Electrochemical in battery polymerization of poly(alkylenedioxythiophene) over lithium iron phosphate for high-performance cathodes

2014 ◽  
Vol 16 (38) ◽  
pp. 20724-20730 ◽  
Author(s):  
Daniel Cíntora-Juárez ◽  
Carlos Pérez-Vicente ◽  
Shahzada Ahmad ◽  
José Luis Tirado
Keyword(s):  
High Performance ◽  
Lithium Iron Phosphate ◽  
Iron Phosphate ◽  
Molecular Wiring

Molecular wiring concept in LiFePO4 cathodes by in battery polymerization.

scholarly journals LiFePO4-Graphene Composites as High-Performance Cathodes for Lithium-Ion Batteries: The Impact of Size and Morphology of Graphene

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 842 ◽  
Author(s):  
Yanqing Fu ◽  
Qiliang Wei ◽  
Gaixia Zhang ◽  
Yu Zhong ◽  
Nima Moghimian ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Lithium Iron Phosphate ◽  
Low Cost ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Full Potential ◽  
Active Materials ◽  
Size And Morphology ◽  
The Impact

In this work, we investigated three types of graphene (i.e., home-made G, G V4, and G V20) with different size and morphology, as additives to a lithium iron phosphate (LFP) cathode for the lithium-ion battery. Both the LFP and the two types of graphene (G V4 and G V20) were sourced from industrial, large-volume manufacturers, enabling cathode production at low cost. The use of wrinkled and/or large pieces of a graphene matrix shows promising electrochemical performance when used as an additive to the LFP, which indicates that the features of large and curved graphene pieces enable construction of a more effective conducting network to realize the full potential of the active materials. Specifically, compared to pristine LFP, the LFP/G, LFP/G V20, and LFP/G V4 show up to a 9.2%, 6.9%, and 4.6% increase, respectively, in a capacity at 1 C. Furthermore, the LFP combined with graphene exhibits a better rate performance than tested with two different charge/discharge modes. Moreover, from the economic and electrochemical performance view point, we also demonstrated that 1% of graphene content is optimized no matter the capacity calculated, based on the LFP/graphene composite or pure LFP.

Judicious design of lithium iron phosphate electrodes using poly(3,4-ethylenedioxythiophene) for high performance batteries

2015 ◽  
Vol 3 (27) ◽  
pp. 14254-14262 ◽  
Author(s):  
Daniel Cíntora-Juárez ◽  
Carlos Pérez-Vicente ◽  
Samrana Kazim ◽  
Shahzada Ahmad ◽  
José Luis Tirado
Keyword(s):  
High Performance ◽  
Lithium Iron Phosphate ◽  
Iron Phosphate

Designing of lithium iron phosphate electrodes using poly(3,4-ethylenedioxythiophene) for high performance batteries.

scholarly journals Non-stoichiometric carbon-coated LiFexPO4as cathode materials for high-performance Li-ion batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33544-33551 ◽  
Author(s):  
Ying Feng ◽  
Junjie Gu ◽  
Feng Yu ◽  
Chunfu Lin ◽  
Jinli Zhang ◽  
...  
Keyword(s):  
Cathode Materials ◽  
High Performance ◽  
Lithium Iron Phosphate ◽  
Iron Phosphate ◽  
Lattice Parameters ◽  
Li Ion Batteries ◽  
Carbon Coated ◽  
Li Ion ◽  
Work First

This work first discloses the evolution of lattice parameters of the non-stoichiometric lithium iron phosphate crystals.

Effects of Particle Size Distribution on Compacted Density of Lithium Iron Phosphate 18650 Battery

2018 ◽  
Vol 15 (4) ◽  
Author(s):  
Lei Chen ◽  
Zhenyu Chen ◽  
Shuaishuai Liu ◽  
Biaofeng Gao ◽  
Junwei Wang
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
High Performance ◽  
Lithium Iron Phosphate ◽  
Iron Phosphate ◽  
Specific Discharge ◽  
Average Size ◽  
Discharge Capacities ◽  
Selection Of

The effects of particle size distribution on compacted density of as-prepared spherical lithium iron phosphate (LFP) LFP-1 and LFP-2 materials electrode for high-performance 18650 Li-ion batteries are investigated systemically, while the selection of two commercial materials LFP-3 and LFP-4 as a comparison. The morphology study and physical characterization results show that the LFP materials are composed of numerous particles with an average size of 300–500 nm, and have well-developed interconnected pore structure and a specific surface area of 13–15 m2/g. For CR2032 coin-type cell, the specific discharge capacities of the LFP-1 and LFP-2 are about 165 mAh/g at 0.2 C. For 18650 batteries, results indicate that the LFP-3 material has the highest compacted density of 2.52 g/cm3 at a concentrated particle size distribution such as D10 = 0.56 μm, D50 = 1.46 μm, and D90 = 6.53 μm. By mixing two different particle sizes of LFP-1 and LFP-2, the compaction density can be increased significantly from 1.90 g/cm3 to 2.25 g/cm3.

High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

2015 ◽  
Vol 3 (5) ◽  
pp. 2043-2049 ◽  
Author(s):  
Zhang Jinli ◽  
Wang Jiao ◽  
Liu Yuanyuan ◽  
Nie Ning ◽  
Gu Junjie ◽  
...  
Keyword(s):  
Carbon Source ◽  
Lithium Ion Batteries ◽  
Hydrothermal Method ◽  
High Performance ◽  
Carbon Coating ◽  
Lithium Iron Phosphate ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Phosphorus Source ◽  
Phosphorus Doped

A novel composite of LiFePO4 with phosphorus-doped carbon layers has been prepared via a simple hydrothermal method using glucose as the carbon source to generate a carbon coating and triphenylphosphine as the phosphorus source.

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