scholarly journals Linear free energy relationships in RNA transesterification: theoretical models to aid experimental interpretations

2014 ◽  
Vol 16 (30) ◽  
pp. 15846-15855 ◽  
Author(s):  
Ming Huang ◽  
Darrin M. York
Keyword(s):  
Free Energy ◽  
Theoretical Models ◽  
Linear Free Energy Relationships ◽  
Stepwise Mechanism ◽  
Linear Free Energy ◽  
Leaving Group ◽  
Energy Relationships

Depending on the nature of the leaving group, reactions may proceedviaa stepwise mechanism or through a single early TS1. Brønsted correlations can be used to distinguish these two mechanisms.

scholarly journals Linear Free Energy Relationships in Glass Corrosion

1988 ◽  
Vol 125 ◽  
Author(s):  
Teofilo A. Abrajano ◽  
John K. Bates ◽  
J. K. Bohlke
Keyword(s):  
Free Energy ◽  
Theoretical Models ◽  
Empirical Approach ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Aluminosilicate Glasses ◽  
Glass Corrosion ◽  
Energy Relationships ◽  
Independent Confirmation ◽  
Existing Data

ABSTRACTVarious theoretical models that have been proposed to correlate glass durability to their composition for a wide variety of silicate, borosilicate, and aluminosilicate glasses are examined. Comparisons are made between the predictions of these models and those of an empirical formulation extracted from existing data in the present work. The empirical approach provides independent confirmation of the relative accuracy of the silica release rate predictions of the different theoretical models in static leaching systems. Extensions of the empirical approach used in this work are discussed.

scholarly journals Linear Free Energy Relationships in Glass Corrosion

1988 ◽  
Vol 123 ◽  
Author(s):  
Teofilo A. Abrajano ◽  
John K. Bates ◽  
J. K. Bohlke
Keyword(s):  
Free Energy ◽  
Theoretical Models ◽  
Empirical Approach ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Aluminosilicate Glasses ◽  
Glass Corrosion ◽  
Energy Relationships ◽  
Independent Confirmation ◽  
Existing Data

AbstractVarious theoretical models that have been proposed to correlate glass durability to their composition for a wide variety of silicate, borosilicate, and aluminosilicate glasses are examined. Comparisons are made between the predictions of these models and those of an empirical formulation extracted from existing data in the present work. The empirical approach provides independent confirmation of the relative accuracy of the silica release rate predictions of the different theoretical models in static leaching systems. Extensions of the empirical approach used in this work are discussed.

Linear free energy relationships in CN bond dissociations in molecular ions of 4-substitutedN-(2-furylmethyl)anilines in the gas phase

2007 ◽  
Vol 42 (11) ◽  
pp. 1496-1503 ◽  
Author(s):  
Eduardo A. Solano Espinoza ◽  
Elena Stashenko ◽  
Jairo Martínez ◽  
Uriel Mora ◽  
Vladimir Kouznetsov
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Molecular Ions ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships
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