scholarly journals Dynamics of the A-band ultraviolet photodissociation of methyl iodide and ethyl iodide via velocity-map imaging with ‘universal’ detection

2015 ◽  
Vol 17 (6) ◽  
pp. 4096-4106 ◽  
Author(s):  
Sara H. Gardiner ◽  
M. Laura Lipciuc ◽  
Tolga N. V. Karsili ◽  
Michael N. R. Ashfold ◽  
Claire Vallance

Universal ionization combined with velocity-map imaging allows a comprehensive investigation into the photodissociation dynamics of methyl iodide and ethyl iodide at a range of UV wavelengths within their A-bands.

2019 ◽  
Vol 21 (28) ◽  
pp. 15695-15704 ◽  
Author(s):  
Marta L. Murillo-Sánchez ◽  
Sonia Marggi Poullain ◽  
Vincent Loriot ◽  
Maria E. Corrales ◽  
Luis Bañares

Femtosecond velocity map imaging to disentangle the electronic predissociation of ethyl iodide in the B-band.


1956 ◽  
Vol 34 (3) ◽  
pp. 354-358 ◽  
Author(s):  
Mary Elaine Leblanc ◽  
A. T. Morse ◽  
L. C. Leitch

An improved method of preparing deuterated alkanes from the halides has been developed. Dehalogenation of ethyl iodide, 1,1-dibromoethane, and 1,1,1-trichloroethane with zinc dust in deuterium oxide – dioxane solutions, or even with deuterium oxide alone, gave excellent yields of ethane-d1, ethane-1,1-d2, and ethane-1,1,1-d3. Methane-d1, -d2, -d3, and -d4 were prepared similarly from methyl iodide, dibromomethane, chloroform, and carbon tetrachloride respectively. The isotopic purity of the products was over 90 mol.%. The reaction is also applicable to higher alkyl halides.


2014 ◽  
Vol 16 (5) ◽  
pp. 2167-2178 ◽  
Author(s):  
Sara H. Gardiner ◽  
Tolga N. V. Karsili ◽  
M. Laura Lipciuc ◽  
Edward Wilman ◽  
Michael N. R. Ashfold ◽  
...  

2001 ◽  
Vol 44 (S1) ◽  
pp. S265-S267
Author(s):  
M. Ogawa ◽  
K. Hatano ◽  
Y. Kawasumi ◽  
K. Ishiwata ◽  
K. Kawamura ◽  
...  

2017 ◽  
Vol 19 (11) ◽  
pp. 7886-7896 ◽  
Author(s):  
S. Marggi Poullain ◽  
D. V. Chicharro ◽  
J. González-Vázquez ◽  
L. Rubio-Lago ◽  
L. Bañares

The photodissociation dynamics of the methyl iodide cation has been studied using velocity map imaging and ab initio theory to disentangle the dissociation mechanisms.


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