Synthesis and aggregation properties of a series of dumbbell polyhedral oligosilsesquioxane-perylene diimide triads

CrystEngComm ◽  
2015 ◽  
Vol 17 (6) ◽  
pp. 1453-1463 ◽  
Author(s):  
Ying Zhang ◽  
Liangliang Zhang ◽  
Heyuan Liu ◽  
Di Sun ◽  
Xiyou Li
Keyword(s):  
Solid State ◽  
Perylene Diimide ◽  
Emission Properties ◽  
Polyhedral Oligosilsesquioxane

A series of perylenetetracarboxylic diimide compounds connected with POSS groups have been synthesized and their solid state emission properties are investigated.

scholarly journals Switching-On Fluorescence by Copper (II) and Basic Anions: A Case Study with a Pyrene-Functionalized Squaramide

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1301
Author(s):  
Giacomo Picci ◽  
Jessica Milia ◽  
Maria Carla Aragoni ◽  
Massimiliano Arca ◽  
Simon J. Coles ◽  
...  
Keyword(s):  
Solid State ◽  
Copper Complex ◽  
Receptor Complex ◽  
Emission Properties ◽  
Naked Eye ◽  
Intense Emission ◽  
Uv Lamp

The new symmetric acyclic N,N’-bis(1-pyrenyl) squaramide (H2L) functionalized with the pyrene moiety as a fluorogenic fragment has been designed and its ability to selectively detect specific anions and metals investigated. H2L selectively binds Cl− both in solution (DMSO 0.5% H2O and MeCN) and in the solid state, and allows to selectively detect Cu2+ in MeCN with the formation of a 2:1 metal-receptor complex, with a green intense emission appreciable by naked eye under the UV lamp. The H2L copper complex preserves its emission properties in the presence of Cl−. The addition of basic anions (OH−, CN−, and F−) up to 10 equivalents caused the deprotonation of the squaramide NHs and a dramatic change of the emission properties of the H2L copper complex.

Synthesis, Self-assembly, and Crystal Structure of a Shape-Persistent Polyhedral-Oligosilsesquioxane-Nanoparticle-Tethered Perylene Diimide

2010 ◽  
Vol 114 (14) ◽  
pp. 4802-4810 ◽  
Author(s):  
Xiangkui Ren ◽  
Bin Sun ◽  
Chi-Chun Tsai ◽  
Yingfeng Tu ◽  
Siwei Leng ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Self Assembly ◽  
Perylene Diimide ◽  
Polyhedral Oligosilsesquioxane

scholarly journals Discrete Dimers of Redox-Active and Fluorescent Perylene Diimide-Based Rigid Isosceles Triangles in the Solid State

2018 ◽  
Vol 141 (3) ◽  
pp. 1290-1303 ◽  
Author(s):  
Siva Krishna Mohan Nalluri ◽  
Jiawang Zhou ◽  
Tao Cheng ◽  
Zhichang Liu ◽  
Minh T. Nguyen ◽  
...  
Keyword(s):  
Solid State ◽  
Perylene Diimide ◽  
Redox Active ◽  
Isosceles Triangles

scholarly journals Nitrile-Substituted 2-(Oxazolinyl)-Phenols: Minimalistic Excited-State Intramolecular Proton Transfer (ESIPT)-Based Fluorophores

2020 ◽  
Author(s):  
Dominik Göbel ◽  
Daniel Duvinage ◽  
Tim Stauch ◽  
Boris Nachtsheim
Keyword(s):  
Excited State ◽  
Solid State ◽  
Proton Transfer ◽  
Density Functional ◽  
Intramolecular Proton Transfer ◽  
Crystal Structure Analysis ◽  
Quantum Yields ◽  
Functional Theory ◽  
Emission Properties ◽  
Emission Enhancement

