scholarly journals The model case of an oxygen storage catalyst – non-stoichiometry, point defects and electrical conductivity of single crystalline CeO2–ZrO2–Y2O3 solid solutions

2014 ◽  
Vol 16 (46) ◽  
pp. 25583-25600 ◽  
Author(s):  
Jens-Peter Eufinger ◽  
Maximilian Daniels ◽  
Kerstin Schmale ◽  
Stefan Berendts ◽  
Gregor Ulbrich ◽  
...  

Defect-chemistry of the oxygen storage compound CeO2–ZrO2–Y2O3 has been investigated with conductivity, EMF and non-stoichiometry measurements and the observed non-ideality was described by an unconventional defect-model.

ACS Nano ◽  
2013 ◽  
Vol 7 (4) ◽  
pp. 2999-3013 ◽  
Author(s):  
Pascal Hartmann ◽  
Torsten Brezesinski ◽  
Joachim Sann ◽  
Andriy Lotnyk ◽  
Jens-Peter Eufinger ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 398
Author(s):  
Yuriy Suhak ◽  
Dmitry Roshchupkin ◽  
Boris Redkin ◽  
Ahsanul Kabir ◽  
Bujar Jerliu ◽  
...  

Electrical conductivity and acoustic loss Q−1 of single crystalline Li(Nb,Ta)O3 solid solutions (LNT) are studied as a function of temperature by means of impedance spectroscopy and resonant piezoelectric spectroscopy, respectively. For this purpose, bulk acoustic wave resonators with two different Nb/Ta ratios are investigated. The obtained results are compared to those previously reported for congruent LiNbO3. The temperature dependent electrical conductivity of LNT and LiNbO3 show similar behavior in air at high temperatures from 400 to 700 °C. Therefore, it is concluded that the dominant transport mechanism in LNT is the same as in LN, which is the Li transport via Li vacancies. Further, it is shown that losses in LNT strongly increase above about 500 °C, which is interpreted to originate from conductivity-related relaxation mechanism. Finally, it is shown that LNT bulk acoustic resonators exhibit significantly lower loss, comparing to that of LiNbO3.


2008 ◽  
Vol 179 (27-32) ◽  
pp. 1432-1435 ◽  
Author(s):  
Elena Konysheva ◽  
John T.S. Irvine ◽  
Astrid Besmehn

Author(s):  
Issei Suzuki ◽  
Zexin Lin ◽  
Sakiko Kawanishi ◽  
Kiyohisa Tanaka ◽  
Yoshitaro Nose ◽  
...  

Valence band dispersions of single-crystalline SnS1-xSex solid solutions were observed by angle-resolved photoemission spectroscopy (ARPES). The hole effective masses, crucial factors in determining thermoelectric properties, were directly evaluated. They decrease...


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