scholarly journals Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO

2014 ◽  
Vol 16 (27) ◽  
pp. 13635-13644 ◽  
Author(s):  
Noémie Elgrishi ◽  
Matthew B. Chambers ◽  
Vincent Artero ◽  
Marc Fontecave
Keyword(s):  
Transition Metals ◽  
Electrochemical Reduction ◽  
Reduction Of Co2

Homoleptic terpyridine complexes of 3d transition metals are found to electrocatalytically reduce CO2 to either CO or tuneable CO–H2 mixtures.

Electrochemical reduction of CO2 on graphene supported transition metals – towards single atom catalysts

2017 ◽  
Vol 19 (18) ◽  
pp. 11436-11446 ◽  
Author(s):  
Haiying He ◽  
Yesukhei Jagvaral
Keyword(s):  
Transition Metals ◽  
Electrochemical Reduction ◽  
Single Atom ◽  
Single Atoms ◽  
Computational Screening ◽  
Reduction Of Co2

Graphene supported single atoms show improved reactivity towards electrochemical CO2 reduction with the best candidates identified for producing CH4 by computational screening.

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

Electrochemical Reduction of CO2 to CO in Organic Electrolyte with HCl Oxidized to Cl2 on Anode for Phosgene Synthesis

2021 ◽  
pp. 138728
Author(s):  
Chaojuan Li ◽  
Jin Shi ◽  
Jianxiong Liu ◽  
Yajian Duan ◽  
Yaxin Hua ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Organic Electrolyte ◽  
Reduction Of Co2

Effect of 3d-transition metals doped in ZnO monolayers on the CO2 electrochemical reduction to valuable products: first principles study

2021 ◽  
Vol 550 ◽  
pp. 149380
Author(s):  
Pornsawan Sikam ◽  
Kaito Takahashi ◽  
Thantip Roongcharoen ◽  
Thanadol Jitwatanasirikul ◽  
Chirawat Chitpakdee ◽  
...  
Keyword(s):  
Transition Metals ◽  
Electrochemical Reduction ◽  
First Principles ◽  
First Principles Study
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