Herein, we present minimalistic single-benzene, excited-state intramolecular proton transfer (ESIPT) based fluorophores as powerful solid state emitters. The very simple synthesis gave access to all four regioisomers of nitrile-substituted 2(oxazolinyl)phenols (MW = 216.1). In respect of their emission properties they can be divided into aggregation-induced emission enhancement (AIEE) luminophores (1-CN and 2-CN), dual state emission (DSE) emitters (3-CN) and aggregation-caused quenching (ACQ) fluorophores (4‐CN). Remarkably, with compound 1-CN we discovered a minimalistic ESIPT based fluorophore with extremely high quantum yield in the solid state ΦF = 87.3% at λem = 491 nm. Furthermore, quantum yields in solution were determined up to ΦF = 63.0%, combined with Stokes shifts up till 11.300 cm–1. Temperature dependent emission mapping, crystal structure analysis and time-dependent density functional theory (TDDFT) calculations gave deep insight into the origin of the emission properties.<br>

scholarly journals Conjugates of tetraphenylethene and diketopyrrolopyrrole: tuning the emission properties with phenyl bridges

2014 ◽  
Vol 50 (63) ◽  
pp. 8747-8750 ◽  
Author(s):  
Xiao Yuan Shen ◽  
Yi Jia Wang ◽  
Haoke Zhang ◽  
Anjun Qin ◽  
Jing Zhi Sun ◽  
...  
Keyword(s):  
Solid State ◽  
Emission Properties

Bridging DPP (ACQ-gen) and TPE (AIE-gen) with phenyls derived TPE–ph–DPP conjugates displaying enhanced and red-shifted emission in the solid state.

Water-sulfate anion interplay in the evolution of solid state architectures and emission properties of Zn and Cd coordination networks with four azine ligands

2020 ◽  
Vol 286 ◽  
pp. 121312 ◽  
Author(s):  
Vasile Lozovan ◽  
Victor Ch. Kravtsov ◽  
Eduard B. Coropceanu ◽  
Anatolii V. Siminel ◽  
Olga V. Kulikova ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Networks ◽  
Sulfate Anion ◽  
Emission Properties

Solid-state thiolate-stabilized copper nanoclusters with ultrahigh photoluminescence quantum yield for white light-emitting devices

Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15791-15799 ◽  
Author(s):  
Hao-Hua Deng ◽  
Qiong-Qiong Zhuang ◽  
Kai-Yuan Huang ◽  
Paramasivam Balasubramanian ◽  
Zhen Lin ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
White Light ◽  
Copper Nanoclusters ◽  
Light Emitting ◽  
Aggregation Induced Emission ◽  
Emission Properties ◽  
Light Emitting Devices ◽  
Photoluminescence Quantum Yield

White-light-emitting devices are successfully fabricated by using solid-state copper nanoclusters as the sole phosphors with aggregation-induced emission properties.

Conformation twisting induced orientational disorder, polymorphism and solid-state emission properties of 1-(9-anthryl)-2-(1-naphthyl)ethylene

CrystEngComm ◽  
2012 ◽  
Vol 14 (23) ◽  
pp. 8286 ◽  
Author(s):  
Ye-Xin Li ◽  
Hong-Bo Zhou ◽  
Jin-Ling Miao ◽  
Guo-Xin Sun ◽  
Guo-Bao Li ◽  
...  
Keyword(s):  
Solid State ◽  
Orientational Disorder ◽  
Emission Properties

Synthesis and Optical properties of Perylene Bisimide Incorporated Low Bandgap Polymers for Photovoltaics

2009 ◽  
Vol 1154 ◽  
Author(s):  
Sivamurugan Vajiravelu ◽  
suresh valiyaveettil
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Conjugated Polymers ◽  
Chemical Structure ◽  
Optical Band Gap ◽  
Visible Region ◽  
Perylene Diimide ◽  
Low Bandgap ◽  
Perylene Bisimide ◽  
C Nmr

AbstractHerein we report on the synthesis of perylene diimide (PDI) based P1 and P2 conjugated polymers via Suzuki polymerization. The chemical structure of the polymers was elucidated using GPC, 1H, 13C NMR and elemental analysis. The absorption spectra of polymers were in the visible region from 250 – 800 nm in solution and in solid state. The optical band gap was (Egopt) found to be between 1.60 – 1.83 eV in solid state.

Sign in / Sign up

Export Citation Format

Share Document