A study into the extracted ion number for NASICON structured Na3V2(PO4)3 in sodium-ion batteries

2014 ◽  
Vol 16 (33) ◽  
pp. 17681-17687 ◽  
Author(s):  
Weixin Song ◽  
Xiaoyu Cao ◽  
Zhengping Wu ◽  
Jun Chen ◽  
Kaili Huangfu ◽  
...  

Excellent C-rate and cycling performance with a high specific capacity of 117.6 mA h g−1 have been achieved on NASICON-structure Na3V2(PO4)3 sodium-ion batteries.

2014 ◽  
Vol 7 (5) ◽  
pp. 1643-1647 ◽  
Author(s):  
Ya You ◽  
Xing-Long Wu ◽  
Ya-Xia Yin ◽  
Yu-Guo Guo

High-quality Prussian blue crystals with a small number of vacancies and a low water content show high specific capacity and remarkable cycle stability as cathode materials for Na-ion batteries.


RSC Advances ◽  
2019 ◽  
Vol 9 (27) ◽  
pp. 15210-15216 ◽  
Author(s):  
Mingxiang Deng ◽  
Sijie Li ◽  
Wanwan Hong ◽  
Yunling Jiang ◽  
Wei Xu ◽  
...  

Antimony sulfide (Sb2S3) has drawn widespread attention as an ideal candidate anode material for sodium-ion batteries (SIBs) due to its high specific capacity of 946 mA h g−1 in conversion and alloy reactions.


2018 ◽  
Vol 6 (5) ◽  
pp. 2139-2147 ◽  
Author(s):  
Dan Zhou ◽  
Li-Zhen Fan

A novel Co2P-3D PNC composite with Co2P NPs encapsulated in 3D porous N-doped carbon nanosheet networks was synthesized by a cobalt nitrate-induced PVP-blowing method combined with an in situ phosphidation process. The resultant Co2P-3D PNC anode delivers high specific capacity, enhanced rate capability, and improved cycling stability.


Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5539
Author(s):  
Hongyang Zhou ◽  
Jin Gu ◽  
Weiwei Zhang ◽  
Chuanshuang Hu ◽  
Xiuyi Lin

Cellulose nanofibrils (CNF) with high thermal stability and excellent electrolyte wettability attracted tremendous attention as a promising separator for the emerging sodium-ion batteries. The pore structure of the separator plays a vital role in electrochemical performance. CNF separators are assembled using the bottom-up approach in this study, and the pore structure is carefully controlled through film-forming techniques. The acid-treated separators prepared from the solvent exchange and freeze-drying demonstrated an optimal pore structure with a high electrolyte uptake rate (978.8%) and Na+ transference number (0.88). Consequently, the obtained separator showed a reversible specific capacity of 320 mAh/g and enhanced cycling performance at high rates compared to the commercial glass fiber separator (290 mAh/g). The results highlight that CNF separators with an optimized pore structure are advisable for sodium-ion batteries.


2018 ◽  
Vol 47 (4) ◽  
pp. 1223-1232 ◽  
Author(s):  
K. Hemalatha ◽  
M. Jayakumar ◽  
A. S. Prakash

The resurgence of sodium-ion batteries in recent years is due to their potential ability to form intercalation compounds possessing a high specific capacity and energy density comparable to existing lithium systems.


Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2206 ◽  
Author(s):  
Zehua Chen ◽  
Liang Lu ◽  
Yu Gao ◽  
Qixiang Zhang ◽  
Chuanxiang Zhang ◽  
...  

The effects of fluorine (F) doping on the phase, crystal structure, and electrochemical performance of Na2Ti3O7 are studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical measurements. F-doping does not change the crystal structure of NTO, although it has an effect on the morphology of the resultant product. As an anode material for sodium-ion batteries, the specific capacity of Na2Ti3O7 exhibits a 30% increase with F-doping owing to the improved sodium ion diffusion coefficient. F-doped Na2Ti3O7 also displays an enhanced rate capability and favourable cycling performance for more than 800 cycles.


2018 ◽  
Vol 11 (04) ◽  
pp. 1850072 ◽  
Author(s):  
Jifei Liu ◽  
Jianfeng Dai ◽  
Liangbiao Huang ◽  
Bi Fu

Transition metal oxides applied as anode material for sodium-ion batteries have been widely investigated due to their high specific capacity, especially for Co3O4-related nanomaterials. However, its intrinsic low electronic conductivity and the aggregation phenomenon of commercial Co3O4 nanoparticles result in a low initially coulombic efficiency and the fading of cycle performance. In this paper, commercial Co3O4 nanoparticles/carbon composite nanofiber mats were synthesized by sol–gel electrospinning. When directly applied, such flexible negative electrodes as sodium-ion batteries, revealed high specific capacity and excellent rate performance simultaneously, which are not only attributed to the high electronic conductivity of carbon nanofiber mats that could enhance the ionic and electronic transport property, but also attributed to its three-dimensional fibrous network that could prevent the aggregation of commercial Co3O4 nanoparticles. Such a flexible, binder-free and high electronic conductivity negative electrode enables promising applications for large-scale energy storage and conversion.


RSC Advances ◽  
2017 ◽  
Vol 7 (18) ◽  
pp. 10885-10890 ◽  
Author(s):  
Yingchang Yang ◽  
Shijia Liao ◽  
Wei Shi ◽  
Yundong Wu ◽  
Renhui Zhang ◽  
...  

Nitrogen-doped TiO2(B) nanorods exhibit high specific capacity, good cycling stability and enhanced rate capability when utilized in sodium-ion batteries.


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