Nh3 Scr

scholarly journals Evaluation of Cu/SAPO-34 Catalysts Prepared by Solid-State and Liquid Ion-Exchange Methods for NOx Removal by NH3-SCR

ACS Omega ◽  
2019 ◽  
Vol 4 (12) ◽  
pp. 14699-14713 ◽  
Author(s):  
Maitane Urrutxua ◽  
Beñat Pereda-Ayo ◽  
Unai De-La-Torre ◽  
Juan R. González-Velasco
Keyword(s):  
Solid State ◽  
Ion Exchange ◽  
Nox Removal ◽  
Nh3 Scr

Hydrothermal synthesis of flower cluster-shaped ZnO microstructures with sodium lignosulfonate as structure-directing agent

2015 ◽  
Vol 26 (11) ◽  
pp. 9171-9177
Author(s):  
Chen Hao ◽  
Huailiang Zhang ◽  
Xiaohong Wang ◽  
Yuru Shen ◽  
Yinglu Yang ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Sodium Lignosulfonate ◽  
Structure Directing Agent

The role of various iron species in Fe-β catalysts with low iron loadings for NH3-SCR

2014 ◽  
Vol 4 (5) ◽  
pp. 1350-1356 ◽  
Author(s):  
Haiyan Liu ◽  
Jun Wang ◽  
Tie Yu ◽  
Shikuan Fan ◽  
Meiqing Shen
Keyword(s):  
Ion Exchange ◽  
Iron Species ◽  
Exchange Method ◽  
Nh3 Scr ◽  
Ion Exchange Method

A series of Fe-β catalysts, containing 0.17–0.52 wt% Fe, were prepared by a liquid ion-exchange method to study the influence of various iron species on NH3-SCR activity.

Hydrothermal synthesis of Sn-Beta zeolites in F−-free medium

2018 ◽  
Vol 5 (11) ◽  
pp. 2763-2771 ◽  
Author(s):  
Hao Xu ◽  
Xudong Wang ◽  
Peng Ji ◽  
Haihong Wu ◽  
Yejun Guan ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Lewis Acid ◽  
Crystal Size ◽  
Acid Catalysts ◽  
Free Medium ◽  
Lewis Acid Catalysts ◽  
Structure Directing Agent ◽  
Highly Active ◽  
Beta Zeolites

Sn-Beta zeolites, with high Sn content and smaller crystal size, hydrothermally synthesized in F−-free medium using N-cyclohexyl-N,N-dimethylcyclohexanaminium hydroxide as the structure-directing agent with the assistance of Na+ and seed, are highly active as Lewis acid catalysts.

Low-temperature Shift DeNOx Activity of Nanoflake V2O5 loaded WO3/TiO2 as NH3-SCR Catalyst

2022 ◽  
pp. 109191
Author(s):  
Jae Gu Heo ◽  
Mahboob Ullah ◽  
Myoung-Pyo Chun ◽  
Yong Sik Chu ◽  
Seong Gwan Seo ◽  
...  
Keyword(s):  
Low Temperature ◽  
Temperature Shift ◽  
Scr Catalyst ◽  
Nh3 Scr

scholarly journals The Effect of Tourmaline on SCR Denitrification Activity of MnOx/TiO2 at Low Temperature

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1020
Author(s):  
Yizhe Helian ◽  
Suping Cui ◽  
Xiaoyu Ma
Keyword(s):  
Low Temperature ◽  
Catalytic Reduction ◽  
Catalytic Performance ◽  
Scr Catalyst ◽  
Highly Efficient ◽  
Nh3 Scr ◽  
Catalytic Material ◽  
Acidic Sites ◽  
Denitrification Activity ◽  
The Stability

Selective catalytic reduction (SCR) technology is the most widely used flue gas denitration technology at present. The stability of a catalyst is the main factor limiting the development of this technology. In this study, an environmentally friendly and highly efficient NH3-SCR catalyst was prepared by coprecipitation method from acidolysis residue of industrial waste and tourmaline. We found that the addition of tourmaline has an important impact on the denitration activity of the catalytic material. The NOx conversion exceeded 97% at 200 °C with the dosage of 10% tourmaline, which is about 7% higher than that without doping. The improvement of catalytic performance was mostly attributed to the permanent electrodes of tourmaline, which effectively promotes the dispersion of MnOx/TiO2 catalytic materials, increases the number of acidic sites and changes the valence distribution of manganese ions in products, which speeds up the diffusion of protons and ions, resulting in the acceleration of redox reaction. These as-developed tourmaline-modified MnOx/TiO2 materials have been demonstrated to be promising as a new type of highly efficient low-temperature NH3-SCR catalyst.

Sign in / Sign up

Export Citation Format

Share Document